2012 Fiscal Year Final Research Report
Development of Novel Amphiphilic Polymers for the Promotion of Oxidation Reactions in Aqueous Media
| Project/Area Number |
22550115
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Osaka Institute of Technology |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KOBAYASHI Shoji 大阪工業大学, 工学部, 講師 (30374903)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 機能性高分子 / グリーンケミストリー / Oxone / 酸化反応 / エポキシ化反応 / 両親媒性樹脂 / 水媒質中の有機反応 |
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| Research Abstract |
New amphiphilic cross-linked polystyrene-based copolymersbearing carbonyl groups in the grafted chains of the copolymers were designed andprepared. These copolymer-resins were significantly effective as reaction sites to promotethe epoxidation reactions of various alkenes by Oxone inside their polymer matrices inwater. The optimum structure of the copolymers and the optimum reaction conditions wereestablished. Through this research project, we can propose new highly secure methodologyfor oxidation reaction in aqueous media.
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