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2011 Fiscal Year Final Research Report

DEVELOPMENT OF HIGH-SPEED RESPONSED FERROELECTRICS WITH ELECTRONIC POLARIZATION

Research Project

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Project/Area Number 22655038
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionTohoku University

Principal Investigator

AKUTAGAWA Tomoyuki  東北大学, 多元物質科学研究所, 教授 (60271631)

Project Period (FY) 2010 – 2011
Keywords強誘電体 / クラスター / 分子性結晶 / 電子変位 / 秩序-無秩序転移 / ポリ酸 / 電子スピン共鳴
Research Abstract

Ferroelectric materials with high-speed electric responses over 106 Hz have been attracted much attentions from the viewpoint of memory device applications. Most of the researches have been examined in the inorganic materials. In this work, organic-inorganic hybrid type mixed-valenced polyoxometalate compounds were examined as a new candidate of ferroelectric materials. The order-disorder transition of free electron within the cluster was applied for the dipole inversion unit for the high speed electronic response.

  • Research Products

    (42 results)

All 2012 2011 2010

All Journal Article (20 results) (of which Peer Reviewed: 18 results) Presentation (19 results) Book (3 results)

  • [Journal Article] Molecular Motions and Hydrogen-Bonding Networks in (o-Aminoanilinium)-(Crown Ethers)-[PMo_<12> O_<40>]^<4->2012

    • Author(s)
      Daigoro Endo, Tomoyuki Akutagawa, Kazuya Kubo, Shin-ichiro Noro, Leroy Cronin, and Takayoshi Nakamura
    • Journal Title

      Bull Chem. Soc. Jpn

      Volume: 85 Pages: 305-315

    • Peer Reviewed
  • [Journal Article] Huge Dielectric Response and Molecular Motions in Paddle-wheel [Cu(II)_2(Adamantylcarboxylate)_4(DMF)_2].(DMF)_22011

    • Author(s)
      Qiong Ye, Kiyonori Takahashi, Norihisa Hoshino, Takemitsu Kikuchi, Tomoyuki Akutagawa, Shin-ichiro Noro, Sadamu Takeda, and Takayoshi Nakamura
    • Journal Title

      Chemistry An European Journal

      Volume: 17 Pages: 14442-14449

    • Peer Reviewed
  • [Journal Article] Polymorphs and Structural Phase Transition of [Ni(dmit)_2]^-Crystals Induced by Flexible (trans-Cyclohexane-1, 4-diammonium)(Benzo[18] crown-6)_2 Supramolecule2011

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Norihisa Hoshino, Takemitsu Kikuchi, Shin-ichiro Noro, Ren Gen Xiong, Takayoshi Nakamura
    • Journal Title

      Crystal Growth & Design

      Volume: 11 Pages: 4175-4182

    • Peer Reviewed
  • [Journal Article] Structural Phase Transition due to Flexible Supramolecule of (4-Cyanomethylanilinium)([18] crown-6)in [Ni(dmit)_2]^-Crystal2011

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Heng-Yun Ye, Tian Hang, Jia-Zhen Ge, Ren-Gen Xiong, Shin-ichiro Noro, and Takayoshi Nakamura
    • Journal Title

      CrystEngCommun

      Volume: 13 Pages: 6185-6192

    • Peer Reviewed
  • [Journal Article] Hydrogen-bonded Assemblies of Two-Electron Reduced Mixed-Valence [XMo_<12> O_<40>] (X=P and Si)with p-Phenylenediamines2011

    • Author(s)
      Tomoyuki Akutagawa, Fumito Kudo, Ryo Tsunashima, Shin-ichiro Noro ; Leroy Cronin, Takayoshi Nakamura
    • Journal Title

      Inorg. Chem

      Volume: 50 Pages: 6711-6718

    • Peer Reviewed
  • [Journal Article] Raul Quesada Cabrera, Paul F. McMillan, Paul Kogerler, and Leroy Cronin, Exploring Q1the thermochromism of sulfite-embedded polyoxometalate capsules2011

    • Author(s)
      Ryo Tsunashima, De-Liang Long, Toru Endo, Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Phys. Chem. Chem. Phys

