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2013 Fiscal Year Final Research Report

Development of highly efficient practical wastewater treatment systems using reactive and functional stimuli-responsive polymers

Research Project

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Project/Area Number 23310054
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

SAITOH Tohru  名古屋大学, 工学(系)研究科(研究院), 准教授 (40186945)

Co-Investigator(Kenkyū-buntansha) UEHARA Nobuo  宇都宮大学, 工学部, 准教授 (50203469)
TAKAGAI Yoshitaka  福島大学, 共生システム理工学類, 准教授 (70399773)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords温度感応性高分子 / 排水浄化 / 反応性官能基 / フェノール化合物 / エストロゲン / 界面活性剤 / 重金属イオン / 酵素反応
Research Abstract

Highly efficient wastewater treatment systems were designed by using thermoresponsive polymers having functional groups that can react with desired environmental pollutants in water. Phenolic compounds and estrogens which have insufficiently been eliminated from water by conventional wastewater treatment processes were rapidly and nearly completely removed from wastewaters. By change the functional groups, the proposed method was applicable to the rapid removal of toxic metal ions in environmental waters and ortho-phthalaldehyde in antiseptic solutions for endoscopes. Moreover, temperature-independent coagulation methods were also developed and used for designing practical wastewater treatment systems.

  • Research Products

    (34 results)

All 2014 2013 2012 2011

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (19 results) Book (3 results)

  • [Journal Article] Combined use of surfactant-induced coagulation of poly(allylamine hydrochloride) with peroxidase-mediated degradation for the rapid removal of estrogens and phenolic compounds from water2014

    • Author(s)
      T. Saitoh, K. Fukushima, A. Miwa
    • Journal Title

      Separation and Purification Technology

      Volume: Vol. 128 Pages: 11-17

    • DOI

      10.1016/j.seppur.2014.02.038

    • Peer Reviewed
  • [Journal Article] Rapid removal of cationic dyes from water by coprecipitation with aluminum hydroxide and sodium dodecyl sulfate2014

    • Author(s)
      T. Saitoh, M. Saitoh, C. Hattori, M. Hiraide
    • Journal Title

      Journal of Environmental Chemical Engineering

      Volume: Vol. 2, No. 1 Pages: 752-758

    • DOI

      10.1016/j.jece.2013.11.015

    • Peer Reviewed
  • [Journal Article] カスケード型高倍率濃縮分離システムの構築と分析化学的応用(総合論文)2013

    • Author(s)
      高貝 慶隆
    • Journal Title

      分析化学

      Volume: Vol. 62, No. 4 Pages: 317-323

    • DOI

      10.2116/bunsekikagaku.62.317

    • Peer Reviewed
  • [Journal Article] Fusion growth of gold nanoparticles induced by the conformational change of a thermoresponsive polymer studied by distance distribution functions2013

    • Author(s)
      T. Morita, K. Kurihara, O. Yoshida, H. Imamura, Y. Hatakeyama, K. Nishikawa, N. Uehara
    • Journal Title

      Journal of Physical Chemistry

      Volume: Vol.117, No.26 Pages: 535-545

    • DOI

      10.1021/jp310906b

    • Peer Reviewed
  • [Journal Article] Pre- concentration of trace metals in water using a newly designed thermoresponsive chelating polymer for the sensitive determination by graphite furnace atomic absorption spectrometry2013

    • Author(s)
      T. Saitoh, A. Arakawa, M. Hiraide
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: Vol.86, No.4 Pages: 438-444

    • DOI

      10.1246/bcsj.20120284

    • Peer Reviewed
  • [Journal Article] Rapid removal of o-phthalaldehyde from water by polyallylamine-conjugated thermo- responsive polymer-mediated extraction2013

    • Author(s)
      T. Saitoh, K. Fukushima, M. Hiraide
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: Vol.86, No.2 Pages: 296-298

