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2013 Fiscal Year Final Research Report

Development of the environmental friendly hydrogen generation system by using sulfur compounds

Research Project

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Project/Area Number 23241026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionTohoku University

Principal Investigator

TOHJI Kazuyuki  東北大学, 環境科学研究科, 教授 (10175474)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Hideyuki  東北大学, 大学院環境科学研究科, 准教授 (90312652)
SATO Yoshinori  東北大学, 大学院環境科学研究科, 准教授 (30374995)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords環境材料 / 再生可能エネルギー / イオウ利用
Research Abstract

From the results of electrochemical analysis, it become clear that catalytic reaction between polysulfide ion and fullerenes and oxygen was progress at the water - organic solvents interface. As the results, polysulfide ion (by products of photo catalytic reactions) was successfully changed into elemental sulfur and/or fullerenes-sulfur compounds. Moreover, polysulfide ion can be changed into industrial materials, such as polysulfide rubber which has high resistance properties. Synthesized elemental sulfur can be changed into hydrogen sulfide, which is the origin of photo catalytic reaction. Thus, environmental friendly hydrogen generation system by using sulfur can be constructed.

  • Research Products

    (28 results)

All 2013 2012 2011 Other

All Journal Article (7 results) Presentation (20 results) (of which Invited: 2 results) Remarks (1 results)

  • [Journal Article] Effective hydrogen generation and resource circulation based on sulfur cycle system2013

    • Author(s)
      Hideyuki Takahashi, Takashi Mabuchi, Tsugumi Hayashi, Shun Yokoyama, Kazuyuki Tohji
    • Journal Title

      AIP Conference Proc. (SolChES)

      Volume: 1568 Pages: 67-73

  • [Journal Article] Basic study for the construction of solar cell using CdS photocatalysts and Na2S4 electrolyte2013

    • Author(s)
      Takashi Mabuchi, Tsugumi Hayashi, Hideyuki Takahashi, Kazuyuki Tohji
    • Journal Title

      AIP Conference Proc. (SolChES)

      Volume: 1568 Pages: 74-76

  • [Journal Article] Basic study for the application of Cu supported ZnS and ZnO photocatalysts for the CO2 conversion into alcohol2013

    • Author(s)
      Yasuharu Kajino, Hideyuki Takahashi, Kazuyuki Tohji
    • Journal Title

      AIP Conference Proc. (SolChES)

      Volume: 1568 Pages: 24-27

  • [Journal Article] 硫黄循環による硫化水素からの水素エネルギー製造2013

    • Author(s)
      高橋英志、林亜実、横山俊、梶野康晴、水藤芳基、馬渕隆、小林祥大、伊藤康友、田路和幸
    • Journal Title

      鉱山

      Volume: 713 Pages: 9-19

  • [Journal Article] Synthesis method for well crystallized alloy nanoparticles in aqueous solution under room temperature by controlling the metal complexes condition2013

    • Author(s)
      Takashi Mabuchi, Shun Yokoyama, Hideyuki Takahashi, and Kazuyuki Tohji
    • Journal Title

      Annual TechConnect World Technical Proc

      Volume: (CD-ROM)

  • [Journal Article] Synthesis of Cd hydroxide particles with hollow structures by a one-step process2011

    • Author(s)
      Ying Tian, Xin Cui, Fangming Jin, Xu Zeng, Tsugumi Hayashi, Hideyuki Takahashi, Kazuyuki Tohji
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 50 Pages: 13585-13588

  • [Journal Article] Recovery of poly sulfide anions in basic solution produced by the decomposition of H2S by fullerene, Fullerenes2011

    • Author(s)
      Tsugumi Hayashi; Yohei Baba; Toshiharu Taga; Akira Kishimoto; Hideyuki Takahashi, Kazuyuki Tohji
    • Journal Title

      Nanotubes and Carbon Nanostructures

      Volume: 19 Pages: 684-691

  • [Presentation] Relationship between detailed condition of Pt nano co-catalyst on the surface of photocatalysts and its activity2013

    • Author(s)
      Kousuke Ito, Shun Yokoyama, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Redox Site Separation Effects for Photocatalytic Activity Using ZnS Stratified Photocatalysts2013

    • Author(s)
      Akihiro Kobayashi, Shun Yokoyama, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Separation of Redox Site by Utilizing the Nanostructure of ZnS Stratified Photocatalysts2013

    • Author(s)
      Akihiro Kobayashi, Shun Yokoyama, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Basic study for the construction of wet solar, Na2S4 electrolyte, and inorganic photo-carrier transport materials2013

    • Author(s)
      Takashi Mabuchi, Shun Yokoyama, Norihiro Shimoi, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Improvement of photo-carrier transport efficiency from the semiconductor particles to electrode by using organic carrier transport materials2013

