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2011 Fiscal Year Final Research Report

Measurements of nuclear-spin temperature of water molecules produced from low-temperature surface reactions

Research Project

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Project/Area Number 22840001
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Geochemistry/Astrochemistry
Research InstitutionHokkaido University

Principal Investigator

HAMA Tetsuya  北海道大学, 低温科学研究所, 助教 (20579172)

Project Period (FY) 2010 – 2011
Keywords彗星 / 星間分子雲 / アモルファス氷 / 表面 / 低温 / 原子反応 / 原子核スピン温度
Research Abstract

The present study reports measurements of nuclear-spin temperatures of thermally desorbed H_2O molecules from amorphous solid water(ASW) by combining temperature-programmed desorption and resonance-enhanced multiphoton ionization. The nuclear-spin temperature of thermally desorbed H_2O molecules from ASW prepared at 8K was almost at the statistical high-temperature limit. This result suggests that the nuclear-spin temperatures of gaseous H_2O molecules thermally desorbed from comets do not necessarily reflect the surface temperature at which H_2O molecules condensed or formed

  • Research Products

    (21 results)

All 2012 2011 2010 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results) Remarks (1 results)

  • [Journal Article] Water Formation Through a Quantum Tunneling Surface Reaction, OH+H_2, at 10K2012

    • Author(s)
      Y. Oba, N. Watanabe, T. Hama, K. Kuwahata, H. Hidaka, A. Kouchi
    • Journal Title

      Astrophys. J

      Volume: 749 Pages: 67(12)

    • Peer Reviewed
  • [Journal Article] A theoretical and experimental study on translational and internal energies of H_2O and OH from the 157 nm irradiation of amorphous solid water at 90 K2011

    • Author(s)
      S. Andersson, C. Arasa, A. Yabushita, M. Yokoyama, T. Hama, M. Kawasaki, C. M. Western, M. N. Ashfold
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 13, 35 Pages: 15810-20

    • DOI

      DOI:10.1039/C1CP21138B

    • Peer Reviewed
  • [Journal Article] Experimental studies of surface reactions among OH radicals that yield H2O and CO2 at 40-60K2011

    • Author(s)
      Y. Oba, N. Watanabe, A. Kouchi, T. Hama and V. Pirronello
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 13, 35 Pages: 15792-15797

    • Peer Reviewed
  • [Journal Article] Surface abundance change in vacuum ultraviolet photodissociation of CO2 and H2O mixture ices2011

    • Author(s)
      T. Kinugawa, A. Yabushita, M. Kawasaki, T. Hama and N. Watanabe
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 13, 35 Pages: 15785-15791

    • DOI

      DOI:10.1039/C1CP20595A

    • Peer Reviewed
  • [Journal Article] Spin Temperature of Water Molecules Desorbed from the Surfaces of Amorphous Solid Water, Vapor-deposited and Produced from Photolysis of a CH_4/O_2 Solid Mixture2011

    • Author(s)
      T. Hama, N. Watanabe, A. Kouchi, M. Yokoyama
    • Journal Title

      Astrophys. J. Lett

      Volume: 738, 1, L15 Pages: 5(pp)

    • DOI

      DOI:10.1088/2041-8205/738/1/L15

    • Peer Reviewed
  • [Journal Article] ピロネロバレリオ(2011)星間分子雲における二酸化炭素生成に関する実験的研究2011

    • Author(s)
      大場康弘, 渡部直樹, 香内晃, 羽馬哲也
    • Journal Title

      地球化学

      Volume: 45 Pages: 213-226

    • Peer Reviewed
  • [Journal Article] 157nmレーザー光照射による氷からのOHラジカルとO原子の脱離機構2010

    • Author(s)
      羽馬哲也
    • Journal Title

      原子衝突研究協会誌「しょうとつ」

      Volume: 7, 6 Pages: 5-15

    • Peer Reviewed
  • [Presentation] 共鳴多光子イオン化法による氷から熱脱離した水分子の原子核スピン温度測定実験2012

    • Author(s)
      羽馬哲也,渡部直樹,香内晃
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学(西宮市)
    • Year and Date
      2012-03-24
  • [Presentation] Spin temperature measurement of thermally desorbed water molecules from water ice prepared at 8K, 18th Symposium on Atomic, Cluster, and Surface Physics2012

