2012 Fiscal Year Final Research Report
Asymmetric electrochemical polymerization with cholesteric liquid crystals and interference light electrochromism
Project/Area Number |
22550161
|
Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials/Devices
|
Research Institution | University of Tsukuba |
Principal Investigator |
GOTO Hiromasa 筑波大学, 数理物質系, 准教授 (40292528)
|
Project Period (FY) |
2010 – 2012
|
Keywords | キラル / コレステリック液晶 / ポーラロン / 光学活性エレクトロクロミズム / 吸収スペクトル / 回折 / 干渉 / 電解重合 |
Research Abstract |
Chiral liquid crystal electrolyte solution was prepared, and electrochemical synthesis of conjugated polymers were carried out. Furthermore, polymers with diffraction properties were obtained by electrochemical polymerization in chiral liquid crystals, and smectic A. Opticalproperties of the polymers were examined. Through this study, "elective reflection light electrochromism" was established. Next, electrochemical polymerization in crystals, and phase transition sequential polymerization were developed. Metallic reflection electrochromism phenomenon was confirmed.
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