2012 Fiscal Year Final Research Report
Transformation of functional π-conjugated molecules into open-shell state
| Project/Area Number |
22750036
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
HIROTO Satoru 名古屋大学, 工学研究科, 助教 (30547427)
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| Project Period (FY) |
2010 – 2012
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| Keywords | ラジカル / ポルフィリン / 多環芳香族炭化水素 / シクロファン |
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| Research Abstract |
We developed efficient method for introduction of various functionalities toward hexa-peri-hexabenzocoronenes. Second, we discovered that oxidation of amino-substituted porphyrins provided pyrazine-fused dimers in excellent yield with high regioselectivity. The pyrazine-fused dimers were also obtained by oxidation of amino-substituted anthracenes. In this case, pyrrole-fused dimer with helical conformation was obtained. Furthermore, oxidation of dihydroxyanthracenes afforded highly distorted [2.2]metacyclophanes.
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