Creation of Alkaline IonConductor with Metal-OrganicFrameworks Having Acidic Functional Groups by Protection and Deprotection Method

2012 Fiscal Year Final Research Report

• Project/Area Number: 22750053
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Single-year Grants
• Research Field: Inorganic chemistry
• Research Institution: Kyushu University (2012); Kyoto University (2010-2011)
• Principal Investigator: YAMADA Teppei 九州大学, 大学院・工学研究院, 准教授 (10404071)
• Project Period (FY): 2010 – 2012
• Keywords: 配位高分子 / 保護-脱保護法 / イオン伝導

Research Abstract

Novel method for introducinc acidic functional groups was invented onto the inner surface of the metal-organic frameworks. Acidic functional groups were protected by organc group, which were reacted with metal ions to obtainnovel MOFs havinc acidic functional groups. We also succeeded in introducing various kinds of ionic species and also in finding MOFs showing high ionic conductivity

Research Products

• [Journal Article] Preparation of Sub-10 nm AgI Nanoparticles and a Study on their Phase Transition Temperature (2013)
  • Author(s): Yamasaki Shuhei、Yamada Teppei、Kobayashi Hirokazu、Kitagawa Hiroshi
  • Journal Title: Chem.-Asian J. Volume: Vo l. 8、No. 1 Pages: 73-75
  • DOI: DOI:10.1002/asia.201200790
  • URL: http://dx.doi.org/10.1002/asia.201200790
  • Peer Reviewed
• [Journal Article] Superprotonic Conductivity in a Highly Oriented Crystalline Metal-Organic Framework Nanofilm (2013)
  • Author(s): Xu Gang、Otsubo Kazuya、Yamada Teppei、Sakaida Shun 、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 1 3 5、No. 20 Pages: 7438-7441
  • DOI: DOI:10.1021/ja402727d
  • URL: http://dx.doi.org/10.1021/ja402727d
  • Peer Reviewed
• [Journal Article] Proton-Conductive Magnetic Metal-Organic Frameworks, {NR3(CH2COOH)}[MaIIMbIII(ox)3]: Effect of Carboxyl Residue upon Proton Conduction (2013)
  • Author(s): Okawa Hisashi、Sadakiyo Masaaki、Yamad a Teppei、Maesato Mitsuhiko、Ohba Masaaki、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 1 3 5、No. 6 Pages: 2256-2262
  • DOI: DOI:10.1021/ja309968u
  • Peer Reviewed
• [Journal Article] Graphene Oxide Nanosheet with High Proton Conductivity (2013)
  • Author(s): Karim Mohammad Razaul、Hatakeyama Kazuto、Matsui Takeshi、Takehira Hiroshi、Taniguchi Takaaki、Koinuma Michio、Matsumoto Yasumichi、Akutagawa Tomoyuki、Nakamura Takayoshi、Noro Shin-ichiro、Yamada Teppei、Kitagawa Hiroshi、Hayami Shinya
  • Journal Title: J. Am. Chem. Soc.
  • DOI: DOI:10.1021/ja401060q
  • URL: http://dx.doi.org/10.1021/ja401060q
• [Journal Article] A Key Mechanism of Ethanol Electrooxidation Reaction in a Noble-Metal-Free Metal-Organic Framework (2013)
  • Author(s): Ishimoto Takayoshi、Ogura Teppei、Koyama Michihisa、Yang Lifen、Kinoshita Shozo、Yamada Teppei、Tokunaga Makoto、Kitagawa Hiroshi
  • Journal Title: J. Phys. Chem. C Volume: Vo l. 11 7、No. 20 Pages: 10607-10614
  • DOI: DOI:10.1021/jp4031046
  • URL: http://dx.doi.org/10.1021/jp4031046
  • Peer Reviewed
• [Journal Article] Syntheses of metal-organic frameworks with protected phosphonate ligands (2012)
  • Author(s): Yamada Teppei、Kitagawa Hiroshi
  • Journal Title: CrystEngComm Volume: Vo l. 1 4、No. 12 Pages: 4148-4152
  • URL: http://dx.doi.org/10.1039/C2CE25358E
  • Peer Reviewed
• [Journal Article] Facile "Modular Assembly" for Fast Construction of a Highly Oriented Crystalline MOF Nanofilm (2012)
