Hydrogen diffusion in mantle minerals (Olivine, wadsleyite, ringwoodite)

2011 Fiscal Year Final Research Report

• Project/Area Number: 22740341
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Petrology/Mineralogy/Science of ore deposit
• Research Institution: Tohoku University
• Principal Investigator: SHATSKIY Anton 東北大学, 大学院・理学研究科, 助教 (00546252)
• Project Period (FY): 2010 – 2011
• Keywords: 地殻 / マントル / 核 / 高圧揮発性元素

Research Abstract

1) Recently I completed to collect X-ray diffraction patterns for simple carbonate systems Na2CO3, K2CO3, CaCO3, and FeCO3 in the range 1-30 GPa and 27-1400℃ to constrain phase relations and EOS. 2) I supposed mechanism and estimated possible rates of carbonatite±H_2O and hydrous melt ascent from the transition zone and might be lower mantle. This mechanism so called"dissolution-precipitation" controlled by diffusion transport of silicate components via hydrous or carbonatite melt. 3) I collected experimental data point to constrain phase diagrams and melting phase relations in simple carbonate systems (K-Mg, K-Ca, Na-Mg, Na-Ca, K-Ca-Mg, Na-Ca-Mg, K-Na-Ca-Mg)at the conditions corresponding to the basement of lithospheric mantle.

Research Products

• [Journal Article] Crystal chemistry of sodium in the Earth's interior : The structure of Na_2MgSi_5O_<12> synthesized at 17. 5 GPa and 1700 ℃ (2011)
  • Author(s): Bindi, L., Dymshits, A. M., Bobrov, A. V., Litasov, K. D., Shatskiy, A. F., Ohtani, E., Litvin, Y. A.
  • Journal Title: American Mineralogist Volume: 96 Pages: 447-450
  • Peer Reviewed
• [Journal Article] Systematic study of hydrogen incorporation into Fe-free wadsleyite (2011)
  • Author(s): Litasov, K. D., Shatskiy, A., Ohtani, E., Katsura, T.
  • Journal Title: Physics and Chemistry of Minerals Volume: 38 Pages: 75-84
  • Peer Reviewed
• [Journal Article] Phase relations and melting in the systems of peridotite-H_2O-CO_2 and eclogite-H_2O-CO_2 at pressures up to 27 GPa (2011)
  • Author(s): Litasov, K. D., Shatskiy, A. F., Pokhilenko, N. P.
  • Journal Title: Doklady Earth Sciences Volume: 437 Pages: 498-502
  • Peer Reviewed
• [Journal Article] Mechanisms of Cr and H incorporation in stishovite determined by single-crystal EPR spectroscopy and DFT calculations (2011)
  • Author(s): Pan, Y., Mashkovtsev, R. I., Huang, D., Mao, M., Shatskiy, A.
  • Journal Title: American Mineralogist Volume: 96 Pages: 1331-1342
  • Peer Reviewed
• [Journal Article] Press less split-sphere apparatus equipped with scaled-up Kawai-cell for mineralogical studies at 10-20 GPa (2011)
  • Author(s): Shatskiy, A., Borzdov, Y. M., Litasov, K. D., Ohtani, E., Khokhryakov, A. F., Pal' yanov, Y. N., Katsura, T.
  • Journal Title: American Mineralogist Volume: 96 Pages: 541-548
  • Peer Reviewed
• [Journal Article] High pressure generation using scaled-up Kawai-cell (2011)
  • Author(s): Shatskiy, A., Katsura, T., Litasov, K. D., Shcherbakova, Y. M., Borzdov, Y. M., Yamazaki, D., Yoneda, A., Ohtani, E.
  • Journal Title: Physics of the Earth and Planetary Interiors
  • DOI: doi:10.1016/j.pepi.2011.1008.1001.
