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2012 Fiscal Year Final Research Report

New lubrication mechanism based on the structuring of liquid adsorbed at the solid-liquid interface

Research Project

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Project/Area Number 22710093
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Nanostructural science
Research InstitutionTohoku University

Principal Investigator

MIZUKAMI Masashi  東北大学, 多元物質科学研究所, 講師 (60333902)

Project Period (FY) 2010 – 2012
Keywordsトライボロジー / 表面・界面物性 / 固-液界面 / 吸着 / 潤滑
Research Abstract

We have revealed that alcohols and carboxylic acids, which have hydrogen-bonding groups, adsorbed on a silica surface in a nonpolar liquid, cyclohexane, forming ordered structures extending from ten to several tens of nanometers through hydrogen bonding between the surface silanol groups and alcohols (or carboxylic acids) as well as between alcohols (or carboxylic acids), which we call surface molecular macroclusters. We also found that the strong repulsive force appeared at the surface separation below ca. 5 nm when the molecular macrocluster layers were formed. This phenomenon realizes the high resistance to the normal load with low viscosity liquids, which are required for the lubricants. In this study, we aimed to regulate the structure and properties of molecular macrocluster layers based on the kind of adsorbing molecule, and to establish the new lubrication mechanism based on the structuring of liquid adsorbed at the solid-liquid interface.

  • Research Products

    (62 results)

All 2013 2012 2011 2010 Other

All Journal Article (12 results) (of which Peer Reviewed: 9 results) Presentation (47 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Sutructural Change in Smectic Liquid Crystal Nano-Film under Molecular-Scale Confinement Measured by Synchrotron X-ray Diffraction2013

    • Author(s)
      S. Nakano, M. Mizukami, N. Ohta, N. Yagi, I. Hatta, K. Kurihara
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Pages: 035002-1-4

    • Peer Reviewed
  • [Journal Article] Structuring of Interfacial Water on Silica Surface in Cyclohexane Studied by Surface Forces Measurement and Sum Frequency Generation Vibrational Spectroscopy^12012

    • Author(s)
      M. Mizukami, A. Kobayashi, and K. Kurihara
    • Journal Title

      Langmuir

      Volume: 28 Pages: 14284-14290

    • DOI

      DOI:dx.doi.org/10.1021/la303003u)

    • Peer Reviewed
  • [Journal Article] 共振ずり測定法によるナノレオロジー・ナノトライボロジー評価2012

    • Author(s)
      水上雅史,栗原和枝
    • Journal Title

      科学と工業

      Volume: 86巻 Pages: 1-7

  • [Journal Article] Formation of double helix self-assembled monolayers of ethynylhelicene oligomer disulfides on gold surfaces2011

    • Author(s)
      K. Yamamoto, H. Sugihara, R. Amemiya, H. Aikawa, Z. An, M. Yamaguchi, M. Mizukami, K. Kurihara
    • Journal Title

      Tetrahedron

      Volume: 67 Pages: 5972-5978

    • DOI

      DOI:10.1016/j.tet.2011.06.024

    • Peer Reviewed
  • [Journal Article] Direct Observation of Double Layer Interactions between the Potential Controlled Gold Electrode Surfaces Using the Electrochemical Surface Forces Apparatus2011

    • Author(s)
      T. Kamijo, M. Kasuya, M. Mizukami, K. Kurihara
    • Journal Title

      Chem. Lett

      Volume: 40 Pages: 674-675

    • DOI

      DOI:10.1246/cl.2011.674

    • Peer Reviewed
  • [Journal Article] 表面力装置による金属.高分子接着の評価22011

    • Author(s)
      水上雅史,杉原理,山辺秀敏,安東勲雄,黒川幸子,栗原和枝
    • Journal Title

      色材協会誌

      Volume: 84 Pages: 87-91

    • Peer Reviewed
  • [Journal Article] 原子間力顕微鏡(AFM)により相互作用力を測定する2011

    • Author(s)
      水上雅史
    • Journal Title

      化学と工業

      Volume: 64巻,6号 Pages: 464-465

  • [Journal Article] 表面力測定からみた固体表面の水の特性2010

    • Author(s)
      粕谷素洋,水上雅史,栗原和枝
    • Journal Title

      分析化学

      Volume: 59 Pages: 957-965

    • Peer Reviewed
  • [Journal Article] Properties of Water at Solid Surface Revealed Using Surface Force Measurement2010