  • Author(s): Xu Gang、Yamad a Tepp ei、Otsubo Kazuya、Sakaida Shun、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vol. 134、No. 40 Pages: 16524-16527
  • DOI: DOI:10.1021/ja307953m
  • URL: http://dx.doi.org/10.1021/ja307953m
  • Peer Reviewed
• [Journal Article] Selective Separation of Water, Methanol, and Ethanol by a Porous Coordination Polymer Built with a Flexible Tetrahedral Ligand (2012)
  • Author(s): Shigematsu Akihito、Yamad a Tepp ei、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vol. 134、No. 32 Pages: 13145-13147
  • DOI: DOI:10.1021/ja306401j
  • URL: http://dx.doi.org/10.1021/ja306401j
  • Peer Reviewed
• [Journal Article] High Proton Conductivity by a Metal-Organic Framework Incorporating Zn8O Clusters with Aligned Imidazolium Groups Decorating the Channels (2012)
  • Author(s): Sen Susan、Nair Nisanth N.、Yamada Teppei、Kitagawa Hiroshi、Bharadwaj Parimal K.
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 1 3 4、No. 47 Pages: 19432-19437
  • DOI: DOI:10.1021/ja3076378
  • URL: http://dx.doi.org/10.1021/ja3076378
  • Peer Reviewed
• [Journal Article] Promotion of Low-Humidity Proton Conduction by Controlling Hydrophilicity in Layered Metal-Organic Frameworks (2012)
  • Author(s): Sadakiyo Masaaki 、Okawa Hisashi、Shigematsu Akihito、Ohba Masaaki、Yamad a Teppei、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vol. 134、No. 12 Pages: 5472-5475
  • DOI: DOI:10.1021/ja300122r
  • Peer Reviewed
• [Journal Article] Quasi-Elastic Neutron Scattering Studies on Dynamics of Water Confined in Nanoporous Copper Rubeanate Hydrates (2011)
  • Author(s): Yamada Takeshi、Yonamine Ryo、Yamad a Teppei、Kitagawa Hiroshi、Tyagi Madhusudan、Nagao Michihiro、Yamamuro Osamu
  • Journal Title: J. Phys. Chem. B Volume: Vo l. 11 5、No. 46 Pages: 13563-13569
  • DOI: DOI:10.1021/jp2029467
  • URL: http://dx.doi.org/10.1021/jp2029467
  • Peer Reviewed
• [Journal Article] Synthesis of a novel isoreticular metal-organic framework by protection and complexation of 2,5-dihydroxyterephthalic acid (2011)
  • Author(s): Yamada Teppei、Kitagawa Hiroshi
  • Journal Title: Supramol. Chem. Volume: Vo l. 2 3、No. 3-4 Pages: 315-318
  • DOI: DOI:10.1080/10610278.2010.531138
  • URL: http://dx.doi.org/10.1080/10610278.2010.531138
  • Peer Reviewed
• [Journal Article] Porous Interpenetrating Metal-Organic Frameworks with Hierarchical Nodes (2011)
  • Author(s): Yamada Teppei、Iwakiri Shoji、Hara Takafumi、Kanaizuka Katsuhiko、Kurmoo Mohamedally、Kitagawa Hiroshi
  • Journal Title: Cryst. Growth Des. Volume: Vo l. 11、No. 5 Pages: 1798-1806
  • DOI: DOI:10.1021/cg1017278
  • URL: http://dx.doi.org/10.1021/cg1017278
  • Peer Reviewed
• [Journal Article] Structure manufacturing of proton-conducting organic-inorganic hybrid silicophosphite membranes by solventless synthesis (2011)
  • Author(s): Tokuda Yomei、Oku Satoshi、Yamada Teppei、Takahashi Masahide、Yoko Toshinobu、Kitagawa Hiroshi、Ueda Yoshikatsu
  • Journal Title: J. Mater. Res. Volume: Vo l. 2 6、No. 6 Pages: 796-803
  • DOI: DOI:10.1557/jmr.2010.89
  • Peer Reviewed
• [Journal Article] Wide Control of Proton Conductivity in Porous Coordination Polymers (2011)
  • Author(s): Shigematsu Akihito、Yamad a Tepp ei、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 133、No. 7 Pages: 2034-2036
  • DOI: DOI:10.1021/ja109810w
  • URL: http://dx.doi.org/10.1021/ja109810w
  • Peer Reviewed
• [Journal Article] Hydroxyl Group Recognition by Hydrogen-Bonding Donor and Acceptor Sites Embedded in a Layered Metal-Organic Framework (2011)