  • Peer Reviewed
• [Journal Article] Phase boundary between perovskite and post-perovskite structures in MnGeO_3 determined by in situ X-ray diffraction measurements using sintered diamond anvils (2011)
  • Author(s): Yamazaki, D., Ito, E., Katsura, T., Yoshino, T., Zhai, S., Fukui, H., Shatskiy, A., Guo, X., Shan, S., Okuchi, T., Tange, Y., Higo, Y., Funakoshi, K.
  • Journal Title: American Mineralogist Volume: 96 Pages: 89-92
  • Peer Reviewed
• [Journal Article] Single-crystal elasticity of stishovite : New experimental data obtained using high-frequency resonant ultrasound spectroscopy and a Gingham check structure model (2011)
  • Author(s): Yoneda, A., Cooray, T., Shatskiy, A.
  • Journal Title: Physics of the Earth and Planetary Interiors Volume: 190-191 Pages: 80-86
  • Peer Reviewed
• [Journal Article] Press less split-sphere apparatus equipped with scaled-up Kawai-cell for mineralogical studies at 10-20 Gpa (2011)
  • Author(s): A. Shatskiy, Y. M. Borzdov, K. D. Litasov, E. Ohtani, A. F. Khokhryakov, Y. N. Palyanov, T. Katsura
  • Volume: 96, 4
  • Pages: 541-548
  • Peer Reviewed
• [Journal Article] Systematic study of hydrogen incorporation into Fe-free wadsleyite (2011)
  • Author(s): K. D. Litasov, A. Shatskiy, E. Ohtani, T. Katsura
  • Journal Title: Physics and Chemistry of Mineral Volume: 38 Pages: 75-84
  • Peer Reviewed
• [Journal Article] Electrical conductivity measurements of periclase under high pressure and high temperature (2010)
  • Author(s): X. P. Wu, B. H. Zhang, J. S. Xu, T. Katsura, S. M. Zhai, T. Yoshino, G. Manthilake, A. Shatskiy
  • Journal Title: Physica B-Condensed Matter Volume: 405 Pages: 53-56
  • Peer Reviewed
• [Journal Article] Stishovite single-crystal growth and application to silicon self-diffusion measurements (2010)
  • Author(s): A. Shatskiy, D. Yamazaki, Y. M. Borzdov, T. Matsuzaki, K. D. Litasov, T. Cooray, A. Ferot, E. Ito, T. Katsura
  • Journal Title: American Mineralogist Volume: 95 Pages: 135-143
  • Peer Reviewed
• [Journal Article] Performance of semi-sintered ceramics as pressure-transmitting media up to 30GPa (2010)
  • Author(s): A. Shatskiy, K. D. Litasov, H. Terasaki, T. Katsura, E. Ohtani
  • Journal Title: High Pressure Research Volume: 30 Pages: 443-450
  • Peer Reviewed
• [Journal Article] Aluminum Nitride Crystal Growth from an Al-N System at 6. 0 GPa and 1800 degrees C (2010)
  • Author(s): A. Shatskiy, Y. M. Borzdov, D. Yamazaki, K. D. Litasov, T. Katsura, Y. N. Palyanov
  • Journal Title: Crystal Growth & Design Volume: 10 Pages: 2563-2570
  • Peer Reviewed
• [Journal Article] Crystal structure of anhydrous phase X, K_<1. 93>(Mg_<2. 02> Cr_<0. 02>)Si_<2. 00> O_7 (2010)
  • Author(s): T. Matsuzaki, K. Hagiya, A. Shatskiy, T. Katsura, M. Matsui
  • Journal Title: Journal of Mineralogical and Petrological Sciences Volume: 105 Pages: 303-308
  • Peer Reviewed
• [Journal Article] Pressure-volume-temperature equation of state of tungsten carbide to 32 GPa and 1673 K (2010)
  • Author(s): K. D. Litasov, A. Shatskiy, Y. W. Fei, A. Suzuki, E. Ohtani, K. Funakoshi
  • Journal Title: Journal of Applied Physics Volume: 108
  • Peer Reviewed