    • DOI

      10.1246/bcsj.20120269

    • Peer Reviewed
  • [Journal Article] 熱応答性金ナノ複合体を用いるチオール化合物のセンシング(総合論文)2012

    • Author(s)
      上原 伸夫
    • Journal Title

      分析化学

      Volume: Vol.61, No.6 Pages: 535-545

    • DOI

      10.2116/bunsekikagaku.61.535

    • Peer Reviewed
  • [Journal Article] アドミセルクロマトグラフィーにおける薬剤成分の分離挙動2012

    • Author(s)
      奥村 量征, 伊藤 暁哉, 齋藤 徹, 平出 正孝
    • Journal Title

      分析化学

      Volume: Vol.61, No.8 Pages: 719-722

    • DOI

      10.2116/bunsekikagaku.61.719

    • Peer Reviewed
  • [Journal Article] Effective collection of hydrophobic organic pollutants in water with aluminum hydroxide and hydrophobically modified polyacrylic acid2012

    • Author(s)
      T. Saitoh, N. Ono, M. Hiraide
    • Journal Title

      Chemosphere

      Volume: Vol.89, No.6 Pages: 759-763

    • DOI

      10.1016/j.chemosphere.2012.07.009

    • Peer Reviewed
  • [Journal Article] Polyallyl- amine-conjugated thermoresponsive polymers for the rapid removal of phenolic compounds from water2012

    • Author(s)
      T. Saitoh, K. Asano, M. Hiraide
    • Journal Title

      Reactive and Functional Polymers

      Volume: Vol.72, No.6 Pages: 317-322

    • DOI

      10.1016/j.reactfunctpolym.2012.03.006

    • Peer Reviewed
  • [Journal Article] Gas chromatography-mass spectro- metric determination of ivermectin following trimethylsilylation with application to residue analysis in biological meat tissue samples2011

    • Author(s)
      A. Sanbonsuge, T. Takase, D. Shiho, Y. Takagai
    • Journal Title

      Analytical Methods

      Volume: Vol.3, No.9 Pages: 2160-2164

    • DOI

      10.1039/c1ay05236e

    • Peer Reviewed
  • [Journal Article] Thermal- induced growth of gold nanoparticles conjugated with thermoresponsive polymer without chemical reduction2011

    • Author(s)
      N. Uehara, M. Fujita, T. Shimizu
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: Vol.369, No.1 Pages: 142-147

    • DOI

      10.1016/j.jcis.2011.03.078

    • Peer Reviewed
  • [Presentation] ガスクロマトグラフィー質量分析計の高感度化手法としての低曇点非イオン性界面活性剤を用いる曇点抽出2014

    • Author(s)
      松尾 晴児, 高貝 慶隆
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      20140327-30
  • [Presentation] 二本鎖型カチオン界面活性剤修飾モンモリロナイトへの水中薬剤成分の分配挙動2013

    • Author(s)
      柴山 卓芳, 齋藤 徹
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      20131122-23
  • [Presentation] Surfactant mediated extraction of environmental pollutants for gas chromatography - mass spectrometric analysis2013

    • Author(s)
      Y. Takagai,W.L.Hinze
    • Organizer
      TJASSST2013
    • Place of Presentation
      Hammamet (Tunisia)
    • Year and Date
      20131115-17
  • [Presentation] 日本鎖型カチオン界面活性剤含有オルガノクレーを用いるβ-ラクタム系抗生物質の低環境負荷捕集分解2013

    • Author(s)
      柴山 卓芳, 齋藤 徹
    • Organizer
      第3回CSJ 化学フェスタ 2013
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      20131021-23
  • [Presentation] オルガノクレーを用いる水中抗菌剤の高効率捕集・分解2013

    • Author(s)
      齋藤 徹, 柴山 卓芳
    • Organizer
      化学工学会第45回秋季年会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      20130916-18
  • [Presentation] 界面活性剤とのイオン対形成を利用する水中テトラサイクリン系抗菌剤の迅速捕集2013

    • Author(s)
      柴田 健司, 齋藤 徹
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      20130910-12
  • [Presentation] 界面活性剤-ポリアリルアミン凝集系を用いる水中エストロゲンの迅速除去2013

    • Author(s)
      齋藤 徹, 福島 皓太郎, 三輪 明日香
    • Organizer
      日本分析化学会第62年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      20130910-12
  • [Presentation] Interaction of poly(N-isopropylacrylamide) and surfac- tants under low concentration conditions2013

