2011 Fiscal Year Final Research Report
Generation mechanism of catalysis of silica and application to the catalytic reactions
| Project/Area Number |
22656185
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Catalyst/Resource chemical process
|
|---|
| Research Institution | Kyoto University |
|---|
Principal Investigator |
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
SHISHIDO Tetsuya 京都大学, 大学院・工学研究科, 准教授 (80294536)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
TERAMURA Kentaro 京都大学, 大学院・工学研究科, 講師 (80401131)
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Keywords | シリカ / 光触媒 / 固体酸触媒 / 水酸基 / その場観察 |
|---|
| Research Abstract |
The pore-size dependence of the acidic properties of mesoporous silica FSM-16 in the range from 1. 8 to 3. 8 nm was investigated with the catalysis of 2-butanol dehydration and using FTIR spectra of adsorbed pyridine. The activity was the highest for FSM-16 with a minimum pore diameter, and decreased with increasing poresize. Basic nanospace was synthesized by the homogeneous modification of FSM-16 with 3-(triethoxysilyl) pyridine, which is a rigid substrate without an alkyl cha in as linker. Aldol condensation of butanal gave the corresponding dimer in high yields over 3-(triethoxysilyl) pyridine-modified FSM-16. Nitogen-substituted FSM-16 was synthesized by the NH3 treatment at high temperatures. Knoevenagel reaction takes place over nitrogen-substituted FSM-16.
|
Research Products
(9 results)
