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2011 Fiscal Year Final Research Report

Nano-scale photophysical processes occurring within single conjugated polymer molecules revealed by super-resolution fluorescence microscopy

Research Project

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Project/Area Number 22750122
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

HABUCHI Satoshi  東京工業大学, 大学院・理工学研究科, 准教授 (80503789)

Project Period (FY) 2010 – 2011
Keywords光物性
Research Abstract

Photophysical processes occurring within optoelectronic materials play a crucial role in designing optoelectronic devices. It has been impossible to visualize the photophysical processes directly since these processes generally occur in a spatial size of nanometers to tens of nanometer which cannot be resolved by conventional optical microscopy technique. In this study, we developed a new fluorescence microscopy technique which has a nanometer spatial resolution. Using the technique, we visualized nano-scale exciton migration and localization in conjugated polymer molecules. We demonstrated that the exciton can migrate along the polymer chains up to 70nm, which is much longer than previously expected distances.

  • Research Products

    (42 results)

All 2011 2010

All Journal Article (13 results) (of which Peer Reviewed: 12 results) Presentation (29 results)

  • [Journal Article] Twist angle plays an important role in photophysical properties of a donor-acceptor-type conjugated polymer : A combined ensemble and single-molecule study2011

    • Author(s)
      Habuchi S, Fujita H, Michinobu T, Vacha M.
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY B

      Volume: 115 Pages: 14404-14415

    • Peer Reviewed
  • [Journal Article] Complete suppression of blinking and reduced photobleaching in single MEH-PPV chains in solution2011

    • Author(s)
      Onda S, Kobayashi H, Hatano T, Furumaki S, Habuchi S, Vacha M.
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY LETTERS

      Volume: 2 Pages: 2827-2831

    • Peer Reviewed
  • [Journal Article] Nanoscale dynamic in homogeneities in electroluminescence of conjugated polymers2011

    • Author(s)
      Hatano T, Nozue S, Habuchi S, Vacha M.
    • Journal Title

      JOURNAL OF APPLIED PHYSICS

      Volume: 110 Pages: 053111

    • Peer Reviewed
  • [Journal Article] π共役系高分子のコンフォメーションと光物性2011

    • Author(s)
      Habuchi S
    • Journal Title

      KOGYO ZAIRYO

      Pages: 1284-1288

  • [Journal Article] Control of orientation of rhodamine 6G in organic-inorganic hybrid film by capillary electrophoresis doping technique2011

    • Author(s)
      Taguchi J, Yano T, Habuchi S, Vacha M, Shibata S.
    • Journal Title

      THIN SOLID FILMS

      Volume: 519 Pages: 6106-6109

    • Peer Reviewed
  • [Journal Article] Absorption linear dichroism measured directly on a single light-harvesting system : The role of disorder in chlorosomes of green photosynthetic bacteria2011

    • Author(s)
      Furumaki S, Vacha F, Habuchi S, Tsukatani Y, Bryant DA, Vacha M.
    • Journal Title

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

      Volume: 133 Pages: 6703-6710

    • Peer Reviewed
  • [Journal Article] Structural conformation and photophysical properties of conjugated polymer molecules2011

    • Author(s)
      Habuchi S, Vacha M.
    • Journal Title

      KOBUNSHI

      Volume: 60 Pages: 58-61

    • Peer Reviewed
  • [Journal Article] Molecular weight dependence of emission intensity and emitting sites distribution within single conjugated polymer molecules2011

    • Author(s)
      Habuchi S, Onda S, Vacha M.
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 13 Pages: 1743-1753

    • Peer Reviewed
  • [Journal Article] Multi-beam single-molecule defocused fluorescence imaging reveals local anisotropic nature of polymer thin films2011

    • Author(s)
      Habuchi S, Oba T, Vacha M.
    • Journal Title

      PHYSICAL CHEMISTRY CHEMICAL PHYSICS

      Volume: 13 Pages: 6970-6976

    • Peer Reviewed
  • [Journal Article] Blinking of single dye molecules in a polymer matrix is correlated with free volume in polymers2011

