2011 Fiscal Year Final Research Report
heterogeneous catalytic reaction system under microwave irradiation
| Project/Area Number |
22760598
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
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| Project Period (FY) |
2010 – 2011
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| Keywords | マイクロ波 / 非平衡局所加熱 / 固体触媒 |
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| Research Abstract |
In order to demonstrate the enhancement in the chemical reaction caused by the" nonequilibrium local heating", we have constructed a heterogeneous catalytic reaction system containing the ferromagnetic metal particle catalysts such as Ni.
First, we have successfully prepared face-centered cubic(fcc) Ni nanoparticles having long-chain amine ligands within an extremely short time under microwave irradiation. The particle sizes were controlled using several long-chain amine ligands.
We have demonstrated the enhancement in the C-C coupling reaction caused by the" nonequilibrium local heating" of the surface of the Ni particles under microwave irradiation. Dispersed ferromagnetic particles should act as a catalyst and provide with their surface as a reaction field.
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