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2011 Fiscal Year Final Research Report

Dynamics of Sliding Graft Copolymer

Research Project

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Project/Area Number 22750199
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer/Textile materials
Research InstitutionThe University of Tokyo

Principal Investigator

SAKAI Yasuhiro  東京大学, 大学院・新領域創成科学研究科, 助教 (30401235)

Project Period (FY) 2010 – 2011
Keywords高分子材料物性
Research Abstract

Sliding graft copolymer (SGC) is a new type of graft copolymer whose grafting points can move along the backbone chain. SGC is obtained as a derivative of polyrotaxane, a necklace-like supramolec- ular structure. SGC is expected to exhibit unique structure and physical properties due to the mobility of the grafting points. In this study, a series of SGCs were synthesized, and the structure and dynamics of SGCs in solid state were systematically investigated by X-ray scattering and viscoelastic measurement.

  • Research Products

    (11 results)

All 2013 2012 2011 2010

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (6 results)

  • [Journal Article] シクロデキストリンを用いた環動高分子材料の構造・物性と応用2013

    • Author(s)
      酒井康博,伊藤耕三
    • Journal Title

      オレオサイエンス

      Volume: Vol. 13, No. 3 Pages: 111-116

  • [Journal Article] Struc- ture and Dynamics of Polyrotaxane-based Sliding Graft Copolymers with Alkyl Side Chains2013

    • Author(s)
      Yasuhiro Sakai, Ryojiro Gomi, Kazuaki Kato, Hideaki Yokoyama, and Kohzo Ito
    • Journal Title

      Soft Matter

      Volume: 9 Pages: 1895

    • DOI

      DOI:10.1039/c2sm27047a

    • Peer Reviewed
  • [Journal Article] Fabrication and Structural Analysis of Poly- rotaxane fibers and films2011

    • Author(s)
      Yasuhiro Sakai, Kentaro Ueda, Naoya Ka- tsuyama, Koji Shimizu, Shunya Sato, Jun Kuroiwa, Jun Araki, Akira Teramoto, Koji Abe, Hideaki Yokoyama and Kohzo Ito
    • Journal Title

      Journal of Phys- ics: Condensed Matter

      Volume: 23 Pages: 284108

    • DOI

      DOI:10.1088/0953-8984/23/28/284108

    • Peer Reviewed
  • [Journal Article] Orientational motions in mesogenic poly- rotaxane and local mode relaxations of pol- ymer segments in solid state polyrotaxane2011

    • Author(s)
      Aoi Inomata, Masatoshi Kidowaki, Yasuhiro Sakai, Hideaki Yokoyama and Kohzo Ito
    • Journal Title

      Soft Matter

      Volume: 7 Pages: 922

    • DOI

      DOI:10.1039/C0SM00930J

    • Peer Reviewed
  • [Journal Article] Crystal- linity and Cooperative Motions of Cyclic Molecules in Partially Threaded Solid-State Polyrotaxanes2010

    • Author(s)
      Aoi Inomata, Yasuhiro Sakai, et al.
    • Journal Title

      Macromolecules

      Volume: 43(10) Pages: 4660

    • DOI

      DOI:10.1021/ma100259t

    • Peer Reviewed
  • [Presentation] 「環動ゲル・エラストマーの物性と応用2013

    • Author(s)
      酒井 康博
    • Organizer
      第62回高分子学会年次大会
    • Place of Presentation
      国立京都国際会館(京都府)
    • Year and Date
      2013-05-29
  • [Presentation] アルキル側鎖を有するスライディング・グラフトコポリマーの構造と力学特性2012

    • Author(s)
      酒井 康博
    • Organizer
      第61回高分子討論会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Year and Date
      2012-09-19
  • [Presentation] Structure and Dynamics of Sliding Graft Copolymers Having Alkyl Side Chains2011

    • Author(s)
      Yasuhiro Sakai
    • Organizer
      The 12th Pacific Polymer Confer- ence (PPC12)
    • Place of Presentation
      Jeju, South Korea.
    • Year and Date
      2011-11-17
  • [Presentation] 環動ゲル・エラストマーの最近の展開2011

    • Author(s)
      酒井 康博
    • Organizer
      繊維学会 第1回若手研究 委員会
    • Place of Presentation
      花 王株式会社すみだ事業場(東京都)
    • Year and Date
      2011-08-01
  • [Presentation] Polyrotaxane elastomer with macro-crosslinker2010

    • Author(s)
      Yasuhiro Sakai
    • Organizer
      The International Chem-ical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-17
  • [Presentation] Molecular Fluctuations in Mesogenic Polyrotaxanes2010

    • Author(s)
      Yasuhiro Sakai
    • Organizer
      5th Pacific Rim Conference on Rheology (PRCR-5)
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2010-08-06

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Published: 2014-08-29  

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