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2012 Fiscal Year Final Research Report

Development of Transition Metal-Initiated Controlled Polymerization of Diazocarbonyl Compounds

Research Project

  • PDF
Project/Area Number 22550113
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionEhime University

Principal Investigator

IHARA Eiji  愛媛大学, 大学院・理工学研究科, 教授 (90243592)

Project Period (FY) 2010 – 2012
Keywords高分子合成 / ジアゾ酢酸エステル / パラジウム錯体触媒
Research Abstract

The researcher in this project has succeeded in establishing a new synthetic method for carbon-carbon main chain polymers. The objective of this project was development of a method for controlling the polymerization with respect to the molecular weight and stereo structure of the resulting polymers. By using certain initiators based on palladium complexes, the objective was achieved in a certain extent.

  • Research Products

    (11 results)

All 2013 2012 2011 2010 Other

All Journal Article (5 results) (of which Peer Reviewed: 3 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Pd-mediated Polymerization of Diazoacetates with Aromatic Ester Group: Synthesis and Photophysical Property of Poly(1-pyrenylmethoxycarbonylmethylene).2013

    • Author(s)
      Eiji Ihara, Ryoji Okada, Takanobu Sogai, Tetsuya Asano, Masami Kida, Kenzo Inoue, Tomomichi Itoh, Hiroaki Shimomoto, Yukihide Ishibashi, and Tsuyoshi Asahi.
    • Journal Title

      J. Poly. Sci., Part A: Polym. Chem.

      Volume: Vo l. 51 Pages: 1020-1023

    • DOI

      DOI:10.1002/pola.26480

    • Peer Reviewed
  • [Journal Article] π-AllylPdCl-based Initiating Systems for Polymerization of Alkyl Diazoacetates: Initiation and Termination Mechanism Based on Analysis of Polymer Chain End Structures.2012

    • Author(s)
      Eiji Ihara, Masaki Akazawa, Takashi Itoh, Mototaka Fujii, Kazuki Yamashita, Kenzo Inoue, Tomomichi Itoh, and Hiroaki Shimomoto.
    • Journal Title

      Macromolecules

      Volume: Vol. 45 Pages: 6869-6877

    • DOI

      DOI:10.1021/ma3013527

    • Peer Reviewed
  • [Journal Article] 遷移金属錯体を開始剤とするジアゾ酢酸エステルの重合2011

    • Author(s)
      井原栄治
    • Journal Title

      未来材料

      Volume: 11巻 Pages: 18-24

  • [Journal Article] Polymerization of Various Alkyl Diazoacetates Initiated with (N-Heterocyclic Carbene)Pd/Borate Systems.2011

    • Author(s)
      Eiji Ihara, Hiroki Takahashi, Masaki Akazawa, Tomomich Itoh, and Kenzo Inoue.
    • Journal Title

      Macromolecules

      Volume: Vol. 44 Pages: 3287-3292

    • DOI

      DOI:10.1021/ma200064b

    • Peer Reviewed
  • [Journal Article] ポリ(置換メチレン)合成:炭素-炭素結合を主鎖骨格とする高分子の新しい合成法2010

    • Author(s)
      井原栄治
    • Journal Title

      触媒

      Volume: 52巻 Pages: 575-581

  • [Presentation] Synthesis of Water-Soluble Poly(substituted methylene)s with hydroxy and oxyethylene groups by Palladium-Mediated Polymerization of Diazocarbonyl Compounds.2012

    • Author(s)
      Hiroaki Shimomoto (Eiji Ihara)
    • Organizer
      The 9th SPSJ International Polymer Conference (IPC2012)
    • Place of Presentation
      Kobe
    • Year and Date
      2012-12-14
  • [Presentation] π-アリルパラジウムクロリドを開始剤とするジアゾ酢酸エステルの重合/ー末端構造解析による重合開始・停止機構の解析ー.2012

    • Author(s)
      居藤崇志(井原栄治)
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-21
  • [Presentation] Pd錯体開始剤系によるオリゴエチレングリコール鎖を有するジアゾ酢酸エステルの重合2012

    • Author(s)
      清水康太(井原栄治)
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-19
  • [Presentation] 水酸基を保護したジアゾ酢酸2-ヒドロキシエチルの重合と得られるポリマーの脱保護2012

    • Author(s)
      伊藤絵里加(井原栄治)
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-19
  • [Presentation] Pd錯体を開始剤とするジアゾ酢酸エステルの重合によるポリ(置換メチレン)合成2012

    • Author(s)
      井原栄治
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-19
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/~achem/poly/

URL: 

Published: 2014-08-29  

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