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2012 Fiscal Year Final Research Report

Design and Development of Highly-functionalized Solid Catalysts for Construction of Biomass Utilization Process

Research Project

  • PDF
Project/Area Number 22560764
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionJapan Advanced Institute of Science and Technology

Principal Investigator

EBITANI Kohki  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 教授 (50242269)

Project Period (FY) 2010 – 2012
Keywords固体触媒 / バイオマス / 再資源化 / 固体酸触媒 / 固体塩基触媒 / 還元反応 / 酸化反応
Research Abstract

In this research project, various types of solid catalysts such as supported metal nanoparticles, solid acid, and layered clay compounds, were developed for converting inedible bimomass-derivatives into useful raw materials of polymers and fuels. The reactions were performed under mild conditions using 1atm oxygen in water solvent at temperatures around 100oC. Urthermore, heterogeneous catalysts were combined for one-pot conversions of sugars into frufurals without isolation and purification of the reaction intermediates.

  • Research Products

    (44 results)

All 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (33 results) Remarks (2 results)

  • [Journal Article] Synthesis of alpha-amino acids from glucosamine-HCl and its derivatives by aerobic oxidation in water catalyzed by Au nanoparticles on basic supports2013

    • Author(s)
      Y. Ohmi, S. Nishimura, K. Ebitani
    • Journal Title

      in press

    • DOI

      DOI:10.1002/cssc.201300303

    • Peer Reviewed
  • [Journal Article] Metal-free oxidative synthesis of succinic acid from biomass-derived furan compounds using a solid acid catalyst with hydrogen peroxide2013

    • Author(s)
      H. Choudhary, S. Nishimura, K. Ebitani
    • Journal Title

      Applied Catalysis: A: General

      Volume: 458 Pages: 55-62

    • Peer Reviewed
  • [Journal Article] Role of Negatively Charged Au State in Aerobic Oxidation of lcohols over Hydrotalcite Supported AuPd Nanoclusters2013

    • Author(s)
      S. Nishimura, Y. Yakita, M. Katayama, K. Higashimine, K. Ebitani
    • Journal Title

      Catalysis Science and Technology

      Volume: 3 Pages: 351-359

    • Peer Reviewed
  • [Journal Article] Hydrotalcite-Supported Platinum Nanoparticles Prepared by Green Synthesis Method for Selective Oxidation of Glycerol in Water Using Molecular Oxygen2012

    • Author(s)
      D. Tongsakul, S. Nishimura, C. Thammacharoen, S. Ekgasit, K. Ebitani
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 51 Pages: 16182-16187

    • Peer Reviewed
  • [Journal Article] Synthesis of Levulinic Acid from Fructose Using Amberlyst-15 as a Solid Acid Catalyst2012

    • Author(s)
      P. A. Son, S. Nishimura, K. Ebitani
    • Journal Title

      React. Kinet., Mech. Catal..

      Volume: 106 Pages: 185-192

    • Peer Reviewed
  • [Journal Article] Highly efficient aqueous oxidation of furfural to succinic acid using reusable heterogeneous acid catalyst with hydrogen peroxide2012

    • Author(s)
      H. Choudhary, S. Nishimura, K. Ebitani
    • Journal Title

      Chemistry Letters

      Volume: 4 Pages: 409-411

    • Peer Reviewed
  • [Journal Article] One-pot Synthesis of Furans from Various Saccharides using Combination of Solid Acid and Base Catalysts2012

    • Author(s)
      J. Tutejya, S. Nishimura, K. Ebitani
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 85 Pages: 275-281

    • Peer Reviewed
  • [Journal Article] Promotion effect of coexistent hydromagnesite in a highly active solid base hydrotalcite catalyst for transesterifications of glycols into cyclic carbonates2012

    • Author(s)
      A. Kumar, K. Iwatani, S. Nishimura, A. Takagaki, K. Ebitani
    • Journal Title

      Catalysis Today

      Volume: 185 Pages: 241-246

    • Peer Reviewed
  • [Journal Article] Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals2012

