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2012 Fiscal Year Final Research Report

Development offast-responsive conductivepolymer actuators electrically driven in air

Research Project

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Project/Area Number 22550192
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

OKUZAKI Hidenori  山梨大学, 大学院・医学工学総合研究部, 准教授 (60273033)

Project Period (FY) 2010 – 2012
Keywords高分子機能材料
Research Abstract

Free-standing films made of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT/PSS) with various PSS composition ratios were prepared by casting water dispersion of the PEDOT/PSS colloidal particles in the presence of an extra PSS. The maximum contraction of the film by application of an electric field increased with increasing both PSS composition ratio and relative humidity (RH), where the value attained 7% for the film with 93% of PSS at 70 %RH. Since the isothermal sorption curve of the film was less dependent on the PSS content, the significant increase of the film contraction was explained by two mechanisms: (i) the extra PSS prevented from hydrogen bonding between the adjacent PEDOT/PSS particles that suppressed dimensional changes of the film; (ii) the higher the RH, the larger the water content sorbed in the film.

  • Research Products

    (53 results)

All 2013 2012 2011 2010 Other

All Journal Article (10 results) (of which Peer Reviewed: 4 results) Presentation (37 results) Book (4 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Organic Robotics Based on Conducting Polymers2013

    • Author(s)
      H. Okuzaki
    • Journal Title

      Advances in Science and Technology

      Volume: 79 Pages: 87-93

  • [Journal Article] 最新ユニークゲルの機能と設計2012

    • Author(s)
      奥崎秀典
    • Journal Title

      ファインケミカル

      Volume: 41 Pages: 5

  • [Journal Article] 伸縮性と高導電性を有する高分子フィルムの開発2012

    • Author(s)
      奥崎秀典
    • Journal Title

      OHM

      Volume: 99 Pages: 8-9

  • [Journal Article] 伸縮性と高導電性を両立した高分子フィルムの開発〈アラビトール添加によるPEDOT/PSSの高機能化〉2012

    • Author(s)
      李悦忱,堀井辰衛,奥崎秀典
    • Journal Title

      プラスチックス

      Volume: 3 Pages: 11-16

  • [Journal Article] Synthesis and Characterization of Highly Conductive PEDOT/PSS Colloidal Gels2012

    • Author(s)
      T. Horii, H. Hikawa, Y. Mochizuki, H. Okuzaki
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 37 Pages: 515-518

    • Peer Reviewed
  • [Journal Article] Effect of pH on Structure and Conductivity of PEDOT/PSS2012

    • Author(s)
      Y. Mochizuki, T. Horii, H. Okuzaki
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 37 Pages: 307-310

    • Peer Reviewed
  • [Journal Article] Stretchable and Highly Conductive Polymer Films2012

    • Author(s)
      Y. Li, Y. Masuda, Y. Iriyama, H. Okuzaki
    • Journal Title

      Trans. Mater. Res. Soc. Jpn.

      Volume: 37 Pages: 303-306

    • Peer Reviewed
  • [Journal Article] PEDOT/PSSの高導電化と電子デバイスへの応用2011

    • Author(s)
      奥崎秀典
    • Journal Title

      表面科学

      Volume: 32 Pages: 653-658

  • [Journal Article] Effect of Ethylene Glycol on Structure and Carrier Transport in Highly Conductive Poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate)2011

    • Author(s)
      Murakami, Y. Mori, H. Okuzaki
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 36 Pages: 165-168

    • Peer Reviewed
  • [Journal Article] Electrically Driven PEDOT/PSS Actuators, Proceeding of SPIE2010

    • Author(s)
      H. Okuzaki
    • Journal Title

      Smart Structures and Materials & Nondestructive Evaluation and Health Monitoring

      Volume: 7672 Pages: 1-7

  • [Presentation] PEDOT/PSSの合成と高導電化2013

    • Author(s)
      奥崎秀典
    • Organizer
      2012年度第3回機能性高分子コンデンサ研究会
    • Place of Presentation
      ホテル鷺乃湯
    • Year and Date
      2013-03-29
  • [Presentation] 導電性高分子を用いた新規EAP アクチュエータ2013

    • Author(s)
      奥崎秀典
    • Organizer
      Electro-Active Polymer (EAP) 研究シンポジウム ~フラウンホーファー・産総研共同研究キックオフ~
    • Place of Presentation
      梅田スカイビル
    • Year and Date
      2013-03-19
  • [Presentation] PEDOT/PSSの高導電化と透明導電膜への応用2013