• [Journal Article] Pressure generation and investigation of the post-perovskite transformation in MgGeO_3 by squeezing the Kawai-cell equipped with sintered diamond anvils (2010)
  • Author(s): E. Ito, D. Yamazaki, T. Yoshino, H. Fukui, S. M. Zhai, A. Shatzkiy, T. Katsura, Y. Tange, K. Funakoshi
  • Journal Title: Earth and Planetary Science Letters Volume: 293 Pages: 84-89
  • Peer Reviewed
• [Journal Article] Experimental study of the pyroxene-garnet phase transition in the Na_2MgSi_5O_<12> system at pressures of 13-20 GPa : First synthesis of sodium majorite (2010)
  • Author(s): A. M. Dymshits, A. V. Bobrov, K. D. Litasov, A. F. Shatskiy, E. Ohtani, Y. A. Litvin
  • Journal Title: Doklady Earth Sciences Volume: 434 Pages: 1263-1266
  • Peer Reviewed
• [Presentation] Silicate diffusion in alkali-carbonatite and hydrous melt at 16. 5 and 24 GPa, with implications for mass transfer in the deep mantle. Silicate diffusion in alkali-carbonatite and hydrous melt at 16. 5 and 24 GPa, with implications formass transfer in the (2012)
  • Author(s): Shatskiy, A., Litasov, K. D., Katsura, T., Borzdov, Y. M., Yamazaki, D., Ohtani, E
  • Organizer: Joint Symposium of Misasa-2012 and Geofluid-2''
  • Place of Presentation: Misasa, Japan
  • Year and Date: 20120318-21
• [Presentation] Self-diffusion coefficients of mantle minerals and its applications to mantle rheology (2012)
  • Author(s): Katsura, T., Yamazaki, D., Chakraborty, S., Dohmen, R., Shatsky, A., Xu, J.-S., Fei, H.-Z., Hegoda, C., Yurimoto, H., Wiedenbeck, M.
  • Organizer: Joint Symposium of Misasa-2012 and Geofluid-2''
  • Place of Presentation: Misasa, Japan
  • Year and Date: 20120318-21
• [Presentation] Melting of mantle in the presence of C-O-H fluid : The role of oxygen fugacity (2012)
  • Author(s): Litasov, K. D. Ohtani, E., Shatskiy, A.
  • Organizer: 9^<th> International Workshop on Water Dynamics
  • Place of Presentation: Sendai, Japan
  • Year and Date: 20120307-09
• [Presentation] Mechanism of hydrous fluid and alkali-rich carbonate melt segregation in the deep mantle (2012)
  • Author(s): Shatskiy, A., Litasov, K. D. Ohtani, E.
  • Organizer: 9^<th> International Workshop on Water Dynamics
  • Place of Presentation: Sendai, Japan
  • Year and Date: 20120307-09
• [Presentation] Melting phase relations of unaltered Udachnaya-East kimberlite at 3-6. 5 GPa and 900-1500℃ (2012)
  • Author(s): Sharygin, I. S., Litasov, K. D., Shatskiy, A., Golovin, A. V., Ohtani, E., Pokhilenko, N. P.
  • Organizer: 9^<th> International Workshop on Water Dynamics
  • Place of Presentation: Sendai, Japan
  • Year and Date: 20120307-09
• [Presentation] Melting of peridotite and eclogite coexisting with reduced C-O-Hfl uid at 3-16 GPa : further constraints for redox melting models (2012)
  • Author(s): Litasov, K. D., Shatskiy, A., Ohtani, E.
  • Organizer: 10^<th> International Kimberlite Conference, Bangalore
  • Place of Presentation: India
  • Year and Date: 20120206-11
• [Presentation] Melting phase relations of chlorine-bearing kimberlite at 2. 1-6. 5 GPa and 900-1500℃ (2012)
  • Author(s): Sharygin, I. S., Litasov, K. D., Shatskiy, A., Golovin, A. V., Ohtani, E., Pokhilenko, N. P.