      Pages: 7297-7297

    • Peer Reviewed
  • [Journal Article] Supramolecular cations of the m-fluoroanilinium(dibenzo[18] crown-6)in ferromagnetic salt2011

    • Author(s)
      Toru Endo, Tomoyuki Akutagawa, Shin-ichiro Noro, and Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 1491-1496

    • Peer Reviewed
  • [Journal Article] Diverse structures and adsorption properties of quasi-Werner-type copper(II)complexes2011

    • Author(s)
      Shin-ichiro Noro, Tomonori Ohba, Katsuo Fukuhara, Yukiko Takahashi, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 40 Pages: 2268-2274

  • [Journal Article] An Imidazolate-and Azide-Bridged Copper(II)Coordination Polymer Consisting of Alternating Di-and Mononuclear Units2010

    • Author(s)
      Ken-ichi Sakai, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Eur. J. Inorg. Chem

      Pages: 116-120

    • Peer Reviewed
  • [Journal Article] Electron transport in a gold nanoparticle assembly structure stabilized by a physisorbed porphyrin derivative2010

    • Author(s)
      Yuki Noda, Shin-ichiro Noro, Tomoyuki Akutagawa, and Takayoshi Nakamura
    • Journal Title

      Phys. Rev. B

      Volume: 82 Pages: 205420

    • Peer Reviewed
  • [Journal Article] Ren-Gen Xiong, Polymorphism and Magnetism of cis-Cyclohexane-1, 4-diammonium)(Dicyclohexano [18] crown-6)_2[Ni(dmit)_2]_2 Salts2010

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Shin-ichiro Noro, Takayoshi Nakamura, Ren-Gen Xiong
    • Journal Title

      Cryst. Growth & Des

      Volume: 10 Pages: 4856-4860

    • Peer Reviewed
  • [Journal Article] Highly Polar 7, 7-Bis(N, N-dimethylpiperazinium)-8, 8-dicyanoquinodimethane in [Ni(dmit)_2]^-Salt ; Crystal Structure and Magnetic Properties2010

    • Author(s)
      Subbalakshmi Jayanty, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      CrystEngComm

      Volume: 12 Pages: 4087-4090

    • Peer Reviewed
  • [Journal Article] Zn_3(4-OOCC_6H_4PO_3)_2 : A polar metal phosphonate with pillared layered structure showing SHG-activity and large dielectric anisotropy2010

    • Author(s)
      Jin-Tang Li, Deng-Ke Cao, Tomoyuki Akutagawa, and Li-Min Zheng
    • Journal Title

      Dalton Transactions

      Volume: 39 Pages: 8606-8608

    • Peer Reviewed
  • [Journal Article] Ren-Gen Xiong, Asymmetrical [Ni(dmit)_2]-Arrangements Induced by (1R, 2R)-Cyclohexanediammonium-Crown Ether Supramolecules2010

    • Author(s)
      Qiong Ye, Tomoyuki Akutagawa, Toru Endo, Shin-ichiro Noro, Takayoshi Nakamura, Ren-Gen Xiong
    • Journal Title

      Inorganic Chemistry

      Volume: 49 Pages: 8591-8600

    • Peer Reviewed
  • [Journal Article] [18] crown-6 Rotator in Spin-Ladder Compound of m-Aminoanilinium([18] crown-6)[Ni(dmit)_2]-2010

    • Author(s)
      Tomoyuki Akutagawa, Daisuke Sato, Ye Qiong, Toru Endo, Shin-ichiro Noro, Sadamu Takeda, Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 39 Pages: 8219-8227

  • [Journal Article] Orthogonality of Jahn-Teller axes in a dinuclear Cu(II)complex bridged by one F-anion2010

    • Author(s)
      Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Chemical Communications

      Volume: 46 Pages: 4619-4620

    • Peer Reviewed
  • [Journal Article] Selective separation of larger molecules from Lewis base mixture by flexible one-dimensional Cu(II)coordination polymer with shape-recognizing space2010

    • Author(s)
      Shin-ichiro Noro, Tomoyuki Akutagawa, Takayoshi Nakamura
    • Journal Title