    • Author(s)
      M. Kasuya, M. Mizukami, K. Kurihara
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 59 Pages: 957-965

    • Peer Reviewed
  • [Journal Article] Resonance Shear Measurement of Nanoconfined Ionic Liquids2010

    • Author(s)
      K. Ueno, M. Kasuya, M. Watanabe, M. Mizukami, K. Kurihara
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 12 Pages: 4066-4071

    • DOI

      DOI:10.1039/b923571j

    • Peer Reviewed
  • [Journal Article] 共振ずり測定に基づく液体ナノ潤滑のモデル化2010

    • Author(s)
      水上雅史,栗原和枝
    • Journal Title

      トライボロジスト

      Volume: 55巻,1号 Pages: 24-30

    • Peer Reviewed
  • [Journal Article] 共振ずり測定装置「RSM-1」2010

    • Author(s)
      曹 家栄, 遠藤 聡, 石井芳一, 粕谷素洋, 水上雅史, 栗原和枝
    • Journal Title

      ULVAC TECHNICAL JOURNAL

      Volume: No.73 Pages: 34-37

  • [Presentation] Multilayer Assemblies of Gold Nanoparticles Prepared Using Surface Molecular Macroclusters2013

    • Author(s)
      T. Kajiwara, T. Shinzawa, M. Mizukami, K. Kurihara
    • Organizer
      JSPS Core-to-Core Program and Specially Promoted Research Joint Symposium, Micro and Extended-Nano Space Chemistry and Perspective of Next-Generation Analytical Devices
    • Place of Presentation
      The Univ. of Tokyo, Japan
    • Year and Date
      20130326-27
  • [Presentation] 共振ずり測定に基づく液体ナノ薄膜のトライボロジー特性の解析法2013

    • Author(s)
      水上雅史,栗原和枝
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Year and Date
      20130322-25
  • [Presentation] ネマチック液晶の電場配向に与えるナノ空間への閉じ込めの影響2013

    • Author(s)
      中野真也, 水上雅史, 太田昇, 八木直人, 八田一郎, 栗原和枝
    • Organizer
      日本化学会第93春季年会(2013)
    • Place of Presentation
      立命館大学
    • Year and Date
      20130322-25
  • [Presentation] 共振ずり測定による潤滑油モデルとしてのヘキサデカンの特性評価2013

    • Author(s)
      富田和仁, 水上雅史, 猪俣敬娥, 栗原和枝
    • Organizer
      平成24年度日本表面科学会東北・北海道支部講演会
    • Place of Presentation
      日本大学工学部
    • Year and Date
      20130311-12
  • [Presentation] 表面力および和周波発生振動分光法によるシクロヘキサン中にシリカ表面に吸着した水の構造・特性評価2012

    • Author(s)
      水上雅史, 小林篤史, 栗原和枝
    • Organizer
      第32回表面科学学術講演会
    • Place of Presentation
      東北大学
    • Year and Date
      20121120-22
  • [Presentation] 雲母表面間に閉じ込められたスメクチック液晶薄膜の放射光X線回折による構造評価2012

    • Author(s)
      中野真也, 水上雅史, 太田昇, 八木直人, 八田一郎, 栗原和枝
    • Organizer
      平成24年度日本結晶学会年会
    • Place of Presentation
      東北大学
    • Year and Date
      20121025-26
  • [Presentation] シリカ表面間に閉じ込められた水の共振ずり測定による特性評価2012

    • Author(s)
      粕谷素洋, 日野正也, 山田飛将, 水上雅史, 森広行, 梶田晴司, 大森俊英, 鈴木厚, 栗原和枝
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20120919-20
  • [Presentation] ネマチック液晶分子の電場配向への閉じ込め効果2012

    • Author(s)
      中野真也, 水上雅史, 太田昇, 八木 直人, 八田一郎, 栗原和枝
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学
    • Year and Date
      20120919-20
  • [Presentation] 共振法による限定ナノ空間中の液体の特性評価:モデル解析の高度化2012

    • Author(s)
      水上雅史, 栗原和枝
    • Organizer
      第61回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      20120529-31
  • [Presentation] Interfacial Water Structured on Silica Surfaces in Cyclohexane through Hydrogen-Bonding Studied by Surface Forces Measurement2012