    • Author(s)
      Suzuki K, Habuchi S, Vacha M.
    • Journal Title

      CHEMICAL PHYSICS LETTERS

      Volume: 505 Pages: 157-160

    • Peer Reviewed
  • [Journal Article] Uncoupling of sister replisomes during eukaryotic DNA replication2010

    • Author(s)
      Yardimci H, Loveland AB, Habuchi S, van Oijen AM, Walter JC.
    • Journal Title

      MOLECULAR CELL

      Volume: 40 Pages: 834-840

    • Peer Reviewed
  • [Journal Article] Conformation and physics of polymer chains : a single-molecule perspective2010

    • Author(s)
      Vacha M, Habuchi S.
    • Journal Title

      NPG ASIA MATERIALS

      Volume: 2 Pages: 134-142

    • Peer Reviewed
  • [Journal Article] Photophysics of the red chromophore of HcRed : Evidence for cis-trans isomerization and protonation-state changes2010

    • Author(s)
      Mudalige K, Habuchi S, Goodwin PM, Pai RK, De Schryver F, Cotlet.
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY B

      Volume: 114 Pages: 4678-4685

    • Peer Reviewed
  • [Presentation] 励起子ダイナミクスのナノイメージング:共役蛍高分子を用いた研究2011

    • Author(s)
      羽渕聡史・バッハマーティン
    • Organizer
      第5回分子科学討論会2011(2011)
    • Place of Presentation
      札幌
    • Year and Date
      20110920-23
  • [Presentation] 共役系高分子-ブロックコポリマーハイブリッド材料の作製及び光物性の評価2011

    • Author(s)
      本望圭紘・大澤祐太・羽渕聡史・羽多野慎悟・彌田智一・バッハマーティン
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] 光吸収異方性測定による緑色硫黄細菌とその変異体が有する単一光捕集複合体の研究2011

    • Author(s)
      古牧周・バッハフランティセク・羽渕聡史・塚谷祐介・ブライアントドナルド・バッハマーティン
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] 超解像イメージングに向けたAtto色素の光物理ダイナミクスの研究2011

    • Author(s)
      屋比久裕・羽渕聡史・バッハマーティン
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] オリゴフェニレンビニレン誘導体単一鎖の構造と蛍光スペクトルの相関2011

    • Author(s)
      小林裕之・羽渕聡史・荻野賢司・バッハマーティン
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] 単一分子の配向・位置計測を用いた高分子薄膜物性解析2011

    • Author(s)
      大場達也・羽渕聡史・バッハマーティン
    • Organizer
      2011年光化学討論
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] 蛍光顕微分光および単一分子計測による有機EL素子のナノスケール評価2011

    • Author(s)
      羽田野龍彦・羽渕聡史・バッハマーティン
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] Conformation and photophysics of single chains of conjugated polymers : Why are they blinking2011

    • Author(s)
      Vacha M. Kobayashi H, Habuchi S, Onda S.
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] Nanoscale visualization of exciton dynamics in single conjugated polymer molecules2011

    • Author(s)
      Habuchi S, Vacha M.
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08
  • [Presentation] Multimode diffusion of ring polymer molecules revealed by a single-molecule study2011

    • Author(s)
      Habuchi S, Satoh N, Yamamoto T, Tezuka Y, Vacha M.
    • Organizer
      XXV International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      20110807-12
  • [Presentation] Multi-beam single-molecule defocused fluorescence imaging reveals nanoscale anisotropic nature of polymer thin film2011

    • Author(s)
      Oba T, Habuchi S, Vacha M.
    • Organizer
      XXV International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      20110807-12
  • [Presentation] Nanoscale characterization of conjugated polymer light emitting diodes by fluorescence micro-spectroscopy2011

    • Author(s)
      Hatano T, Habuchi S, Vacha M
    • Organizer
      XXV International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      20110807-12
  • [Presentation] Emitting sites distribution within single conjugated polymer molecules revealed by super-resolution fluorescence imaging2011

    • Author(s)
      Habuchi S, Onda S, Vacha M.
    • Organizer
      XXV International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Year and Date
      20110807-12
  • [Presentation] Single-molecule studies on polymer science2011