      Chemical Communications

      Volume: 46 Pages: 3134-3136

    • Peer Reviewed
  • [Journal Article] Umpei Nagashim, Excited state intramolecular proton transfer (ESIPT)in six-coordinated zinc(II)-quinoxaline complexes with ligand hydrogen bonds : their fluorescent properties sensitive to axial positions2010

    • Author(s)
      Ken-ichi Sakai, Sami Takahashi, Ataru Kobayashi, Tomoyuki Akutagawa, Takayoshi Nakamura, Masaaki Dosen, Masako Kato
    • Journal Title

      Dalton Transactions

      Volume: 39 Pages: 1989-1995

    • Peer Reviewed
  • [Journal Article] Conformational Polymorph of o-Aminoanilinium(dibenzo[18] crown-6)Supramolecules in [Ni(dmit)2]-Salts2010

    • Author(s)
      Tomoyuki Akutagawa, Hiroyuki Koshinaka, Qiong Ye, Shin-ichiro Noro, Jun Kawamata, Hiroshi Yamaki, Takayoshi Nakamura
    • Journal Title

      Chemistry An Asian Journal

      Volume: 5 Pages: 520-529

    • Peer Reviewed
  • [Journal Article] Ferromagnetic coupling of [Ni(dmit)2]-anions in (m-fluoroanilinium)(dicyclohexano[18] crown-6)[Ni(dmit)2]2010

    • Author(s)
      Tomoyuki Akutagawa, Daisuke Sato, Qiong Ye, Shin-ichiro Noro, Takayoshi Nakamura
    • Journal Title

      Dalton Transactions

      Volume: 39 Pages: 2191-2193

    • Peer Reviewed
  • [Presentation] Diverse Structural Flexibilities and Dielectric Responses of Supramolecules in [Ni(dmit)2] Salts2011

    • Author(s)
      Tomoyuki Akutagawa
    • Organizer
      3rd Asian Conference on Coordination Chemistry (ACCC3)
    • Place of Presentation
      New Delhi
    • Year and Date
      20111017-20
  • [Presentation] アダマンチル基を配位子としたPaddle-Wheel型銅二核錯体の巨大誘電応答2011

    • Author(s)
      高橋仁徳、星野哲久、菊地毅光、Qiong Ye、中村貴義、芥川智行
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      20110917-19
  • [Presentation] マンガン12核単分子磁石への極性回転部位をもつ配位子の導入2011

    • Author(s)
      星野哲久、芥川智行
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Year and Date
      20110917-19
  • [Presentation] Gigantic dielectric response coupled with molecular motions in [Cu(admantylcarboxylate)4(DMF)2].(DMF)22011

    • Author(s)
      Tomoyuki Akutagawa, Kiyonori Takahashi, Takayoshi Nakamura
    • Organizer
      11th European Conference on Molecular Electronics (ECME)
    • Place of Presentation
      Barcelona Spain
    • Year and Date
      20110907-10
  • [Presentation] 分子性結晶におけるプロトン運動と誘電物性2011

    • Author(s)
      芥川智行
    • Organizer
      第9回水素量子アトミクス研究会
    • Place of Presentation
      東北大学金属材料研究所
    • Year and Date
      20110822-23
  • [Presentation] 固体中の分子運動を利用したデバイスへのアプローチ2011

    • Author(s)
      芥川智行
    • Organizer
      日本化学会東北支部第28回無機分析コロキュウム
    • Place of Presentation
      東北大学川渡セミナーハウス
    • Year and Date
      20110610-11
  • [Presentation] 超分子ローター型強誘電体の物性制御2011

    • Author(s)
      芥川智行
    • Organizer
      新学術領域研究「分子自由度が拓く新物質科学」第5回領域会議
    • Place of Presentation
      東京大学
    • Year and Date
      20110608-09
  • [Presentation] 籠状金属酸化物クラスター内に閉じ込められた亜硫酸イオンの熱振動とサーモクロミズム2011

    • Author(s)
      綱島亮・Long, De-Liang・Cronin, Leroy・石黒勝也・芥川智行・中村貴義
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      20110326-29
  • [Presentation] 分子性結晶中の回転運動・熱揺らぎの設計と誘電応答2011