  • Author(s): Sadakiyo Masaaki、Yamada Teppei、Kitagawa Hiroshi
  • Journal Title: J. Am. Chem. Soc. Volume: Vo l. 133、No. 29 Pages: 11050-11053
  • DOI: DOI:10.1021/ja203291n
  • URL: http://pubs.acs.org/doi/abs/10.1021/ja203291n
  • Peer Reviewed
• [Journal Article] A Metal-Organic Framework as an Electrocatalyst for Ethanol Oxidation (2010)
  • Author(s): Yang Lifen、Kinoshita Shozo、Yamada Teppei、Kanda Seiichi、Kitagawa Hiroshi、Tokunaga Makoto、Ishimoto Takayoshi、Ogura Teppei、Nagumo Ryo、Miyamoto Akira、Koyama Michihisa
  • Journal Title: Angew. Chem. Int. Ed. Volume: Vo l. 4 9、No. 31 Pages: 5348-5351
  • DOI: DOI:10.1002/anie.201000863
  • URL: http://dx.doi.org/10.1002/anie.201000863
  • Peer Reviewed
• [Journal Article] Calorimetric and Neutron Diffraction Studies on Transitions of Water Confined in Nanoporous Copper Rubeanate (2010)
  • Author(s): Yamada Takeshi、Yonamine Ryo、Yamad a Teppei、Kitagawa Hiroshi、Yamamuro Osamu
  • Journal Title: J. Phys. Chem. B Volume: Vo l. 1 1 4、No. 25 Pages: 8405-8409
  • DOI: DOI:10.1021/jp912212m
  • URL: http://dx.doi.org/10.1021/jp912212m
  • Peer Reviewed
• [Journal Article] Structures and Proton Conductivity of One-Dimensional M(dhbq)・nH2O (M = Mg, Mn, Co, Ni, and Zn, H2(dhbq) = 2,5-Dihydroxy-1,4-benzoquinone) Promoted by Connected Hydrogen-Bond Networks with Absorbed Water (2010)
  • Author(s): Yamada Teppei、Morikawa Shota、Kitagawa Hiroshi
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: Vo l. 8 3、No. 1 Pages: 42-48
  • DOI: DOI:10.1246/bcsj.20090216
  • URL: http://www.jstage.jst.go.jp/article/bcsj/83/1/83_42/_article
  • Peer Reviewed
• [Journal Article] Design and Characterization of a Polarized Coordination Polymer of a Zinc(II) Biphenyldicarboxylate Bearing a Sulfone Group (2010)
  • Author(s): Kanaizuka Katsuhiko、Iwakiri Shoji、Yamad a Teppei、Kitagawa Hiroshi
  • Journal Title: Chem. Lett. Volume: Vo l. 3 9、No. 1 Pages: 28-29
  • DOI: DOI:10.1246/cl.2010.28
  • URL: http://www.jstage.jst.go.jp/article/cl/39/1/39_28/_article
  • Peer Reviewed
• [Book] Metal-Organic Frameworks: Materials, Properties and Applications (2012)
  • Author(s): Yamada Teppei、Kitagawa Hiroshi
  • Total Pages: 277-290
  • Publisher: eds. O. L. Ortiz and L. D. Ramirez, Nova publishers
• [Book] Bull. Chem. Soc. Coord. Chem. Vol . 60 (2012)
  • Author(s): 山田 鉄兵
  • Total Pages: 45-47
• [Book] 現代化学 Vol. 493、No. 4 (2012)
  • Author(s): 山田 鉄兵、北川 宏
  • Total Pages: 44-45
• [Book] 化学同人 Vol . 66 (2011)
  • Author(s): 山田 鉄兵、北川 宏
  • Total Pages: 36-41
• [Book] 触媒技術の動向と展望 Vol. 2011 (2011)
  • Author(s): 山田 鉄兵、北川 宏、牧浦 理恵
  • Total Pages: 81-89
• [Book] 東京化学同人 Vol . 478 (2011)
  • Author(s): 山田 鉄兵、木下 昌三、北川 宏
  • Total Pages: 50-54
• [Book] 京都大学低温物質科学研究センター誌 Vol . 17 (2010)
  • Author(s): 山田 鉄兵
  • Total Pages: 3-9
  • Publisher: 京都大学低温物質科学センター
• [Book] 空間を持つ機能性物質の創成 Vol . 3 (2010)
  • Author(s): 山田 鉄兵、北川 宏
  • Total Pages: 59-62
• [Book] Bulletin of the Ceramic Society of Japan Vol . 45 (2010)
  • Author(s): 山田 鉄兵、木下 昌三、北川 宏
  • Total Pages: 930
  • Publisher: 日本セラミックス協会
• [Remarks] 受賞 1. 第62回進歩賞(日本化学会) 酸性配位高分子を用いたプロトン伝導体の創成、2013年3月
• [Remarks] 受賞 2. 錯体化学会研究奨励賞(錯体化学会) 配位高分子を用いたプロトン伝導体の創成、2012年9月
• [Remarks] 受賞 3. 第1回新化学技術研究奨励賞(新化学技術推進協会)課題2:世界に先駆ける新製品開発に資する「新素材」実現のための基礎的・基盤的研究 細孔内物質の相転移コントロールによる「漏れない液体」、2012年5月25日
• [Remarks]
  • URL: http://www.chem.kyushu-u.ac.jp/~kimizuka/
• [Remarks]
  • URL: http://www.chem.kyushu-u.ac.jp/~cms/