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2023 Fiscal Year Annual Research Report

Colloidal-rods for examining polymer dynamics in complex flows

Research Project

Project/Area Number 22K14738
Research InstitutionOkinawa Institute of Science and Technology Graduate University

Principal Investigator

CALABRESE Vincenzo  沖縄科学技術大学院大学, マイクロ・バイオ・ナノ流体ユニット, ポストドクトラルスカラー (40895413)

Project Period (FY) 2022-04-01 – 2024-03-31
Keywordspolymer / colloids / rheology
Outline of Annual Research Achievements

The candidate has managed to performe an extensive characterisation of polymer and rod-like colloids in shear and extension in Newtonian solvents. The main output of the research is that the polymer and rod-like colloid dynamics in shear and extensions are different and strongly depends on their flexibility. Another important output of the research regards the onset of aliment of rod-like colloids in crowded polymer solutions. We find that the polymer dynamics govern the onset of shear-induced alignment of colloidal rods suspended in polymer solutions, and the control parameter for the alignment of rods is the Weissenberg number, quantifying the elastic response of the polymer to an imposed flow.

  • Research Products

    (8 results)

All 2024 2023

All Journal Article (4 results) Presentation (4 results)

  • [Journal Article] Extensibility governs the flow-induced alignment of polymers and rod-like colloids2024

    • Author(s)
      Calabrese Vincenzo、Porto Santos Tatiana、Lopez Carlos G.、Lettinga Minne Paul、Haward Simon J.、Shen Amy Q.
    • Journal Title

      Physical Review Research

      Volume: 6 Pages: L012042

    • DOI

      10.1103/PhysRevResearch.6.L012042

  • [Journal Article] Flow-induced alignment of protein nanofibril dispersions2023

    • Author(s)
      Santos Tatiana P.、Calabrese Vincenzo、Boehm Michael W.、Baier Stefan K.、Shen Amy Q.
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 638 Pages: 487~497

    • DOI

      10.1016/j.jcis.2023.01.105

  • [Journal Article] Naturally derived colloidal rods in microfluidic flows2023

    • Author(s)
      Calabrese Vincenzo、Shen Amy Q.、Haward Simon J.
    • Journal Title

      Biomicrofluidics

      Volume: 17 Pages: 021301

    • DOI

      10.1063/5.0142867

  • [Journal Article] Alignment?Rheology Relationship of Biosourced Rod-Like Colloids and Polymers under Flow2023

    • Author(s)
      Detert Marvin、Santos Tatiana Porto、Shen Amy Q.、Calabrese Vincenzo
    • Journal Title

      Biomacromolecules

      Volume: 24 Pages: 3304~3312

    • DOI

      10.1021/acs.biomac.3c00347

  • [Presentation] Extensibility governs the flow-induced alignment of polymers and rod-like colloids2024

    • Author(s)
      Calabrese Vincenzo、Porto Santos Tatiana、Lopez Carlos G.、Lettinga Minne Paul、Haward Simon J.、Shen Amy Q.
    • Organizer
      Gordon Research Conference: Colloidal, Macromolecular and Polyelectrolyte Solutions
  • [Presentation] How do polymers stretch in capillary-driven extensional flows?2024

    • Author(s)
      Calabrese Vincenzo、Shen Amy Q, Haward Simon J
    • Organizer
      Gordon Research Conference: Colloidal, Macromolecular and Polyelectrolyte Solutions
  • [Presentation] Extensibility governs the flow-induced alignment of polymers and rod-like colloids2023

    • Author(s)
      Calabrese Vincenzo、Porto Santos Tatiana、Lopez Carlos G.、Lettinga Minne Paul、Haward Simon J.、Shen Amy Q.
    • Organizer
      7th International Soft Matter Conference
  • [Presentation] Extensibility governs the flow-induced alignment of polymers and rod-like colloids2023

    • Author(s)
      Calabrese Vincenzo、Porto Santos Tatiana、Lopez Carlos G.、Lettinga Minne Paul、Haward Simon J.、Shen Amy Q.
    • Organizer
      International congress on Rheology

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Published: 2024-12-25  

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