    • Author(s)
      芥川智行
    • Organizer
      理化学研究所シンポジウム「分子アンサンブル2011」
    • Place of Presentation
      理化学研究所
    • Year and Date
      2011-10-12
  • [Presentation] 銅二核錯体から成る分子結晶の巨大誘電応答2011

    • Author(s)
      高橋仁徳、星野哲久、菊地毅光、芥川智行
    • Organizer
      東北大学多元物質科学研究所高分子・ハイブリッド材料研究センター2011 PHyMシンポジウム
    • Place of Presentation
      東北大学
    • Year and Date
      2011-06-17
  • [Presentation] 混合原子価ポリオキサメタレートを用いた分子性材料の開発2011

    • Author(s)
      芥川智行
    • Organizer
      東北大学多元物質科学研究所高分子・ハイブリッド材料研究センター 2011 PHyMシンポジウム
    • Place of Presentation
      東北大学
    • Year and Date
      2011-06-17
  • [Presentation] Ferroelectricity in magnetic [Ni(dmit)2] salts2010

    • Author(s)
      Tomoyuki Akutagawa and Takayoshi Nakamura
    • Organizer
      PacificChem2010
    • Place of Presentation
      Honolulu Hawaii USA
    • Year and Date
      20101215-20
  • [Presentation] 分子性結晶中の多彩な分子揺らぎと誘電応答2010

    • Author(s)
      芥川智行
    • Organizer
      第4回G-COE研究会「金属錯体の固体物性科学最前線. 錯体化学と固体物性物理と生物物性の連携新領域創成をめざしてー」
    • Place of Presentation
      東北大学
    • Year and Date
      20101203-05
  • [Presentation] Molecular Fluctuation and Dielectric Response in Flexible Supramolecular Complexes2010

    • Author(s)
      Tomoyuki Akutagawa
    • Organizer
      International Symposium on Advanced Soft Materials
    • Place of Presentation
      Kumamoto
    • Year and Date
      20101124-26
  • [Presentation] 分子性結晶内の動的自由度と誘電物性2010

    • Author(s)
      芥川智行
    • Organizer
      名古屋大学グローバルCOEプログラム第4回物質科学フロンティアセミナー
    • Place of Presentation
      名古屋大学
    • Year and Date
      20101119-20
  • [Presentation] Structural Flexibility and Dielectric Responses of Supramolecules in [Ni(dmit)2] Salts2010

    • Author(s)
      T. Akutagawa, Q. Ye, T. Nakamura
    • Organizer
      The 10th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena (10JCJS)
    • Place of Presentation
      Kyoto
    • Year and Date
      20101017-20
  • [Presentation] Ferroelectric Supramolecular Rotators in Magnetic [Ni(dmit)2] Salts2010

    • Author(s)
      Tomoyuki Akutagawa, Takayoshi Nakamura
    • Organizer
      International Conference on Science and Technology of Synthetic Metals (ICSM2010)
    • Place of Presentation
      Kyoto
    • Year and Date
      20100704-09
  • [Presentation] 分子性結晶中の多彩な分子運動と誘電応答2010

    • Author(s)
      芥川智行
    • Organizer
      新学術領域研究分子自由度が拓く新物質科学A05班合同会議
    • Place of Presentation
      京都大学
    • Year and Date
      2010-11-20
  • [Presentation] 電子活性な分子集合体の設計から機能性材料の開拓2010

    • Author(s)
      芥川智行
    • Organizer
      山口大学大学院理学研究科講演会
    • Place of Presentation
      山口大学
    • Year and Date
      2010-10-05
  • [Book] 超分子が拓く可能性-分子性マルチフェロイクス材料2011

    • Author(s)
      久保和也、芥川智行、中村貴義
    • Total Pages
      72
    • Publisher
      月刊化学
  • [Book] 分子性結晶を用いた強誘電材料の開発2011

    • Author(s)
      菊地毅光、坪内直人、芥川智行
    • Total Pages
      242-247
    • Publisher
      Materials Integration
  • [Book] 現代・界面コロイド科学の辞典2010

    • Author(s)
      芥川智行, 中村貴義
    • Total Pages
      162-163
    • Publisher
      丸善

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Published: 2013-07-31  

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