2013 Fiscal Year Final Research Report
Studies on the high valent cation conducting solids
| Project/Area Number |
23245043
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Osaka University |
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Principal Investigator |
IMANAKA Nobuhito 大阪大学, 工学(系)研究科(研究院), 教授 (30192503)
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| Co-Investigator(Kenkyū-buntansha) |
TAMURA Shinji 大阪大学, 大学院工学研究科, 講師 (80379122)
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| Project Period (FY) |
2011-11-18 – 2014-03-31
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| Keywords | 固体電解質 / 多価イオン / 3価 / 4価 / ナシコン型構造 / 二次元層状構造 |
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| Research Abstract |
In this study, we have developed the trivalent bismuth cation, tetravalent hafnium cation, and tetravalent tellurium cation conducting solids as the novel high valence cation conducting solid electrolytes, and their ion conducting properties were clearly demonstrated. Furthermore, Te4+ cation conducting pathway has been also clarified by the Reitveld analysis. Moreover, the tetravalent ion conduction in the NASICON type structure has been demonstrated to be influenced by both the size and electronegativity of conducting tetravalent cation.
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