2012 Fiscal Year Final Research Report
Synthesis and Cyanide Ion Recognition of Water Soluble Receptors
| Project/Area Number |
22550116
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
ITO Kazuaki 山形大学, 大学院・理工学研究科, 教授 (80250950)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 分子認識 |
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| Research Abstract |
Diacylcarbohydrazide derivatives were synthesized and their anion binding properties were investigated by using UV-vis spectroscopy in MeOH and MeOH/H_2O. Diacylcarbohydrazide derivatives selectively recognized cyanide anion through reversible formation of anion-receptor adducts that stabilized by intramolecular hydrogen bondings. The carbohydrazide derivatives bearing a aliphatic moieties were synthesized and the derivatives showed good gelation ability for various organic solvents. SEM study reveals that fiber-like or sheet-like network were gained from self-assmblingof carbohydrazide derivatives. Based on VT-NMR and IR spectral absorption investigations, the gel materials were generated from self-assembly by cooperative H-bonding and van der Waals. An organo gel of the derivatives became a homogeneous solution in response to the addition of cyanide anions.
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Research Products
(3 results)