    • Author(s)
      Takashi Mabuchi, Shun Yokoyama, Norihiro Shimoi, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Application of Stratified ZnS Photocatalysts against to the Water Clarification Materials2013

    • Author(s)
      Yoshiki Suito, Shun Yokoyama, Hideyuki Takahashi, Koichi Suto, Chihiro Inoue, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Bactericidal Mechanisms of Stratified ZnS Photocatalysts and ZnO Nanoparticles2013

    • Author(s)
      Yoshiki Suito, Shun Yokoyama, Hideyuki Takahashi, Koichi Suto, Chihiro Inoue, Kazuyuki Tohji
    • Organizer
      224th Meeting of The Electrochemical Society
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2013-10-29
  • [Presentation] Coexistence between effective photocatalytic hydrogen production and energy saving based on sulfur cycle system using H2S2013

    • Author(s)
      Hideyuki Takahashi
    • Organizer
      2013 A & WMA Regional Specialty Conference on Sustainable Resources and Air Quality Management Conference
    • Place of Presentation
      Yilan, Taiwan
    • Year and Date
      2013-10-24
  • [Presentation] Effective hydrogen generation and resource circulation based on sulfur cycle system2012

    • Author(s)
      Hideyuki Takahashi
    • Organizer
      International Workshop on Solar-Chemical Energy Storage
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120723-27
    • Invited
  • [Presentation] Basic study for the application of Cu supported ZnS and ZnO photocatalysts for the CO2 conversion into alcohol2012

    • Author(s)
      Yasuharu Kajino, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      International Workshop on Solar-Chemical Energy Storage
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120723-27
  • [Presentation] Basic study for the construction of solar cell using CdS photocatalysts and Na2S4 electrolyte2012

    • Author(s)
      Takashi Mabuchi, Tsugumi Hayashi, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      International Workshop on Solar-Chemical Energy Storage
    • Place of Presentation
      Sendai, Japan
    • Year and Date
      20120723-27
  • [Presentation] Effective Hydrogen Generation and Resource Circulation from Photocatalytic Decomposition of H2S Aqueous Solution2012

    • Author(s)
      H. Takahashi, T. Mabuchi, T. Hayashi, S. Yokoyama, and K. Tohji
    • Organizer
      222th Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-08
  • [Presentation] Improvement of Efficiency of Photo-Excited Electrons Transfer from Thin Film Consisted by the Semiconductor Particles on Electrode Surface to Developing Electrons Pathway2012

    • Author(s)
      T. Mabuchi, T. Hayashi, H. Takahashi, and K. Tohji
    • Organizer
      222th Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-08
  • [Presentation] Synthesis of Cu Supported Stratified Photocatalysts and Its Application for the CO2 Conversion into Alcohol2012

    • Author(s)
      Y. Kajino, H. Takahashi, and K. Tohji
    • Organizer
      222th Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-08
  • [Presentation] Control Method for the Amount of Cu Site on the ZnS Stratified Photocatalysts2012

    • Author(s)
      Y. Kajino, H. Takahashi, and K. Tohji
    • Organizer
      222th Meeting of The Electrochemical Society
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2012-10-08
  • [Presentation] 硫黄循環による硫化水素からの水素エネルギー製造2012

    • Author(s)
      高橋英志
    • Organizer
      日本鉱業協会新材料部会講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-15
    • Invited
  • [Presentation] Electron-accepting properties of fullerenes at the interface of two immiscible electrolyte solutions2011

    • Author(s)
      Tsugumi Hayashi, Tomohiko Okugaki, Hideyuki Takahashi, Kohji Maeda, Kazuyuki Tohji
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-10
  • [Presentation] Designing of new wet solar cell constructed by cadmium sulfide type semiconductors and carbon cluster2011

    • Author(s)
      Tsugumi Hayashi, Hideyuki Takahashi, Kazuyuki Tohji
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-10
  • [Presentation] Effect of dispersive condition and size for the activation of ZnS photocatalysts with stratified morphology2011

    • Author(s)
      Motohide Sasaki, Hideyuki Takahashi, and Kazuyuki Tohji
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-10
  • [Presentation] Effect of the morphology for the degradation ability against to the environmental pollutant source2011

    • Author(s)
      Motohide Sasaki, Yoshiki Suito, Tsugumi Hayashi, Hideyuki Takahashi, and Kazuyuki Tohji
    • Organizer
      220th Meeting of The Electrochemical Society
    • Place of Presentation
      Boston, USA
    • Year and Date
      2011-10-10
  • [Remarks]

    • URL

      http://bucky1.kankyo.tohoku.ac.jp/

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Published: 2015-06-25  

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