    • Author(s)
      A. Takagaki, S. Nishimura, K. Ebitani
    • Journal Title

      Catalysis Surveys from Asia

      Volume: 16 Pages: 164-182

    • Peer Reviewed
  • [Presentation] One-Pot Conversions of Sugars into Furfurals and Sugar Alcohols Using Heterogeneous Catalysts2013

    • Author(s)
      K. Ebitani, S. Dabral, J. Tuteja, S. Nishimura
    • Organizer
      7th International Symposium on Acid-Base Catalysis (ABC-7)
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-14
  • [Presentation] Preparation of Zirconium Carbonate as Solid Base Catalyst for Aqueous Glucose-Fructose Isomerization and One-pot Conversion into Levulinic Acid2013

    • Author(s)
      P. A. Son, S. Nishimura, K. Ebitani
    • Organizer
      7th International Symposium on Acid-Base Catalysis (ABC-7)
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-14
  • [Presentation] Synthesis of Biomass-derived Organic Acids from Furan compounds in Aqueous Media with Heterogeneous Acid Catalyst2013

    • Author(s)
      S. Nishimura, H. Choudhary, P. A. Son, K. Ebitani
    • Organizer
      7th International Symposium on Acid-Base Catalysis (ABC-7)
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-14
  • [Presentation] One-Pot Synthesis of Furfural Derivatives from Pentoses Using Solid Acid and Base Catalysts2013

    • Author(s)
      M. Shirotori, S. Nishimura, K. Ebitani
    • Organizer
      7th International Symposium on Acid-Base Catalysis (ABC-7)
    • Place of Presentation
      Tokyo
    • Year and Date
      2013-05-14
  • [Presentation] Effects of Preparation Methods and Electronic States of the AuPd Bimetallic Nanoparticles on the Activity for Aerobic Oxidation of Alcohols2013

    • Author(s)
      S. Nishimura, Y. Yakita, M. Katayama, K. Higashimine, K. Ebitani
    • Organizer
      TechConnect World Conference and Expo 2013
    • Place of Presentation
      Maryland, Washington, D.C., U.S.A.
    • Year and Date
      2013-05-13
  • [Presentation] アルコール選択酸化反応を用いたAuPd バイメタルナノ粒子の特異的な触媒作用の評価2013

    • Author(s)
      西村 俊, 高橋貴正, 焼田悠介, 海老谷 幸喜
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学, 大阪府
    • Year and Date
      2013-03-26
  • [Presentation] 金ナノ粒子担持固体塩基触媒を用いた水中でのアミ糖類選択的酸化反応2013

    • Author(s)
      大見 陽太郎, 西村 俊, 海老谷 幸喜
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学, 大阪府
    • Year and Date
      2013-03-26
  • [Presentation] 固体触媒技術を用いたバイオマス由来物質の再資源化反応2013

    • Author(s)
      海老谷 幸喜
    • Organizer
      日本化学会第93 春季年会(ATP セッション)
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] AuPd バイメタルナノ粒子を触媒とするアルコール酸化反応における電子移動効果2013

    • Author(s)
      西村 俊, 焼田悠介, 片山まどか, 東嶺孝一, 海老谷 幸喜
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] 多元金属ナノ粒子の物理化学的特性とアルコール酸化反応活性2013

    • Author(s)
      高橋貴正, 西村 俊, 海老谷 幸喜
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] High selectivity of hydrotalcite supported-platinum/gold alloy nanoparticle catalysts for aerobic oxidation of polyols under base-free and atmospheric conditions2013

    • Author(s)
      D. Tongsakul, 西村 俊, 海老谷 幸喜
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] 不均一系パラジウム触媒を使用した糖類からの2,5-ジメチルフランの合成2013

    • Author(s)
      池田直也, 西村 俊, 海老谷 幸喜
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] 固体酸・塩基触媒を用いた五炭糖からのフルフラール誘導体のワンポット合成2013

