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2012 Fiscal Year Final Research Report

Approach to the Understanding of Hydrogen Embrittleness of Steels Using Energy Expression of the Chemical Bond and Its Application to Quantum Alloy Design

Research Project

  • PDF
Project/Area Number 22560658
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionNagoya University

Principal Investigator

MORINAGA Masahiko  名古屋大学, 大学院・工学研究科, 名誉教授 (50126950)

Co-Investigator(Kenkyū-buntansha) YUKAWA Hiroshi  名古屋大学, 大学院・工学研究科, 助教 (50293676)
YOSHINO Masahito  名古屋大学, 大学院・工学研究科, 助教 (10397466)
Project Period (FY) 2010 – 2012
Keywords水素脆化 / 量子材料設計 / 化学結合 / 鉄鋼材料 / 昇温脱離
Research Abstract

Atomization energy analysis is proposed for treating the chemical bond in steels in an energy scale in order to understand the hydrogen embrittleness in view of the chemical bond. Following this analysis, the hydrogen trapping effect is understood by estimating the nature of the chemical bond between hydrogen (H) and non-metal elements (e.g., C) or alloying elements (e.g.,Cr) in steels. Also, the trend of the hydrogen trapping around metal carbides (e.g., VC) in steels is predictable approximately along this analysis. This is confirmed experimentally through the hydrogen trapping test in pure metal carbides by using the ball-milling in a hydrogen atmosphere. Such information is useful for the quantum design of steels against hydrogen embrittleness.

  • Research Products

    (14 results)

All 2013 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 4 results) Presentation (5 results) Remarks (2 results)

  • [Journal Article] DV-Xα法による合金設計2012

    • Author(s)
      森永正彦
    • Journal Title

      DV-Xα研究協会会報

      Volume: 25 Pages: 3-9

  • [Journal Article] Energy Expression of the Chemical Bond between Atoms in Metal Oxides2011

    • Author(s)
      Y. Shinzato, Y.Saito, M. Yoshino, H.Yukawa, M.Morinaga, T.Baba and H.Nakai
    • Journal Title

      J. Phys. Chem. Solids

      Volume: 72 Pages: 853-861

    • Peer Reviewed
  • [Journal Article] Role of O-H Bonding in Catalytic Activity of Nb_2O_5 during the Course of Dehydrogenation of MgH_22011

    • Author(s)
      H.Hirate, H.Sawai, H.Yukawa and M.Morinaga
    • Journal Title

      International Journal of Quantum Chemistry

      Volume: 111 Pages: 2251-2257

    • Peer Reviewed
  • [Journal Article] Atomization Energy Approach to the Understanding of the Chemical Bond between Atoms in 3d Transition-Metal Based Compounds2011

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, H. Yukawa, M.Yoshino and H. Nakai
    • Journal Title

      DV-Xα研究協会会報

      Volume: 24 Pages: 85-91

  • [Journal Article] Quantitative Evaluation of Catalytic Effect of Metal Chlorides on the Desorption Reaction of NaAlH_42010

    • Author(s)
      H.Hirate, Y.Saito, I.Nakaya, I. Nakaya, H.Sawai, H.Yukawa, M.Morinaga and H.Nakai
    • Journal Title

      International Journal of Quantum Chemistry

      Volume: 111 Pages: 950-960

    • Peer Reviewed
  • [Journal Article] Unusual Energy Balance Between Atoms in Postperovskite MgSiO_32010

    • Author(s)
      H.Hirate, H.Sawai, Y.Saito, H.Yukawa, M.Morinaga and H.Nakai
    • Journal Title

      J. Am. Ceram. Soc.

      Volume: 93 Pages: 3449-3454

    • Peer Reviewed
  • [Journal Article] Electronic Approach to Alloy Design2010

    • Author(s)
      M. Morinaga
    • Journal Title

      DV-Xα研究協会会報

      Volume: 23 Pages: 39-45

  • [Presentation] NbC およびNb_2O_5にトラップされた水素の昇温脱離法による安定性の評価2013

    • Author(s)
      吉野正人、酒井智康、中嶋一重、谷本憲哉、湯川宏、森永正彦、渡邊真太、山田智明、長崎正雅、
    • Organizer
      日本金属学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2013-03-29
  • [Presentation] Energy Expression of the Chemical Bond between Atoms in 3d Transition Metal-based Compounds2012

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, M.Yoshino, H. Yukawa and H. Nakai
    • Organizer
      The 5th International Symposium on Designing, Processing and Properties of Advanced Engineering Materials (ISAEM-2012)
    • Place of Presentation
      Loisir Hotel Toyohashi
    • Year and Date
      2012-11-06
  • [Presentation] DV-Xα法による合金設計2012

    • Author(s)
      森永正彦(DV-Xα研究協会・協会賞受賞)
    • Organizer
      DV-Xα研究会
    • Place of Presentation
      福岡大学
    • Year and Date
      2012-08-07
  • [Presentation] Atomization Energy Approach to the Understanding of the Chemical Bond between Atoms in 3d Transition-Metal Based Compounds2011

    • Author(s)
      M. Morinaga, Y. Saito, K. Ito, H. Yukawa, M.Yoshino and H. Nakai
    • Organizer
      DV-Xα研究会
    • Place of Presentation
      静岡大学
    • Year and Date
      2011-08-09
  • [Presentation] Electronic Approach to Alloy Design2010

    • Author(s)
      M. Morinaga
    • Organizer
      DV-Xα法国際会議
    • Place of Presentation
      韓国基礎科学研究支援院(韓国)
    • Year and Date
      2010-08-06
  • [Remarks]

    • URL

      http://sigma.numse.nagoya-u.ac.jp

  • [Remarks]

    • URL

      http://www.toyotariken.jp

URL: 

Published: 2014-08-29  

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