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2011 Fiscal Year Final Research Report

studies on self-oscillating functional systems

Research Project

  • PDF
Project/Area Number 22655001
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Physical chemistry
Research InstitutionYamagata University (2011)
Hokkaido University (2010)

Principal Investigator

NABIKA Hideki  山形大学, 理学部, 准教授 (30372262)

Project Period (FY) 2010 – 2011
Keywords溶液 / コロイド
Research Abstract

By using chemical oscillation, we have succeeded in fabricating functional systems that can undergo spontaneous switching without any external stimuli. With coupling between pH oscillator and pH-responsive metal nanoparticles, autonomous oscillation (in other word autonomous switching) in optical properties between associated surface plasmon and isolated surface plasmon modes was appeared under CSTR condition. Furthermore, we have also succeeded in an autonomous mass transport in nanochannel by coupling between pH-wave propagation which is driven by reaction-diffusion phenomenon and nanochanel. All these results indicate that the use of non-linear chemical reacion that is the origin of self-oscillation in biology is quite useful to create an artificial system that can undergo autonomous oscillation without applying physical energy.

  • Research Products

    (8 results)

All 2012 2011 Other

All Journal Article (4 results) Presentation (3 results) Remarks (1 results)

  • [Journal Article] Dynamics of gold nanoparticle assembly and disassembly induced by pH oscillations2012

    • Author(s)
      H. Nabika, T. Oikawa, K. Iwasaki, K. Murakoshi, K. Unoura
    • Journal Title

      J. Phys. Chem. C

      Volume: 116(10) Pages: 6153-6158

  • [Journal Article] pH-wave propagation in the microchannel modified with pH-responsive molecule2012

    • Author(s)
      H. Nabika, M. Sato, K. Unoura
    • Journal Title

      e-J. Surf. Sci. Nanotech

      Volume: 10 Pages: 50-54

  • [Journal Article] Enhanced Molecular Filtering at Nano-channel by using Self-spreading Lipid Bilayer as Molecular Transport and Filtering Medium

    • Author(s)
      H. Nabika, K. Fukagawa, K. Murakoshi
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: (in press)

  • [Journal Article] Enhanced Brownian Ratchet Molecular Separation using a Self-spreading Lipid Bilayer

    • Author(s)
      T. Motegi, H. Nabika, K. Murakoshi
    • Journal Title

      Langmuir

      Volume: (in press)

  • [Presentation] 非線形反応の機能性材料化学への応用2011

    • Author(s)
      並河英紀
    • Organizer
      2011高分子・ハイブリッド材料研究センター若手フォーラム
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2011-12-21
  • [Presentation] 非線形化学反応を利用した機能性空間材料の創成2011

    • Author(s)
      並河英紀
    • Organizer
      第4回山形大学理学部工学部無機化学系交流セミナー
    • Place of Presentation
      山形大学(山形)
    • Year and Date
      2011-11-23
  • [Presentation] 非平衡振動反応を利用した物質操作2011

    • Author(s)
      並河英紀
    • Organizer
      平成23年度化学系学協会東北大会
    • Place of Presentation
      東北大学(仙台)
    • Year and Date
      2011-09-17
  • [Remarks]

    • URL

      http://www-kschem0.kj.yamagata-u.ac.jp/~nabika/index.html

URL: 

Published: 2013-07-31  

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