2011 Fiscal Year Final Research Report
The development and application of highly efficient reagent having dual main group elements in a molecule
| Project/Area Number |
22850014
|
|---|
| Research Category |
Grant-in-Aid for Research Activity Start-up
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Organic chemistry
|
|---|
| Research Institution | Kyushu University |
|---|
Principal Investigator |
|
|---|
| Project Period (FY) |
2010 – 2011
|
| Keywords | 還元的アルキル化 / ルテニウムクラスター / シラン / エステル |
|---|
| Research Abstract |
In this research, I successfully obtained the reactions of esters by using reagents havingdual silicon atoms in one molecule for reductive alkylations shown below
Reductive alkylations of electron-rich aromatic rings with ester as an alkylatingreagent in the presence of disiloxane and ruthenium-cluster catalyst.
Under the similar conditions of 1), reductive alkylations of tosylamides were accomplished.
During the course of the research, I unexpectedly obtained rearrangement products(RCH2CHO) of vinyl ethers(CH2=CHOR) under silane and ruthenium-cluster catalystconditions.
|