    • Author(s)
      M. Mizukami, A. Kobayashi, K. Kurihara
    • Organizer
      IACIS2012 (14th International Association of Colloid and Interfaces Interface Scientists, Conference)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120513-18
  • [Presentation] Characterization of Water Confined between Silica Surfaces Using Resonance Shear Measurement2012

    • Author(s)
      M. Kasuya, M. Hino, H. Yamada, M. Mizukami, H. Mori, S. Kajita, T. Ohmori, A. Suzuki, K. Kurihara
    • Organizer
      IACIS2012 (14th International Association of Colloid and Interfaces Interface Scientists, Conference)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120513-18
  • [Presentation] Structural Analysis of Smectic Liquid Crystal Nano-Films by Synchrotron X-ray Diffraction Measurement2012

    • Author(s)
      S. Nakano, M. Mizukami, N. Ohta, N. Yagi, I. Hatta, K. Kurihara
    • Organizer
      IACIS2012 (14th International Association of Colloid and Interfaces Interface Scientists, Conference)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120513-18
  • [Presentation] Double Layer Forces at the Potential Controlled Gold Electrodes Studied Using the Electrochemical Surface Forces Apparatus2012

    • Author(s)
      T. Kamijo, M. Kasuya, M. Mizukami, K. Kurihara
    • Organizer
      IACIS2012 (14th International Association of Colloid and Interfaces Interface Scientists, Conference)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120513-18
  • [Presentation] Multilayer Assemblies of Gold Nanoparticles Prepared Using Surface Molecular Macroclusters2012

    • Author(s)
      T. Kajiwara,T. Shinzawa, M. Mizukami, K. Kurihara
    • Organizer
      IACIS2012 (14th International Association of Colloid and Interfaces Interface Scientists, Conference)
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120513-18
  • [Presentation] 表面力測定と界面選択分光法による固-液界面での液体吸着構造評価2012

    • Author(s)
      水上雅史
    • Organizer
      日本学術振興会 ナノプローブテクノロジー第167委員会, 第68回研究会
    • Place of Presentation
      福島
    • Year and Date
      2012-10-19
  • [Presentation] 表面力装置による金属.高分子接着の評価2012

    • Author(s)
      水上雅史, 杉原理, 山辺秀敏, 安東勲雄, 黒川幸子, 栗原和枝
    • Organizer
      2012年色材研究発表会, 大阪府立大学
    • Place of Presentation
      大阪
    • Year and Date
      2012-09-20
  • [Presentation] Interaction of Cellulose Surface and Silica in Apolar Solvents2012

    • Author(s)
      Pieter Mulder Frank, Mieke Kleijn, 水上雅史, 栗原和枝
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学
    • Year and Date
      2012-03-27
  • [Presentation] コロイドプローブ原子間力顕微鏡法による水溶液中の鉄-アミン修飾表面間の相互作用力評価2012

    • Author(s)
      水上雅史,上條利夫,栗原和枝,釣之朗,星野俊幸
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶應義塾大学(神奈川)
    • Year and Date
      2012-03-27
  • [Presentation] Surface forces study on interfacial water adsorbed on silica surfaces2012

    • Author(s)
      A. Kobayashi, M. Mizukami, K. Kurihara
    • Organizer
      Softinterface Mini-symposium on Biomaterials Science in Tsukuba (SIMS2012)
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2012-03-18
  • [Presentation] Interfacial water structured on silica surface in cyclohexane studied by surface forces measurement and SFG spectroscopy2012

    • Author(s)
      A. Kobayashi, M. Mizukami, K. Kurihara
    • Organizer
      UCSB ICMR/CNSI and Tohoku University WPI-AIMR Joint Workshop on Materials Research
    • Place of Presentation
      Santa Barbara, USA , 招待講演
    • Year and Date
      2012-01-11
  • [Presentation] Gold Nanoparticle Assemblies Prepared Using Surface Molecular Macroclusters, GCOE International Center of Research & Education, for Molecular Complex Chemistry2011

    • Author(s)
      T. Kajiwara, T. Shinzawa, M. Mizukami, K. Kurihara
    • Organizer
      Summer School
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20110818-19
  • [Presentation] Organization of Liquids Adsorbed at Solid-Liquid Interfaces in Binary Liquid Mixtures2011

