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2012 Fiscal Year Final Research Report

Development of the complementary multidentate ligands composed of anchored coordinating moieties and their applications to polymer chemistry

Research Project

  • PDF
Project/Area Number 22750108
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionKinki University (2011-2012)
Kyoto University (2010)

Principal Investigator

SHIOTSUKI Masashi  近畿大学, 分子工学研究所, 講師 (30362453)

Project Period (FY) 2010 – 2012
Keywords重合触媒
Research Abstract

A series of new multidentate coordinating compounds having dieneand hetero atom moieties were synthesized, and investigated as for its functionality. In thecase of introduction of chiral moieties on the hetero atoms, predominantly one-handedhelical polymers were successfully formed.

  • Research Products

    (13 results)

All 2013 2012 2011 2010

All Journal Article (3 results) Presentation (10 results)

  • [Journal Article] Helix-sense-selective Polymerization of Achiral Acetylene Monomer Catalyzed by Rh Zwitterionic Complexes with Tethered Chiral Amino and Ether Groups2013

    • Author(s)
      Naoya Onishi, Toshiki Aoki, Takashi Kaneko, Masahiro Teraguchi, Natsuhiro Sano, Toshio Masuda, Masashi Shiotsuki, Fumio Sanda
    • Journal Title

      Chemistry Letters

      Volume: 42 Pages: 278-280

  • [Journal Article] Polymerization of Phenylacetylenes Using Rhodium Catalysts Coordinated by N orbornadiene Linked to a Phosphino or Amino Group2013

    • Author(s)
      Naoya Onishi, Masashi Shiotsuki, Toshio Masuda, Natsuhiro Sano, Fumio Sanda
    • Journal Title

      Organometallics

      Volume: 32 Pages: 846-853

  • [Journal Article] olecular w eight dependence of helical conformation of amino acid-based polyphenylacetylenes2011

    • Author(s)
      Masashi Shiotsuki, Shohei Kumazawa, N aoya Onishi, Fumio Sanda
    • Volume
      49
    • Pages
      4921-4925
  • [Presentation] Well-defined重合触媒を用いたらせん置換ポリアセチレンの合成2012

    • Author(s)
      塩月雅士
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Year and Date
      2012-09-19
  • [Presentation] Synthesis of Pre dominantly One-Handed Helical Polyacet ylenes by the Transition Metal Catalyzed Polymerization of Achiral Monomers in the Presence of Chiral Compounds2012

    • Author(s)
      Jesus Rodriguez Castanon・Fumio Sanda・Masashi Shiotsuki
    • Organizer
      第61回高分子学会年次大会[photograph]
    • Place of Presentation
      パシフィコ横浜(神奈川県)
    • Year and Date
      2012-05-31
  • [Presentation] 機能性多座配位子を有するRh錯体の置換アセチレン重合に対する触媒活性2011

    • Author(s)
      尾西尚弥・塩月雅士・三田文雄・青木俊樹・増田俊夫
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2011-09-30
  • [Presentation] 光学活性フェニルアセチレン誘導体のリビング重合と生成ポリマーのらせん構造に及ぼす分子量の効果2011

    • Author(s)
      熊澤頌平・尾西尚弥・塩月雅士・三田文雄
    • Organizer
      第60回高分子討論会
    • Place of Presentation
      岡山大学(岡山県)
    • Year and Date
      2011-09-29
  • [Presentation] Single Chiral Source Based Helicity Control in t he Helix-Sense-Selective Polymerization of Bis(hydroxymethyl)phenylacetylene Deri vative2011

    • Author(s)
      Jesus RODRIGUEZ CASTANON, Masash i SHIOTSUKI, Fumio SANDA
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2011-05-26
  • [Presentation] 機能性多座配位子を有するロジウム触媒による置換アセチレンの重合2011

    • Author(s)
      尾西尚弥, 塩月雅士, 三田文雄, 増田俊夫
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2011-05-25
  • [Presentation] 分子量の制御された光学活性ポリフェニルアセチレン誘導体の合成とらせん持続長に関する研究2011

    • Author(s)
      熊澤頌平, 塩月雅士, 三田文雄
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2011-05-25
  • [Presentation] ontrolled polymerization of acetylenic m onomers catalyzed by late transition met al complexes2010

    • Author(s)
      塩月雅士・尾西尚弥・三田文雄・増田俊夫
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      米国、ハワイ、ホノルル
    • Year and Date
      2010-12-18
  • [Presentation] Development of rhodium complexes beari ng a tetrafluorobenzobarrelene ligand for the polymerization of phenylacetylene2010

    • Author(s)
      尾西尚弥・塩月雅士・三田文雄・増田俊夫
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      米国、ハワイ、ホノルル
    • Year and Date
      2010-12-18
  • [Presentation] 多座配位子を有するRh触媒を用いた置換アセチレンの重合2010

    • Author(s)
      尾西尚弥・塩月雅士・三田文雄・増田俊夫
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2010-09-15

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Published: 2014-08-29  

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