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2013 Fiscal Year Final Research Report

Growth of highly oriented h-BN single crystal by chemical vapor deposition method

Research Project

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Project/Area Number 23310096
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Microdevices/Nanodevices
Research InstitutionNational Institute for Materials Science

Principal Investigator

WATANABE Kenji  独立行政法人物質・材料研究機構, 光・電子材料ユニット, 主席研究員 (20343840)

Co-Investigator(Renkei-kenkyūsha) TANIGUCHI Takashi  独立行政法人物質・材料研究機構, ナノスケール物質萌芽ラボ, グループリーダー (80354413)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords結晶工学 / 六方晶窒化ホウ素 / グラフェン / 原子層科学 / 結晶成長 / 気相成長 / 格子欠陥 / 電子デバイス
Research Abstract

Hexagonal boron nitride (h-BN), which has a 2D-plane layered structure composed of nitrogen and boron atoms in sp2 bonding, is a proven and effective substrate for atomic layer materials including graphene, because it has an atomically smooth surface that is relatively free of dangling bonds and charge traps.However, to realize atomic layer devices, the single-crystalline growth technique for hBN is of great importance. In this study, we achieved high quality h-BN homoepitaxial growth on the bulk h-BN substrate by employing chemical vapor deposition methods with high-growth temperature.

  • Research Products

    (58 results)

All 2014 2013 2012 2011 Other

All Journal Article (44 results) (of which Peer Reviewed: 44 results) Presentation (9 results) (of which Invited: 4 results) Book (4 results) Remarks (1 results)

  • [Journal Article] Reconfigurable P-N Junction Diodes and the Photovoltaic Effect in Exfoliated MoS2 Films2014

    • Author(s)
      S. Sutar, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104巻 Pages: 122104

    • DOI

      10.1063/1.4870067

    • Peer Reviewed
  • [Journal Article] Screening Charged Impurities and Lifting the Orbital Degeneracy in Graphene By Populating Landau Levels2014

    • Author(s)
      A. Luican-Mayer, K. Watanabe, T. Taniguchi 他6名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 11巻 Pages: 036804

    • DOI

      10.1103/PhysRevLett.112.036804

    • Peer Reviewed
  • [Journal Article] Atomic Structure of Luminescent Centersin High-Efficiency Ce-Doped w-AlN Single Crystal2014

    • Author(s)
      R. Ishikawa, K. Watanabe, T. Taniguchi 他9名
    • Journal Title

      SCIENTIFIC REPORTS

      Volume: 4巻 Pages: 3778

    • DOI

      10.1038/srep03778

    • Peer Reviewed
  • [Journal Article] Ballistic Transport in Graphene Grown By Chemical Vapor Deposition2014

    • Author(s)
      V. E. Calado, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104巻 Pages: 023103

    • DOI

      10.1063/1.4861627

    • Peer Reviewed
  • [Journal Article] Strong Oxidation Resistance of Atomically Thin Boron Nitride Nanosheets2014

    • Author(s)
      L. H. Li, K. Watanabe, T. Taniguchi 他2名
    • Journal Title

      ACS Nano

      Volume: 8巻 Pages: 1457-1462

    • DOI

      10.1021/nn500059s

    • Peer Reviewed
  • [Journal Article] Gate Dependent Raman Spectroscopy of Graphene on Hexagonal Boron Nitride2013

    • Author(s)
      C. Kanokporn, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      J. Phys. : Condens. Matter

      Volume: 25巻 Pages: 505304

    • DOI

      10.1088/0953-8984/25/50/505304

    • Peer Reviewed
  • [Journal Article] Etched Graphene Single Electron Transistors on Hexagonal Boron Nitride in High Magnetic Fields2013

    • Author(s)
      A. Epping, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      physica status solidi (b)

      Volume: 250巻 Pages: 2692-2696

    • DOI

      10.1002/pssb.201300295

    • Peer Reviewed
  • [Journal Article] One -Dimensional Electrical Contact to a Two-Dimensional Material2013

    • Author(s)
      L. Wang, K. Watanabe, T. Taniguchi 他12名
    • Journal Title

      Science

      Volume: 342巻 Pages: 614-617

    • DOI

      10.1126/science.1244358

    • Peer Reviewed
  • [Journal Article] Fabrication and Characterization of High-Mobility Graphene P-n-p Junctions Encapsulated By Hexagonal Boron Nitride2013

