2012 Fiscal Year Final Research Report
Solid-State Polymerization and Structure Control Based on Quinoid Compounds
| Project/Area Number |
22550110
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Mie University |
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Principal Investigator |
ITOH Takahito 三重大学, 大学院・工学研究科, 教授 (90126954)
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| Project Period (FY) |
2010 – 2012
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| Keywords | キノイド化合物 / 固相重合 / トポケミカル重合 / 結晶構造解析 / 分子間相互作用 / 置換基効果 / 不斉アニオン重合 |
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| Research Abstract |
Substituted quinoid compounds (substituted quinodimethanes, substituted quinone methides, substituted quinone methide imines) crystals and theircocrystals were prepared, and the relationship of the solid-state polymerization reactivity with the intermolecular interaction between molecules in the crystals was discussed on the basis of their single-crystal structure analyses and their products obtained by solid-state polymerizations. And also, novel substituted quinone methides were prepared, and their solid-state and solution polymerizations were investigated and control of the primary structure of obtained polymers was discussed.
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[Journal Article] Cis-Specific Topochemical Polymerization: Alternating Copolymerization of 7,7,8,8-tetrakis-(methoxycarbonyl)quinodimethane with 7,7,8,8-Tetracyanoquinodimethane in the Solid State2011
Author(s)
T. Itoh, T. Suzuki, T. Uno, M. Kubo, N. Tohnai, M. Miyata
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Journal Title
Angewndte ChemieInternational. Edition
Volume: 50
Pages: 1-6
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