    • Author(s)
      Habuchi S.
    • Organizer
      TokyoTech-EPFL workshop on Materials
    • Place of Presentation
      Chateau-d' Oex, Switzerland
    • Year and Date
      20110313-16
  • [Presentation] Multimode diffusion of ring polymer molecules revealed by a single-molecule study2010

    • Author(s)
      Habuchi S, Yamamoto T, Tezuka Y, Vacha M.
    • Organizer
      The 16^<th> Takeda Science Foundation Symposium on Bioscience
    • Place of Presentation
      Tokyo
    • Year and Date
      20101201-02
  • [Presentation] Single-molecule approach to nanoscale structure and dynamics of molecular complexes : from conjugated polymers to photosynthetic light harvesting2010

    • Author(s)
      Vacha M, Habuchi S
    • Organizer
      5^<th> International Symposium on Integrated Molecular/Materials Engineering
    • Place of Presentation
      Changzhou, China
    • Year and Date
      20100920-22
  • [Presentation] Multimode diffusion of ring polymer molecules revealed by a single-molecule study2010

    • Author(s)
      Habuchi S, Yamamoto T, Tezuka Y, Vacha M.
    • Organizer
      5^<th> International Symposium on Integrated Molecular/Materials Engineering
    • Place of Presentation
      Changzhou, China
    • Year and Date
      20100920-22
  • [Presentation] 単一緑色硫黄細菌光捕集複合体の光物性解析のための吸収異方性を用いた測定手法の開発2010

    • Author(s)
      古牧周・羽渕聡史・バッハマーティン
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] ナノスケール有機材料物性解析に向けたAFM/共焦点蛍光顕微鏡同時測定法の開発2010

    • Author(s)
      野末秀穂・羽渕聡史・バッハマーティン
    • Organizer
      2010年光化学討論
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] ドナー-アクセプター型共役系高分子の単一分子分光研究2010

    • Author(s)
      羽渕聡史・道信剛志・バッハマーティン
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] 単一共役系ポリマー鎖内発光サイトの空間的移動の分子量依存性2010

    • Author(s)
      恩田賢・羽渕聡史・バッハマーティン
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] ナノシリンダーをテンプレートとした高発光効率デバイスの開発に向けて2010

    • Author(s)
      大澤祐太・バッハマーティン・羽渕聡史・彌田智一・込山英秋
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] 蛍光顕微分光による共役系高分子EL素子のナノスケール評価2010

    • Author(s)
      羽田野龍彦・羽渕聡史・バッハマーティン
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] 単一分子の3次元配向決定のための新規顕微鏡法開発2010

    • Author(s)
      大場達也・羽渕聡史・バッハマーティン
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] Multimode diffusion of ring polymer molecules revealed by a single-molecule study2010

    • Author(s)
      Habuchi S, Yamamoto T, Tezuka Y, Vacha M.
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] Structure of chlorosomal antennae of photosynthetic bacteria studied by single-molecule absorption spectroscopy2010

    • Author(s)
      Vacha M, Furumaki S, Habuchi S.
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      20100908-10
  • [Presentation] Relationship between conformation and optical properties of single conjugated polymer molecules2010

    • Author(s)
      Habuchi S, Onda S, Sugimoto T, Vacha M.
    • Organizer
      17^<th> International Conference on Dynamical Processes in Excited States of Solids
    • Place of Presentation
      Argonne, USA
    • Year and Date
      20100620-25
  • [Presentation] Absorption linear dichroism directly measured on a single light-harvesting complex of photosynthetic bacteria2010

    • Author(s)
      Vacha M, Furumaki S, Vacha F, Psencik J, Habuchi S.
    • Organizer
      17^<th> International Conference on Dynamical Processes in Excited States of Solids
    • Place of Presentation
      Argonne, USA
    • Year and Date
      20100620-25
  • [Presentation] Single-molecule studies on optical and physical properties of polymers2010

    • Author(s)
      Habuchi S.
    • Organizer
      2010 Forum of Polymer/Hybrid Materials Research Center for Young Scientists
    • Place of Presentation
      Sendai
    • Year and Date
      2010-12-06

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Published: 2013-07-31  

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