    • Author(s)
      奥崎秀典
    • Organizer
      第18回シンポジウム「各種透明導電膜の特徴と製膜技術」
    • Place of Presentation
      文京シビックセンター
    • Year and Date
      2013-02-25
  • [Presentation] Ito, PEDOT/PSS Films as Electrically Driven Actuators2012

    • Author(s)
      H. Okuzaki, K. Hosaka, T.
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Hawaii
    • Year and Date
      2012-12-19
  • [Presentation] Conducting Polymers as Electromechanical Transducers2012

    • Author(s)
      H. Okuzaki
    • Organizer
      The 9th SPSJ International Polymer Conference (IPC 2012)
    • Place of Presentation
      Kobe
    • Year and Date
      2012-12-13
  • [Presentation] PEDOT/PSS Gel Actuators Electrically Driven in Air2012

    • Author(s)
      S. Endo, H. Okuzaki
    • Organizer
      Gelsympo 2012
    • Place of Presentation
      Tsukuba
    • Year and Date
      2012-10-09
  • [Presentation] Basic Gel Materials Science2012

    • Author(s)
      H. Okuzaki
    • Organizer
      Gelsympo 2012
    • Place of Presentation
      Tsukuba
    • Year and Date
      2012-10-09
  • [Presentation] PEDOT/PSS Actuators Electrically Driven in Air2012

    • Author(s)
      S. Endo, H. Okuzaki
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] Electroactive Polymer Actuators Utilizing PEDOT/PSS2012

    • Author(s)
      H. Okuzaki
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] Synthesis of Highly Conductive PEDOT/PSS Colloidal Dispersion2012

    • Author(s)
      T. Horii, H. Hikawa, H. Okuzaki
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] Effect of pH on Structure and Conductivity of PEDOT/PSS2012

    • Author(s)
      Y. Mochizuki, H. Okuzaki
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] Effect of Composition Ratio on Structure and Conductivity of PEDOT/PSS2012

    • Author(s)
      H. Hikawa, T. Horii, H. Okuzaki
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] Hierarchical Structure and Electrical Conductivity of PEDOT/PSS2012

    • Author(s)
      H. Okuzaki
    • Organizer
      IUMRS-ICEM 2012
    • Place of Presentation
      Yokohama
    • Year and Date
      2012-09-24
  • [Presentation] 高導電性PEDOT/PSSディスパージョンの合成2012

    • Author(s)
      堀井辰衛,樋川英江,勝沼将人,李悦忱,奥崎秀典
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      2012-09-19
  • [Presentation] PEDOT/PSSの階層構造制御による高導電化2012

    • Author(s)
      奥崎秀典
    • Organizer
      第73回応用物理学会学術講演会
    • Place of Presentation
      松山大学
    • Year and Date
      2012-09-11
  • [Presentation] Hierarchcal Structure and Electrical Conductivity of PEDOT/PSS2012

    • Author(s)
      H. Okuzaki
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM2012)
    • Place of Presentation
      Atlanta
    • Year and Date
      2012-07-09
  • [Presentation] 空気中で電場駆動するPEDOT/PSSアクチュエータ-組成比の効果2012

    • Author(s)
      遠藤悟,奥崎秀典
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
  • [Presentation] 高導電性PEDOT/PSSの合成-分子量の効果-2012

    • Author(s)
      堀井辰衛,樋川英江,奥崎秀典
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
  • [Presentation] 高導電性PEDOT/PSSの合成-組成比の効果-2012

    • Author(s)
      樋川英江,堀井辰衛,奥崎秀典
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2012-05-29
  • [Presentation] 導電性高分子ディスパージョンの階層構造とデバイス応用2012

    • Author(s)
      奥崎秀典
    • Organizer
      誘電・絶縁材料研究会
    • Place of Presentation
      産総研九州センター
    • Year and Date
      2012-02-17
  • [Presentation] 導電性高分子ミクロゲルの合成と階層構造2012

    • Author(s)
      樋川英江,堀井辰衛,奥崎秀典
    • Organizer
      第23回高分子ゲル研究討論会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-01-11
  • [Presentation] 導電性高分子PEDOT/PSSゲルのアクチュエータ特性2012

    • Author(s)
      遠藤悟,奥崎秀典
    • Organizer
      第23回高分子ゲル研究討論会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-01-11
  • [Presentation] PEDOT/PSSの合成と高導電化2011

    • Author(s)
      堀井辰衛,樋川英江,奥崎秀典
    • Organizer
      第21回日本MRS学術シンポジウム2011
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-20
  • [Presentation] Role and Effect of Poly(4-styrenesulfonic acid) on Humido-Sensitive EAP Actuators, 6th World Congress on Biomimetics2011