    • Author(s)
      M. Mizukami, M. Guendouz, D. Morineau, K. Kurihara
    • Organizer
      4th French Research Organizations . Tohoku University Joint Workshop on Frontier Materials (Frontier2011)
    • Place of Presentation
      Sendai, Japan 招待講演
    • Year and Date
      2011-12-05
  • [Presentation] Interfacial Water on Silica Surface in Cyclohexane Studied by Surface Forces Measurement and SFG-Spectroscopy2011

    • Author(s)
      A. Kobayashi, M. Mizukami, K. Kurihara
    • Organizer
      12th Australia-Japan Colloid & Interface Science Symposium
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2011-11-21
  • [Presentation] 界面分子マクロクラスターを用いた金ナノ粒子集積体の調製2011

    • Author(s)
      梶原剛史,新沢達朗,水上雅史,栗原和枝
    • Organizer
      第1回CSJ化学フェスタ
    • Place of Presentation
      早稲田大学
    • Year and Date
      2011-11-15
  • [Presentation] 共振ずり測定法による限定空間中のトラクションオイルナノ薄膜の特性評価2011

    • Author(s)
      日野正也, 水上雅史, 栗原和枝
    • Organizer
      第59回レオロジー討論会
    • Place of Presentation
      桐生
    • Year and Date
      2011-10-07
  • [Presentation] 共振ずり測定法による閉じ込め空間におけるイオン液体の構造化挙動の評価2011

    • Author(s)
      南野 裕, 粕谷素洋, 水上雅史, 栗原和枝
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-29
  • [Presentation] 共振ずり測定法による限定ナノ空間中のトラクションオイルの特性評価2011

    • Author(s)
      日野正也, 水上雅史, 栗原和枝
    • Organizer
      平成23年度化学系学協会東北大会
    • Place of Presentation
      東北大学
    • Year and Date
      2011-09-18
  • [Presentation] コロイドプローブ原子間力顕微鏡法による水溶液中の鉄表面の評価2011

    • Author(s)
      水上雅史, 上條利夫, 栗原和枝, 釣之朗, 星野俊幸
    • Organizer
      第63回コロイドおよび界面化学討論会
    • Place of Presentation
      京都大学 (京都)
    • Year and Date
      2011-09-09
  • [Presentation] 共振ずり測定法による制御空間におけるイオン液体の特性評価2011

    • Author(s)
      南野裕, 粕谷素洋, 水上雅史, 栗原和枝
    • Organizer
      第39回東北地区高分子若手研究会夏季ゼミナール
    • Place of Presentation
      秋田
    • Year and Date
      2011-07-27
  • [Presentation] 表面力装置による金属-高分子接着の評価2011

    • Author(s)
      水上雅史,杉原理,山辺秀敏,安東勲雄,黒川幸子,栗原和枝
    • Organizer
      第60回高分子年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Year and Date
      2011-05-26
  • [Presentation] 和周波発生振動分光法を用いた金属-液体界面の評価2011

    • Author(s)
      山田飛将, 水上雅史, 栗原和枝
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場 (大阪)
    • Year and Date
      2011-05-25
  • [Presentation] 共振ずり測定法による限定ナノ空間中のトラクションオイルの構造化挙動・特性評価2011

    • Author(s)
      日野正也,水上雅史,栗原和枝
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-26
  • [Presentation] 共振ずり測定による限定ナノ空間中のイオン液体の特性評価2011

    • Author(s)
      南野裕,粕谷素洋,水上雅史,栗原和枝
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Year and Date
      2011-03-26
  • [Presentation] Resonance shear measurement of nanoconfined ionic liquids2010

    • Author(s)
      K. Kurihara, K. Ueno, M. Kasuya, M. Watanabe, M. Mizukami
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-18
  • [Presentation] Characterization of liquid crystal thin film under electric field2010

    • Author(s)
      S. Nakano, M. Mizukami, N. Ohta, N. Yagi, I. Hatta, K. Kurihara
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-18
  • [Presentation] Surface Forces Study on Organization of Liquids Adsorbed at Solid-Liquid Interfaces in Binary Liquid Mixtures (Invited)2010

    • Author(s)
      M. Mizukami
    • Organizer
      Frontier 2010 (The third workshop on frontier materials and processes)
    • Place of Presentation
      Albi, France
    • Year and Date
      2010-12-09
  • [Presentation] 共振ずり測定法による制限空間におけるイオン液体の特性評価2010