    • Author(s)
      M. Mori, M. Ogawa, N. Uehara
    • Organizer
      RSC Tokyo International Conference 2013 - Analytical Biochemistry & Biophysics
    • Place of Presentation
      幕張メッセ(千葉市)
    • Year and Date
      20130905-06
  • [Presentation] 温度感応性高分子抽出-極性基導入カラムHPLCによる水中疎水性薬物の計測2012

    • Author(s)
      齋藤 徹, 伊藤 暁哉, 平出 正孝
    • Organizer
      第43回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      20121110-11
  • [Presentation] Discrimination of types of surfactants with using thermoresponsive polymers and fluorophore2012

    • Author(s)
      N. Uehara, M. Ogawa
    • Organizer
      IUMRS-Inter- national Conference on Electronic Materials
    • Place of Presentation
      パシフィコ横浜(横浜市)
    • Year and Date
      20120923-28
  • [Presentation] 界面活性剤支援凝集系の設計による排水中薬物の高効率除去2012

    • Author(s)
      齋藤 徹, 三輪 明日香, 柴田 健司, 平出 正孝
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      20120919-21
  • [Presentation] ポリアリルアミン-オレイン酸凝集系の設計と医療排水の迅速処理2012

    • Author(s)
      福島 皓太郎, 齋藤 徹, 平出 正孝
    • Organizer
      第21回環境化学討論会
    • Place of Presentation
      ひめぎんホール(松山市)
    • Year and Date
      20120711-13
  • [Presentation] イミノ二酢酸結合温度感応性高分子を用いる環境水中金属イオンの高感度分離定量2012

    • Author(s)
      齋藤 徹, 荒川 哲大, 平出 正孝
    • Organizer
      第72回分析化学会討論会
    • Place of Presentation
      鹿児島大学(鹿児島市)
    • Year and Date
      20120519-20
  • [Presentation] ポリアリルアミン結合温度感応性高分子を用いる排水中フタルアルデヒドの簡便・迅速除去2011

    • Author(s)
      福島 皓太郎, 齋藤 徹, 平出 正孝
    • Organizer
      2011年日本化学会西日本大会
    • Place of Presentation
      徳島大学(徳島市)
    • Year and Date
      20111112-13
  • [Presentation] 熱応答性高分子が形成する疎水性場における蛍光プローブのエキシマー発光2011

    • Author(s)
      小川 陽, 上原 伸夫, 清水 得夫
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      20110914-16
  • [Presentation] カスケード型高倍率濃縮分離システムの構築と分析化学的応用2011

    • Author(s)
      高貝 慶隆
    • Organizer
      日本分析化学会第60年会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      20110914-16
  • [Presentation] Thermo- responsive polymer-mediated extraction of antibacterial agents from water2011

    • Author(s)
      T. Saitoh, K. Asano, M. Hiraide
    • Organizer
      EURO Analysis16
    • Place of Presentation
      Belgrade (Servia)
    • Year and Date
      20110911-15
  • [Presentation] Effective collection of hydrophobic organic pollutants in water with aluminum hydroxide and hydrophobically modified polyacrylic acid2011

    • Author(s)
      T. Saitoh, N. Ohno, M. Hiraide
    • Place of Presentation
      Ottawa (Canada)
    • Year and Date
      20110817-19
  • [Presentation] Thermal-induced growth of gold nano- particles conjugated with thermoresponsive polymers2011

    • Author(s)
      N. Uehara, M. Fujita, O. Yoshida, T. Shimizu
    • Organizer
      International Congress of Analytical Sciences
    • Place of Presentation
      国立京都国際会館(京都市)
    • Year and Date
      20110522-26
  • [Book] これからの環境化学入門2013

    • Author(s)
      小熊 幸一, 上原 伸夫, 保倉明子, 林英男
    • Total Pages
      262
    • Publisher
      講談社
  • [Book] (分担) 分析化学用語辞典2011

    • Author(s)
      上原 伸夫, 高貝 慶隆
    • Total Pages
      560
    • Publisher
      日本分析化学会編
  • [Book] 環境水中の変異原性物質の微量計測法の開発, "阿武隈川流域の環境学", 福島大学自然共生・再生研究プロジェクト2011

    • Author(s)
      高貝 慶隆
    • Total Pages
      14
    • Publisher
      福島民報社

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Published: 2015-06-25  

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