2012 Fiscal Year Final Research Report
Synthesis of Carbon Nanorings Bearing Non-planar Aromatics and Their Functionalization
| Project/Area Number |
22550097
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
MIKI Koji 京都大学, 大学院・工学研究科, 講師 (60422979)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 選択的合成・反応 / 大環状分子 / 包接 |
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| Research Abstract |
In this study, the efficient synthetic method to prepare π-conjugated strained macrocyclic compounds having phenyleneacetylene moieties on their backbones, which are difficult to be synthesized by coupling reactions, has been developed. Macrocyclic compounds bearing o- and m-phenylene moieties as well as twin carbon nanorings were successfully synthesized. These macrocycles including twin carbon nanorings form complexes with fullerenes efficiently. Macrocycles having electron-donating groups on their ring structures can form much more stable complexes.
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