    • Author(s)
      S. Masubuchi, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52巻 Pages: 110105

    • DOI

      10.7567/JJAP.52.110105

    • Peer Reviewed
  • [Journal Article] Photovoltaic Infrared Photoresponse of the High-Mobility Graphene Quantum Hall System Due to Cyclotron Resonance2013

    • Author(s)
      S. Masubuchi, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Phys. Rev. B

      Volume: 88巻 Pages: 121402

    • DOI

      10.1103/PhysRevB.88.121402

    • Peer Reviewed
  • [Journal Article] Etched Graphene Quantum Dots on Hexagonal Boron Nitride2013

    • Author(s)
      S. Engels, K. Watanabe, T. Taniguchi 他6名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 103巻 Pages: 073113

    • DOI

      10.1063/1.4818627

    • Peer Reviewed
  • [Journal Article] Dielectric Screening of the Kohn Anomaly of Graphene on Hexagonal Boron Nitride2013

    • Author(s)
      F. Forster, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      Phys. Rev. B

      Volume: 88巻 Pages: 085419

    • DOI

      10.1103/PhysRevB.88.085419

    • Peer Reviewed
  • [Journal Article] Suppression of Thermally Activated Carrier Transport in Atomically Thin MoS2 on Crystalline Hexagonal Boron Nitride Substrates2013

    • Author(s)
      M. Y. Chan, K. Watanabe, T. Taniguchi 他8名
    • Journal Title

      Nanoscale

      Volume: 5巻 Pages: 9572-9576

    • DOI

      10.1039/C3NR03220E

    • Peer Reviewed
  • [Journal Article] Flexible and Transparent MoS2 Field-Effect Transistors on Hexagonal Boron NitrideGraphene Heterostructures2013

    • Author(s)
      G.-H. Lee, K. Watanabe, T. Taniguchi 他11名
    • Journal Title

      ACS Nano

      Volume: 7巻 Pages: 7931-7936

    • DOI

      10.1021/nn402954e

    • Peer Reviewed
  • [Journal Article] Direct Imaging of Charged Impurity Density in Common Graphene Substrates2013

    • Author(s)
      K. M. Burson, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      Nano Lett.

      Volume: 13巻 Pages: 3576-3580

    • DOI

      10.1021/nl4012529

    • Peer Reviewed
  • [Journal Article] Electrical Spin Injection Into Graphene Through Monolayer HexagonalBoron Nitride2013

    • Author(s)
      T. Yamaguchi, K. Watanabe, T. Taniguchi 他6名
    • Journal Title

      Applied Physics Express

      Volume: 6巻 Pages: 073001

    • DOI

      10.7567/APEX.6.073001

    • Peer Reviewed
  • [Journal Article] Insulating Behavior At the Neutrality Point in Single-Layer Graphene2013

    • Author(s)
      F. Amet,K. Watanabe, T. Taniguchi 他2名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 110巻 Pages: 216601

    • DOI

      10.1103/PhysRevLett.110.216601

    • Peer Reviewed
  • [Journal Article] Optical Thickness Determination of Hexagonal Boron Nitride Flakes2013

    • Author(s)
      D. Golla, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 102巻 Pages: 161906

    • DOI

      10.1063/1.4803041

    • Peer Reviewed
  • [Journal Article] Thermal Conductivity and Phonon Transport in Suspended Few-Layer Hexagonal Boron Nitride2013

    • Author(s)
      I. Jo, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Nano Letters

      Volume: 13巻 Pages: 550-554

    • DOI

      10.1021/nl304060g

    • Peer Reviewed
  • [Journal Article] Graphene on Boron Nitride Microwave Transistors Driven By Graphene Nanoribbon Back-Gates2013

    • Author(s)
      C. Benz, K. Watanabe, T. Taniguchi 他6名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 102巻 Pages: 0335

    • DOI

      10.1063/1.4788818

    • Peer Reviewed
  • [Journal Article] Optical Probing of the Electronic Interaction Between Graphene and Hexagonal Boron Nitride2013

    • Author(s)
      G. Ahn, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      ACS Nano