  • Organizer: 10^<th> International Kimberlite Conference
  • Place of Presentation: Bangalore, India
  • Year and Date: 20120206-11
• [Presentation] Sodium majorite and its pyrope solid solutions : High pressure experiment and crystal-chemical implications (2012)
  • Author(s): Dymshits, A. M., Bindi, L., Bobrov, A. V., Litasov, K. D., Shatskiy, A. F., Ohtani, E., Litvin Yu. A.
  • Organizer: 10^<th> International Kimberlite Conference
  • Place of Presentation: Bangalore, India
  • Year and Date: 20120206-11
• [Presentation] Segregation rate and transport mechanism of volatile-bearing melt in the deep mantle (2012)
  • Author(s): Shatskiy A., Litasov K. D., Ohtani E.
  • Organizer: 10^<th> International Kimberlite Conference
  • Place of Presentation: Bangalore, India
  • Year and Date: 20120206-11
• [Presentation] Possible carbon flux from the core-phenomenological constraint (2011)
  • Author(s): Dobretsov, N. L., Shatskiy, A. F.
  • Organizer: Deep Carbon Cycle International Workshop (DCO-3)
  • Place of Presentation: Altai, Novosibirsk
  • Year and Date: 20110825-30
• [Presentation] Dissolution-precipitation as a possible mechanism of carbonatite melt segregation in upwellingmantle (2011)
  • Author(s): Shatskiy, A., Litasov, K. D., Borzdov, Y. M., Katsura, T., Yamazaki, D., Ohtani, E.
  • Organizer: Deep Carbon Cycle International Workshop (DCO-3)
  • Place of Presentation: Altai, Novosibirsk
  • Year and Date: 20110825-30
• [Presentation] Possible carbon flux from the core-phenomenological constraints (2011)
  • Author(s): Dobretsov, N. L., Shatskiy, A. F.
  • Organizer: International Symposium LIP's of Asia
  • Place of Presentation: Irkutsk, Russia
  • Year and Date: 20110820-28
• [Presentation] Dissolution-precipitation as a possible mechanism of C-O-H fluid/melt segregation in the deep mantle (2011)
  • Author(s): Shatskiy, A., Litasov, K. D., Ohtani, E.
  • Organizer: Goldschmidt conference
  • Place of Presentation: Prague, Czech Republic
  • Year and Date: 20110814-19
• [Presentation] Melting in the Peridotite and Eclogite, Coexisting with Reduced C-O-H Fluid at 3-16 GPa (2011)
  • Author(s): Litasov, K. D., Shatskiy, A., Ohtani, E.
  • Organizer: Goldschmidt conference
  • Place of Presentation: Prague, Czech Republic
  • Year and Date: 20110814-19
• [Presentation] Na-Bearing Majoritic Garnets in the System Mg3Al2Si5O12-Na2MgSi5O12 at 11. 20 GPa : Solid Solutions and Structural Peculiarities (2011)
  • Author(s): Bobrov, AV., Dymshits, A. M., Bindi, L., Litasov, K. D., Satskiy, A. F., Ohtani, E., Litvin, Y. A.
  • Organizer: Goldschmidt conference
  • Place of Presentation: Prague, Czech Republic
  • Year and Date: 20110814-19
• [Presentation] Melting phase relations in the peridotite and eclogite systems coexisting with reduced C-O-H fluid at 3-16 GPa (2011)
  • Author(s): Litasov, K. D., Shatskiy, A., Ohtani, E.
  • Organizer: Japan Geoscience Union Meeting
  • Place of Presentation: Makuhari, Japan
  • Year and Date: 20110522-28
• [Presentation] Diffusion of silicates in alkali carbonate malt and water fluid, experimental study at 17-24 GPa and 1400-1750℃ (2011)
  • Author(s): Shatskiy, A., Litasov, K. D., Katsura, T., Yamazaki, D., Ohtani, E.