    • Author(s)
      城取万陽, 西村 俊, 海老谷 幸喜
    • Organizer
      第93回日本化学会春季年会
    • Place of Presentation
      立命館大学, 滋賀県
    • Year and Date
      2013-03-23
  • [Presentation] One-pot conversion of sugars to furans by combination of heterogeneous acid and base catalysts2013

    • Author(s)
      J. Tuteja, S. Nishimura, K. Ebitani
    • Organizer
      Pure and Applied Chemistry International Conference 2013 (PACCON2013)
    • Place of Presentation
      Chon Buri, Thailand
    • Year and Date
      2013-01-24
  • [Presentation] 多元金属ナノ粒子の調製とその触媒作用2012

    • Author(s)
      高橋貴正, 西村 俊, 海老谷 幸喜
    • Organizer
      平成24 年度日本化学会北陸地区講演会と研究発表会
    • Place of Presentation
      福井, 福井県
    • Year and Date
      2012-11-17
  • [Presentation] 固体触媒を用いた糖類からの2,5-ジメチルフランの合成2012

    • Author(s)
      池田直也, 西村 俊, 海老谷 幸喜
    • Organizer
      平成24 年度日本化学会北陸地区講演会と研究発表会
    • Place of Presentation
      福井, 福井県
    • Year and Date
      2012-11-17
  • [Presentation] One-pot Synthesis of Furan Derivatives and Sugar alcohols From Raffinose Using Heterogeneous Catalysts2012

    • Author(s)
      S. Dabral, S. Nishimura, K. Ebitani
    • Organizer
      The Irago Conference (AP-IRC 2012)
    • Place of Presentation
      Tahara, Aichi
    • Year and Date
      2012-11-15
  • [Presentation] Selective and base-free aerobic oxidation of 1,3-propanediol to 3-hydroxypropanoic acid using heterogeneous catalyst in aqueous media2012

    • Author(s)
      M. Mohammad, S. Nishimura, K. Ebitani
    • Organizer
      The Irago Conference (AP-IRC 2012)
    • Place of Presentation
      Tahara, Aichi
    • Year and Date
      2012-11-15
  • [Presentation] Green oxidation of furan carbonyls over heterogeneous catalyst in aqueous media2012

    • Author(s)
      H. Choudhary, S. Nishimura, K. Ebitani
    • Organizer
      10th International Congress of Young Chemists (YoungChem 2012)
    • Place of Presentation
      Gdansk, Poland
    • Year and Date
      2012-10-10
  • [Presentation] AuPd ナノクラスター担持触媒の電子状態とアルコール酸化反応における触媒作用2012

    • Author(s)
      西村 俊, 焼田悠介, 片山まどか, 東嶺孝一, 海老谷 幸喜
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学, 福岡県
    • Year and Date
      2012-09-25
  • [Presentation] Development of catalytic systems for transformations of biomass-derived materials into value-added chemicals2012

    • Author(s)
      K. Ebitani
    • Organizer
      Japan-India workshop on "Development of sustainable catalytic reaction system using carbon dioxide and water"
    • Place of Presentation
      Sendai, 宮城県
    • Year and Date
      2012-05-28
  • [Presentation] アルコールのクロスカップリング反応によるアリルフェニルエーテル合成を目指した不均一系Pd触媒の開発2012

    • Author(s)
      松尾 仁史, 西村 俊, 海老谷 幸喜
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-26
  • [Presentation] 金担持ハイドロタルサイト触媒を用いた水中でのグルコサミン塩酸塩の選択的酸化反応によるグルコサミン酸の合成2012

    • Author(s)
      大見陽太郎, 西村 俊, 海老谷 幸喜
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-26
  • [Presentation] AuPd バイメタルナノ粒子触媒の電子状態とアルコール酸化反応活性2012

