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2011 Fiscal Year Final Research Report

Organic Solar Cell Fabrication Based on Nanoporous Semiconducting Polymer Films

Research Project

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Project/Area Number 22750100
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

HIGASHIHARA Tomoya  東京工業大学, 大学院・理工学研究科, 助教 (50504528)

Project Period (FY) 2010 – 2011
Keywordsブロック共重合体 / イオン結合 / 自己組織化 / ミクロ相分離 / 有機薄膜太陽電池
Research Abstract

In this project, the fundamental studies on improvements of organic solar cell performance were targeted. The active layer of an organic solar cell consists of a blend system of p-type and n-type semiconductors. Due to the unclear nanostructures of p/n blend morphology, the energy conversion efficiency(PCE) of the organic cells has not been improved yet. The preparation of nanoporous semiconductor films was succeeded based on the template system of block copolymers. Based on the control of nanostructures, enhancement of PCE and stability of organic solar cells could be achieved.

  • Research Products

    (17 results)

All 2012 2011 2010

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (7 results) Book (1 results)

  • [Journal Article] Synthesis and Caracterization of Novel Polythiophenes with Graphene-like Structures via Intramolecular Oxidative Coupling2012

    • Author(s)
      Ayumi Takahashi, Chih-Jung Lin, Kaoru Ohshimizu, Tomoya Higashihara, Wen-Chang Chen, and Mitsuru Ueda
    • Journal Title

      Polym. Chem.

      Volume: 3 Pages: 479-485

    • Peer Reviewed
  • [Journal Article] Enhancement of Power Conversion Efficiency and Long-term Stability ofP3HT/PCBM Solar Cells Using C_60 Derivatives with Thiophene Units as Surfactants2012

    • Author(s)
      Yi-Cang Lai, Tomoya Higashihara, Jung-Ching Hsu, Mitsuru Ueda, Wen-Chang Chen
    • Journal Title

      Solar Eng. Mater. Solar Cells

      Volume: 97 Pages: 164-170

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Block Copolythiophene with Hexyl and Triethylene Glycol Side Chains2011

    • Author(s)
      Tomoya Higashihara, Kaoru Ohshimizu, Yecheol Ryo, Takuya Sakurai, Ayumi Takahashi, Shuichi Nojima, Moonhor Ree, and Mitsuru Ueda
    • Journal Title

      Polymer

      Volume: 52 Pages: 3687-3695

    • Peer Reviewed
  • [Journal Article] Synthesis of Poly(m-phenylene) and Poly(m-phenylene)-block-poly(3-hexylthiophene) with Low Polydispersities2011

    • Author(s)
      Kaoru Ohshimizu, Ayumi Takahashi, Tomoya Higashihara, and Mitsuru Ueda
    • Journal Title

      J. Polym. Sci., Part A : Polym. Chem

      Volume: 49 Pages: 2709-2714

    • Peer Reviewed
  • [Journal Article] Synthesis of All-conjugated Poly(3-hexylthiophene)-block-poly(3-(4'-(3'', 7''-dimethyloctyloxy)-3'-pyridinyl) thiophene) and Its Blend for Photovoltaic Applications2011

    • Author(s)
      Yi-Cang Lai, Kaoru Ohshimizu, Ayumi Takahashi, Jung-Ching Hsu, Tomoya Higashihara, Mitsuru Ueda, and Wen-Chang Chen
    • Journal Title

      J. Polym. Sci., Part A : Polym. Chem

      Volume: 49 Pages: 2577-2587

    • Peer Reviewed
  • [Journal Article] Synthesis of Novelπ-Conjugated Rod-rod-rod Triblock Copolymers Containing Poly(3-hexylthiophene) and Polyacetylene Segments by Combination of Quasi-living GRIM and Living Anionic Polymerization2011

    • Author(s)
      Tomoya Higashihara, Cheng-Liang Liu, Wen-Chang Chen, and Mitsuru Ueda
    • Journal Title

      Polymers

      Volume: 3 Pages: 236-251

    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Polythiophenes Bearing Aromatic Groups at the 3-Position2011

    • Author(s)
      Kaoru Ohshimizu, Ayumi Takahashi, Yecheol Rho, Tomoya Higashihara, Moonhor Ree, and Mitsuru Ueda
    • Journal Title