  • Organizer: Japan Geoscience Union Meeting
  • Place of Presentation: Makuhari, Japan
  • Year and Date: 20110522-28
• [Presentation] Role of alkali carbonates in the mantle magmatism, metasomatism, and diamond formation (2011)
  • Author(s): Shatskiy, A., Litasov, K. D., Sharygin, I., Ohtani, E.
  • Organizer: Japan Geoscience Union Meeting
  • Place of Presentation: Makuhari, Japan
  • Year and Date: 20110522-28
• [Presentation] Melting phase relations of modelalkali carbonatite systems at 3-21 GPa and implication to mantle metasomatism (2010)
  • Author(s): Litasov, K. D., Shatskiy, A., Ohtani, E.
  • Organizer: 51th High-Pressure Conference of Japan
  • Place of Presentation: 仙台
  • Year and Date: 20101020-22
• [Presentation] Pressless split-sphere apparatus equipped with scaled-up Kawai-cell for mineralogical studiesat 10-20 GPa (2010)
  • Author(s): Shatskiy, A., Borzdov, Y. M., Litasov, K. D., Ohtani, E., Palyanov, Y. M., Katsura, T.
  • Organizer: 51th High-Pressure Conference of Japan
  • Place of Presentation: 仙台
  • Year and Date: 20101020-22
• [Presentation] Dissolution-precipitation as a possible mechanism for C-O-H fluid transport in the mantle (2010)
  • Author(s): Shatskiy, A. F., Litasov, K. D., Borzdov, Y. M., Katsura, T., Ohtani, E.
  • Organizer: XVI All-Russian Conference on Experimental Mineralogy
  • Place of Presentation: チェルノゴロフカ, ロシア
  • Year and Date: 20100921-23
• [Presentation] Carbonate-silicate-Fe-metal reactions and stabilityof C-O-H species in the Earth's mantle (2010)
  • Author(s): Litasov, K. D., Shatskiy, A., Terasaki, H., Ohtani, E.
  • Organizer: Dynamic Earth and Heterogenous Structure, Global Center Of Excellence Symposium
  • Place of Presentation: 仙台
  • Year and Date: 20100713-15
• [Presentation] Seacrh for the driving force for fluid migration through the deep mantle (2010)
  • Author(s): Shatskiy, A., Litasov, K. D., Borzdov, Y. M., Katsura, T., Ohtani, E.
  • Organizer: Dynamic Earth and Heterogenous Structure, Global Center Of Excellence Symposium
  • Place of Presentation: 仙台
  • Year and Date: 20100713-15
• [Presentation] Carbon-silicate-Fe-metal reactions at highpressures : New experimental constraints on deep volatile cycles (2010)
  • Author(s): Litasov, K. D., Shatskiy, A., Terasaki, H., Ohtani, E., Fei, Y.
  • Organizer: 2010Japan Geoscience Union Meeting
  • Place of Presentation: 千葉
  • Year and Date: 20100523-28
• [Presentation] Incipient fluid migration through thedeep mantle by dissolution-precipitation : crystal growth constraints (2010)
  • Author(s): Shatskiy, A., Litasov, K. D., Borzdov, Y. M., Katsura, T., Ohtani, E.
  • Organizer: eting
  • Place of Presentation: 千葉
  • Year and Date: 20100523-28
• [Presentation] Experimental study of carbonate-silicate-metal equilibriaat pressures to 30 GPa : New insights into deep volatile cycles (2010)
  • Author(s): Litasov, K. D., Shatskiy, A., Fei, Y., Ohtani, E.
  • Organizer: European Geoscience Union, 2010 General Assembly
  • Place of Presentation: ウィーン、オーストリア
  • Year and Date: 20100502-07
• [Presentation] Incipient fluid migration through thedeep mantle by dissolution-precipitation : crystal growth constraint (2010)
  • Author(s): Shatskiy, A., Litasov, K. D., Borzdov, Y. M., Katsura, T., Ohtani, E.
  • Organizer: European Geoscience Union, 2010 General Assembly
  • Place of Presentation: ウィーン、オーストリア
  • Year and Date: 20100502-07