    • Author(s)
      焼田悠介, 西村 俊, 海老谷 幸喜
    • Organizer
      第92回日本化学会春季年会
    • Place of Presentation
      神奈川
    • Year and Date
      2012-03-26
  • [Presentation] Pt/Au Bimetallic Nanoparticles Supported onto Hydtolciute Surface as Heterogeneous Catalyst for Selective Oxidation of Glycerol Synthesized via Green Chemistry2011

    • Author(s)
      D. Tongsakul, S. Nishimura, C. Thammacharoen, S. Ekgasit, K. Ebitani
    • Organizer
      14th Asian Chemical Congress 2011
    • Place of Presentation
      Bankok, Thailand
    • Year and Date
      20110905-08
  • [Presentation] One-pot Conversion of Saccharides to Furfurals over Combination of Solid acid-base Catalysts2011

    • Author(s)
      J. Tuteja, S. Nishimura, K. Ebitani
    • Organizer
      The Asia-Pacific Interdisciplinary Research Conference 2011 (APIRC 2011)
    • Place of Presentation
      Toyohashi University of Technology, Japan
    • Year and Date
      2011-11-17
  • [Presentation] Green oxidation of furfural to succinic acid using hydrogen peroxide in the presence of heterogeneous catalyst in aqueous medium2011

    • Author(s)
      H. Choudhary, S. Nishimura, K. Ebitani
    • Organizer
      The Asia-Pacific Interdisciplinary Research Conference 2011 (APIRC 2011)
    • Place of Presentation
      Toyohashi University of Technology, Japan
    • Year and Date
      2011-11-17
  • [Presentation] 異なる構造のAuPd バイメタルナノ粒子を担持したハイドロタルサイト触媒によるアルコールの選択酸化反応2011

    • Author(s)
      焼田悠介, 西村 俊, 海老谷 幸喜
    • Organizer
      第41回石油・石油化学討論会
    • Place of Presentation
      山口
    • Year and Date
      2011-11-10
  • [Presentation] Green synthesis of platinum/gold bimetallic nano- particles supported onto hydrotalcite surface as heterogeneous catalyst for selective oxidation of glycerol2011

    • Author(s)
      D. Tongsakul, S. Nishimura, C. Thammacharoen; S. Ekgasit, K. Ebitani
    • Organizer
      2011 AIChE Annual Meeting
    • Place of Presentation
      Minneapolis, Minnesota, USA
    • Year and Date
      2011-10-17
  • [Presentation] Au-Pd バイメタルナノ粒子を担持したハイドロタルサイト触媒によるアルコールの選択酸化反応2011

    • Author(s)
      焼田悠介, 西村 俊, 海老谷 幸喜
    • Organizer
      第108回触媒討論会
    • Place of Presentation
      北見工業大学, 北海道
    • Year and Date
      2011-09-21
  • [Presentation] フルクトースの脱水反応を用いた参照固体酸触媒の評価に関する検討2011

    • Author(s)
      武末侑希, 西村 俊, 海老谷 幸喜
    • Organizer
      触媒学会第32回参照触媒討論会
    • Place of Presentation
      北見工業大学, 北海道
    • Year and Date
      2011-09-19
  • [Presentation] Selective Oxidation of 5-Hydroxymethylfurfural using Hydrotalcite- supported Metal Catalysts under Atmospheric Oxygen Pressure2011

    • Author(s)
      S. Nishimura, M. Takahashi, N. K. Gupta, A. Takagaki, K. Ebitani
    • Organizer
      13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-05-25
  • [Presentation] Highly Active Hydrotalcite Catalyst for Cyclic Carbonates Synthesis via Transesterification of Alcohols with Dialkyl Carbonates2011

    • Author(s)
      S. Nishimura, A. Kumar, K. Iwatani, A. Takagaki, K. Ebitani
    • Organizer
      13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2011-05-25
  • [Remarks] 最近の研究業績(日本語)

    • URL

      http://www.jaist.ac.jp/~ebitani/conj.htm

  • [Remarks] 最近の研究業績(英語)

    • URL

      http://www.jaist.ac.jp/~ebitani/cone.htm

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Published: 2014-08-29  

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