    • Author(s)
      H. Okuzaki
    • Organizer
      Artificial Muscles, and Nano-Bio
    • Place of Presentation
      Paris
    • Year and Date
      2011-10-27
  • [Presentation] PEDOT/PSS の合成と高導電化2011

    • Author(s)
      堀井辰衛,樋川英江,奥崎秀典
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-28
  • [Presentation] Electro-Active Polymer Actuators Utilizing PEDOT/PSS2011

    • Author(s)
      H. Okuzaki
    • Organizer
      14th Asian Chemical Congress (14 ACC)
    • Place of Presentation
      Bangkok
    • Year and Date
      2011-09-07
  • [Presentation] PEDOT/PSSの合成と高導電化2011

    • Author(s)
      堀井辰衛,樋川英江,奥崎秀典
    • Organizer
      日本化学会 第5回関東支部大会
    • Place of Presentation
      東京農工大学
    • Year and Date
      2011-08-30
  • [Presentation] PEDOT/PSSの高導電化とデバイス応用2011

    • Author(s)
      奥崎秀典
    • Organizer
      グローバルCOE特別講演会
    • Place of Presentation
      信州大学
    • Year and Date
      2011-08-03
  • [Presentation] 機能性有機材料の加工技術と有機デバイスへの応用2011

    • Author(s)
      奥崎秀典
    • Organizer
      将来加工技術第136委員会 第15回(合同)研究会
    • Place of Presentation
      弘済会館
    • Year and Date
      2011-07-29
  • [Presentation] PEDOT/PSS AS A Novel EAP Actuator2011

    • Author(s)
      H. Okuzaki
    • Organizer
      75th Prague Meeting on Macromolecules
    • Place of Presentation
      Prague
    • Year and Date
      2011-07-12
  • [Presentation] PEDOT/PSSの高導電化とデバイスへの応用2011

    • Author(s)
      奥崎秀典
    • Organizer
      有機エレクトロニクス研究会
    • Place of Presentation
      化学会館
    • Year and Date
      2011-07-01
  • [Presentation] 導電性高分子ディスパージョンの高導電化と有機エレクトロニクスへの応用2011

    • Author(s)
      奥崎秀典
    • Organizer
      10-2高分子基礎物性研究会(伝導性ポリマーの構造と機能)
    • Place of Presentation
      東京大学
    • Year and Date
      2011-03-04
  • [Presentation] PEDOT/PSSの高導電化と有機エレクトロニクスへの応用2010

    • Author(s)
      奥崎秀典
    • Organizer
      第20回日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2010-12-21
  • [Presentation] Novel EAP Actuators utilizing PEDOT/PSS2010

    • Author(s)
      K. Hosaka, T. Ito, H. Okuzaki
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Hawaii
    • Year and Date
      2010-12-19
  • [Presentation] Ito, Electromechanical Properties of Humido-Sensitive Conducting Polymers2010

    • Author(s)
      H. Okuzaki, K. Hosaka, T
    • Organizer
      The 11th International Chemistry Conference and Exhibition in Africa (11 ICCA)
    • Place of Presentation
      Egypt
    • Year and Date
      2010-11-20
  • [Presentation] PEDOT/PSS Bending Actuators2010

    • Author(s)
      T. Ito, K. Hosaka, H. Okuzaki
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM2010)
    • Place of Presentation
      Kyoto
    • Year and Date
      2010-07-06
  • [Presentation] Ito, Electrically Driven PEDOT/PSS Actuators2010

    • Author(s)
      H. Okuzaki, K. Hosaka, T
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM2010)
    • Place of Presentation
      Kyoto
    • Year and Date
      2010-07-05
  • [Book] 有機電子デバイスのための導電性高分子の物性と評価2012

    • Author(s)
      奥崎秀典
    • Publisher
      シー・エム・シー
  • [Book] PEDOTの材料物性とデバイス応用2012

    • Author(s)
      奥崎秀典
    • Publisher
      サイエンス&テクノロジー
  • [Book] PEDOTの特性・合成手法とデバイス応用2011

    • Author(s)
      奥崎秀典
    • Publisher
      情報機構
  • [Book] 未来を動かすソフトアクチュエータ2010

    • Author(s)
      奥崎秀典
    • Publisher
      シー・エム・シー
  • [Remarks]

    • URL

      http://www.ccn.yamanashi.ac.jp/~okuzaki/okuzaki.html

  • [Patent(Industrial Property Rights)] 導電性高分子材料及び導電性高分子材料の製造方法2010

    • Inventor(s)
      奥崎秀典
    • Industrial Property Rights Holder
      国立大学法人山梨大学
    • Industrial Property Number
      特願2010-189097
    • Filing Date
      2010-08-26

URL: 

Published: 2014-08-29  

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