    • Author(s)
      南野裕,粕谷素洋,水上雅史,栗原和枝
    • Organizer
      平成22年度化学系学協会東北大会
    • Place of Presentation
      岩手大学(盛岡市)
    • Year and Date
      2010-09-25
  • [Presentation] Metal-Polymer Adhesion Studied by Surface Forces Apparatus2010

    • Author(s)
      M. Mizukami, O. Sugihara, S. Suzuki, M. Matsudaira, H. Yamabe, I. Andoh, S. Kurokawa, K. Kurihara
    • Organizer
      NCSS2010(International Conference on Nanoscopic Colloid and Surface Science)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-09-22
  • [Presentation] Resonance Shear Measurement of Nanoconfined Ionic Liquids2010

    • Author(s)
      K. Ueno, M. Kasuya, M. Mizukami, M. Watanabe, K. Kurihara
    • Organizer
      NCSS2010 (International Conference on Nanoscopic Colloid and Surface Science)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-09-21
  • [Presentation] Au Nanoparticle Assemblies Prepared Using Surface Molecular Macroclusters2010

    • Author(s)
      T. Kajiwara, T. Shinzawa, M. Mizukami, K. Kurihara
    • Organizer
      NCSS2010 (International Conference on Nanoscopic Colloid and Surface Science)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-09-21
  • [Presentation] Rheological Study of Liquid Crystal Confined in Nano-Space under Electric Field2010

    • Author(s)
      S. Nakano, M. Mizukami, K. Kurihara
    • Organizer
      NCSS2010 (International Conference on Nanoscopic Colloid and Surface Science)
    • Place of Presentation
      Chiba, Japan
    • Year and Date
      2010-09-21
  • [Presentation] 共振ずり測定によるトラクションオイルナノ薄膜の特性評価2010

    • Author(s)
      水上雅史,日野正也,栗原和枝
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-16
  • [Presentation] 界面分子マクロクラスターを用いた金ナノ粒子集積2010

    • Author(s)
      梶原剛史,新沢達郎,水上雅史,栗原和枝
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-16
  • [Presentation] Nanorheology of Liquid Crystal Thin Film under Electroric Field2010

    • Author(s)
      S. Nakano, M. Mizukami, K. Kurihara
    • Organizer
      Tohoku University Global Center of Excellence Program Summer School 2010
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2010-08-20
  • [Presentation] Au Nanoparticle Assemblies Prepared Using Surface Molecular Macroclusters2010

    • Author(s)
      T. Kajiwara, T. Shinzawa, M. Mizukami, K. Kurihara
    • Organizer
      Tohoku University Global Center of Excellence Program Summer School 2010
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      2010-08-19
  • [Presentation] Nanorheology of Liquid Crystal Confined between Mica Surfaces under Electric Field2010

    • Author(s)
      S. Nakano, M. Mizukami, K. Kurihara
    • Organizer
      PRCR-5 (5th Pacific Rim Conference on Rheology)
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2010-08-02
  • [Presentation] Molecular Macrocluster Formation at the Solid-Liquid Interfaces Studied by Surface Forces Measurement2010

    • Author(s)
      M. Mizukami, K. Kurihara
    • Organizer
      ICCT-2010 (21st IUPAC International Conference on Chemical Thermodynamics)
    • Place of Presentation
      Tsukuba, Japan
    • Year and Date
      2010-08-02
  • [Book] 表面力装置による金属-高分子接着の評価"接着・粘着分析", 23節2012

    • Author(s)
      水上雅史
    • Total Pages
      239-245
    • Publisher
      技術情報協会
  • [Book] 「ナノレオロジー・ナノトライボロジー」"CSJカレントレビュー04界面の分子科学",13章2011

    • Author(s)
      水上雅史,栗原和枝
    • Total Pages
      144-150
    • Publisher
      化学同人
  • [Remarks] 第46回(平成24年度)色材協会賞(論文賞),水上雅史,杉原理,山辺秀敏,安東勲雄,黒川幸子,栗原和枝,"表面力装置による金属-高分子接着の評価2",2012年9月20日受賞

    • URL

      http://www.tagen.tohoku.ac.jp/labo/kurihara/index.html

URL: 

Published: 2014-08-29  

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