2012 Fiscal Year Final Research Report
Development and Scope of Homogeneous Reversible Dehydrogenation/ Hydrogenation by Means of Highly Functional Dehydrogenation Catalyst
| Project/Area Number |
22550098
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
YAMAGUCHI Rhyohei 京都大学, 大学院・人間環境学研究科, 名誉教授 (40115960)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 錯体・有機金属触媒 / 脱水素化反応 / 水素化反応 / 含窒素複素環 / 水素貯蔵システム / イリジウム錯体 |
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| Research Abstract |
Novel iridium complex catalysts bearing a variety of functional ligands have been designed and synthesized, and homogeneous catalytic systems for dehydrogenation/hydrogenation of nitrogen heterocycles using these catalysts have been developed. As a result, an efficient dehydrogenation/hydrogenation catalytic system for organic hydride containing 6% hydrogen content under mild conditions has been successfully achieved, providing the basis for a new and effective hydrogen storage system.
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