2012 Fiscal Year Final Research Report
Development of asymmetrically catalytic reactions produced only small amount of carbon dioxide using sea water as a reaction solvent
| Project/Area Number |
22590007
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Gifu Pharmaceutical University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
ITOH Akichika 岐阜薬科大学, 薬学部, 教授 (10203126)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 海水 / 有機触媒 / 温室効果ガス削減 / フルオラス |
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| Research Abstract |
To achieve lowering of carbon dioxide, we examined the development of efficient organocatalysts that can use in ecofriendly sea water as a reaction solvent instead of an organic solvent. We have found that novel sulfonamide oraganocatalysts promote efficiently asymmetric aldol reactions in water or brine. The organocatalysts have been improved their catalytic activity by introduction of fluorous group. In addition, the fluorous oraganocatalysts can be easily recovered and reused.
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