2012 Fiscal Year Final Research Report
Development of polymerization methods for novel polyyne polymers based on organometallic chemistry
| Project/Area Number |
22655031
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2012
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| Keywords | ポリイン / カルビン / クロスカップリング重合 / アセチレン等価体 / N-ヘテロカルベン |
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| Research Abstract |
Polyyne is an allotrope of carbon consists of alternating single and triple C-C bonds. Although the polymer is interesting because of its potential applicability for functional materials, chemical synthetic method of the polymer has not been established. In this study, halogenated metal acetylide and its equivalents, cyclopropenone ketals, cyclopropenone dithioketals, and adducts of halogenated metal acetylide with N-heterocyclic carbine, are synthesized as promising monomers of polyyne.
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