2011 Fiscal Year Final Research Report
Synthetic Studies toward Alkaloids having Spiroaminal Skeleton with Oxidative Skeletal Rearrangement
Project/Area Number |
22890013
|
Research Category |
Grant-in-Aid for Research Activity Start-up
|
Allocation Type | Single-year Grants |
Research Field |
Chemical pharmacy
|
Research Institution | Tohoku University |
Principal Investigator |
UEDA Hirofumi 東北大学, 大学院・薬学研究科, 助教 (50581279)
|
Project Period (FY) |
2010 – 2011
|
Keywords | 有機化学 / 有機合成化学 / 天然物合成化学 |
Research Abstract |
We succeeded to develop the cascade oxidative skeletal rearrangement utilizing the oxygen as a oxidant. Its novel and innovative reaction is free from peroxidative agents and metal oxidant, thus the reaction seems to be clean reaction for the environment. And we successful constructed the core tetracyclic aminal skeletons of isoschizogamine and leuconoxine with the developed cascade reaction.
|
Research Products
(20 results)