    • Author(s)
      T. Hama, N. Watanabe and A. Kouchi
    • Organizer
      The Conference Center de l' Alpe d' Huez
    • Place of Presentation
      France
    • Year and Date
      2012-01-23
  • [Presentation] 氷から熱脱離した水分子の原子核スピン温度測定実験2011

    • Author(s)
      羽馬哲也,渡部直樹,香内晃
    • Organizer
      第2回表面科学若手研究会
    • Place of Presentation
      (独)理化学研究所(埼玉県)
    • Year and Date
      2011-11-20
  • [Presentation] Surface diffusion of atomic hydrogen on ice grains at very low temperature2011

    • Author(s)
      T. Hama
    • Organizer
      Mini-Workshop on Gas-Grain Interactions in Interstellar Clouds
    • Place of Presentation
      Univ. of Tokyo(Tokyo)
    • Year and Date
      2011-10-28
  • [Presentation] 重水素原子の低温氷表面における拡散2011

    • Author(s)
      羽馬哲也,渡部直樹,香内晃, V. Pirronello
    • Organizer
      日本物理学会秋季大会
    • Place of Presentation
      富山大学(富山市)
    • Year and Date
      2011-09-23
  • [Presentation] アモルファス氷表面における水素原子の拡散メカニズム2011

    • Author(s)
      羽馬哲也,渡部直樹,香内晃,木村勇気, V. Pirronello
    • Organizer
      第9回水素量子アトミクス研究会
    • Place of Presentation
      富山大学(富山市)
    • Year and Date
      2011-09-23
  • [Presentation] REMPI measurements of spin temperatures of desorbed water molecules from vapor-deposited and photo-produced amorphous solid water at 8K2011

    • Author(s)
      T. Hama, N. Watanabe, A. Kouchi, M. Yokoyama
    • Organizer
      第27回化学反応討論会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2011-06-09
  • [Presentation] Diffusion mechanism of hydrogen and deuterium atoms and the spin temperature of molecules on the surface of water ice at 8. 15 K, IAU Symposium2802011

    • Author(s)
      T. Hama, N. Watanabe, Y. Kimura, A. Kouchi, T. Chigai, V. Pirronello
    • Organizer
      The Molecular Universe
    • Place of Presentation
      Univ. of Castilla-La Mancha(Spain)
    • Year and Date
      2011-06-02
  • [Presentation] 水素および重水素原子の氷表面拡散と水素分子生成2011

    • Author(s)
      羽馬哲也,渡部直樹,木村勇気,香内晃,千貝健
    • Organizer
      日本地球惑星科学連合大会
    • Place of Presentation
      幕張メッセ(千葉)
    • Year and Date
      2011-05-23
  • [Presentation] 低温氷表面に吸着した水素原子の拡散メカニズム2011

    • Author(s)
      羽馬哲也,渡部直樹,香内晃,木村勇気, V. Pirronello
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学(新潟市)
    • Year and Date
      2011-03-28
  • [Presentation] アモルファス氷表面上の光反応機構2011

    • Author(s)
      羽馬哲也
    • Organizer
      CPSセミナー
    • Place of Presentation
      神戸大学(神戸市)
    • Year and Date
      2011-03-23
  • [Presentation] 氷への真空紫外光照射による原子・分子・ラジカルの脱離2011

    • Author(s)
      羽馬哲也
    • Organizer
      2010年度宇宙空間原子分子過程研究会低温衝突.星間分子から量子縮退気体まで
    • Place of Presentation
      JAXA(神奈川県)
    • Year and Date
      2011-02-16
  • [Presentation] Spectroscopic approach to physicochemical processes on ices at low temperatures2010

    • Author(s)
      T. Hama, M. Yokoyama, A. Kouchi, N. Watanabe
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      SheratonWaikiki(U. S. A)
    • Year and Date
      2010-12-18
  • [Remarks]

    • URL

      http://www.lowtem.hokudai.ac.jp/astro/

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Published: 2013-07-31  

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