2012 Fiscal Year Final Research Report
Development of heterotactic polymers by radical polymerization on divinyl-monomers
| Project/Area Number |
22550107
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
SAITO Reiko 東京工業大学, 大学院・理工学研究科, 准教授 (30225742)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 高分子合成 |
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| Research Abstract |
The novel polymerization method for heterotactic polymers via free radical polymerization by using divinyl or pseudo-divinyl monomer was developed. In this method, vinyl groups were finely arranged in the solution by template molecules. The covalent bonding and hydroben bonding of methacrylic acid and catechol provided highly heterotactic and syndiotactic poly(methacrylic acid)s, respectively. Highly heterotactic poly(4-vinyl pyridine) was obtained by forming the inclusion complex with4-vinyl pyridine and cyclodextrin derivatives. The hetrotactic polymers were novel materils.
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