2012 Fiscal Year Final Research Report
Development of Cleavage Reactions of C-O and N-S Bonds Promoted by Novel Low-Valent Titanium Reagents and Their Synthetic Applications
| Project/Area Number |
22550103
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | 選択的合成・反応 / 低原子価チタニウム |
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| Research Abstract |
In this research on low-valent titanium-promoted C-O and N-S bondcleavage reactions, radical reductive ring-opening reaction of epoxides includingstereoselective reactions and S-N bond cleavage of sulfonamides and sulfonylesters havebeen developed. In addition, novel valence-selective generation of low-valent titanium,radical ring-opening of oxetanes and reductive McMurry-type coupling reaction have beendiscovered.
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