2012 Fiscal Year Final Research Report
Development of Highly Reactive Silyl Reagents Based on HypervalentSilicon Species, and Its Application to Catalytic Reactions
| Project/Area Number |
22790014
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Chemical pharmacy
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| Research Institution | Kumamoto University |
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Principal Investigator |
KOTANI Shunsuke 熊本大学, 大学院先導機構, 特任助教 (50551280)
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| Project Period (FY) |
2010 – 2012
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| Keywords | 有機化学 / 不斉合成 / 触媒反応開発 |
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| Research Abstract |
Silyl reagents can realize a several stereoselective organicreations by forming hypervalent silicon complexes with Lewis bases. In this study,trichlorosilyl triflate as a novel silyl reagent has been found to be highly reactiveand its hypervalent silicon complex with chiral phosphine oxides provided a variety ofeffective synthetic reactions.
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