      Macromolecules

      Volume: 44 Pages: 719-727

    • Peer Reviewed
  • [Journal Article] 題目: Enhancement of P3HT/PCBM Photovoltaic Efficiency Using the Surfactant of Triblock Copolymer Containing Poly(3-hexylthiophene) and Poly(4-vinyltriphenylamine) Segments2010

    • Author(s)
      Jung-Hsun Tsai, Yi-Cang Lai, Tomoya Higashihara, Chih-Jung Lin, Mitsuru Ueda, and Wen-Chang Chen
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 6085-6091

    • Peer Reviewed
  • [Journal Article] Preparation of Nanoporous Poly(3-hexylthiophene) Films Based on a Template System of Block Copolymers via Ionic Interaction2010

    • Author(s)
      Ayumi Takahashi, Yecheol Rho, Tomoya Higashihara, Byungcheol Ahn, Moonhor Ree, and Mitsuru Ueda
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 4843-4852

    • Peer Reviewed
  • [Presentation] ENHANCEMENT OF PCE AND LONG-TERM STABILITY OF P3HT : PCBM OPV CELLS USING BLOCK COPOLYTHIOPHENES2011

    • Author(s)
      Tomoya Higashihara, Yi-Cang Lai, Wen-Chang Chen, Mitsuru Ueda
    • Organizer
      21st International Photovoltaic Science and Engineering Conference(PVSEC-21)
    • Place of Presentation
      福岡市(福岡県)
    • Year and Date
      2011-11-27
  • [Presentation] 新規ポリチオフェンブロック共重合体の合成と有機薄膜太陽電池への応用2011

    • Author(s)
      東原知哉, Yi-Cang Lai, Wen-Chang Chen,上田充
    • Organizer
      第20回ポリマー材料フォーラム(招待講演)
    • Place of Presentation
      タワーホール船掘(東京都)
    • Year and Date
      2011-11-25
  • [Presentation] ポリ(3-ヘキシルチオフェン)鎖を有する新規ブロック共重合体の合成と有機薄膜太陽電池への応用2011

    • Author(s)
      東原知哉, Yi-Cang Lai, Wen-Chang Chen,上田充
    • Organizer
      第60回高分子討論会(招待講演)
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2011-09-30
  • [Presentation] Mitsuru Ueda Enhancement of P3HT/PCBM Photovoltaic Efficiency and Stability Based on Surfactant Approach2011

    • Author(s)
      Tomoya Higashihara, Yi-Cang Lai, Jung-Hsun Tsai, Wen-Chang Chen
    • Organizer
      2011 IUMRS International Conference in Asia(招待講演)
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2011-09-21
  • [Presentation] Synthesis of regioregular poly(3-hexylthiophene) with low polydispersity using a zincate complex, tBu4ZnLi2 : Toward a purification-free system2011

    • Author(s)
      Tomoya Higashihara
    • Organizer
      2011 Taiwan-Japan Bilateral Polymer Symposium(招待講演)
    • Place of Presentation
      新竹(台湾)
    • Year and Date
      2011-09-15
  • [Presentation] Controlled Synthesis of Poly(3-hexylthiophene) Using Zincate Complex2011

    • Author(s)
      Tomoya Higashihara, Mitsuru Ueda
    • Organizer
      European Polymer Congress 2011
    • Place of Presentation
      グラナダ(スペイン)
    • Year and Date
      2011-06-26
  • [Presentation] Electrically Bistable Memory Devices Based on Poly(3-hexylthiophene)-block-poly(3-phenoxythiophene) and Its PCBM Composite Films2011

    • Author(s)
      Yi-Cang Lai, Kaoru Ohshimizu, Wen-Ya Lee, Tomoya Higashihara, Mitsuru Ueda, Wen-Chang Chen
    • Organizer
      European Polymer Congress 2011
    • Place of Presentation
      グラナダ(スペイン)
    • Year and Date
      2011-06-26
  • [Book] Block Copolymers Containing Rod Segments2011

    • Author(s)
      Tomoya Higashihara, Mitsuru Ueda John Wiley & Sons
    • Total Pages
      395-429
    • Publisher
      Complex Macromolecular Architecture, Chapter 13

URL: 

Published: 2013-07-31  

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