      Volume: 7巻 Pages: 1533-1541

    • DOI

      10.1021/nn305306n

    • Peer Reviewed
  • [Journal Article] Slow Gold Adatom Diffusion on Graphene : Effect of Silicon Dioxide and Hexagonal Boron Nitride Substrates2013

    • Author(s)
      L. Liu, K. Watanabe, T. Taniguchi 他7名
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 117巻 Pages: 4305-4312

    • DOI

      10.1021/jp305521g

    • Peer Reviewed
  • [Journal Article] Biaxial Compressive Strain Engineering in Graphene/boron Nitride Heterostructures2012

    • Author(s)
      W. Pan, K. Watanabe, T. Taniguchi 他7名
    • Journal Title

      Scientific Reports

      Volume: 2巻 Pages: 893

    • DOI

      10.1038/srep00893

    • Peer Reviewed
  • [Journal Article] Electron Flow in Split-Gated Bilayer Graphene2012

    • Author(s)
      S. Droscher, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      New Journal of Physics

      Volume: 14巻 Pages: 103007

    • DOI

      10.1088/1367-2630/14/10/103007

    • Peer Reviewed
  • [Journal Article] Negligible Environmental Sensitivity of Graphene in a Hexagonal Boron Nitride/graphene/h-Bn Sandwich Structure2012

    • Author(s)
      L. Wang, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      ACS Nano

      Volume: 6巻 Pages: 9314-9319

    • DOI

      10.1021/nn304004s

    • Peer Reviewed
  • [Journal Article] Renormalization of the Graphene Dispersion Velocity Determined From Scanning Tunneling Spectroscopy2012

    • Author(s)
      J. Chae, K. Watanabe, T. Taniguchi 他10名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 109巻 Pages: 116802

    • DOI

      10.1103/PhysRevLett.109.116802

    • Peer Reviewed
  • [Journal Article] Chemical Vapor Deposition of 12c Isotopically Enriched Polycrystalline Diamond2012

    • Author(s)
      T. Teraji, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 51巻 Pages: 090104

    • DOI

      10.1143/JJAP.51.090104

    • Peer Reviewed
  • [Journal Article] Gate-Defined Confinement in Bilayer Graphene-Hexagonal Boron Nitride Hybrid Devices2012

    • Author(s)
      A. S. M. Goossens, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Nano Letters

      Volume: 12巻 Pages: 4656-4660

    • DOI

      10.1021/nl301986q

    • Peer Reviewed
  • [Journal Article] Angle-Dependent Carrier Transmission in Graphene P-N Junctions2012

    • Author(s)
      S. Sutar, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Nano Letters

      Volume: 12巻 Pages: 4460-4464

    • DOI

      10.1021/nl3011897

    • Peer Reviewed
  • [Journal Article] Effective Cleaning of Hexagonal Boron Nitride for Graphene Devices2012

    • Author(s)
      A. G. F.Garcia, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Nano Letters

      Volume: 12巻 Pages: 4449-4454

    • DOI

      10.1021/nl3011726

    • Peer Reviewed
  • [Journal Article] Boundary Scattering in Ballistic Graphene2012

    • Author(s)
      S. Masubuchi, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 109巻 Pages: 036601

    • DOI

      10.1103/PhysRevLett.109.036601

    • Peer Reviewed
  • [Journal Article] Electronic Compressibility of Layer-Polarized Bilayer Graphene2012

    • Author(s)
      A. F. Young, K. Watanabe, T. Taniguchi 他7名
    • Journal Title

      Phys. Rev. B

      Volume: 85巻 Pages: 235458

    • DOI

      10.1103/PhysRevB.85.235458

    • Peer Reviewed
  • [Journal Article] Graphene Based Heterostructures2012

    • Author(s)
      C. R. Dean, K. Watanabe, T. Taniguchi 他7名
    • Journal Title

      Solid State Commun.

      Volume: 152巻 Pages: 1275-1282

    • DOI

      10.1016/j.ssc.2012.04.021

    • Peer Reviewed
  • [Journal Article] Graphene Growth on H-Bn By Molecular Beam Epitaxy2012

    • Author(s)
      J. M. Garcia, K. Watanabe, T. Taniguchi 他10名
    • Journal Title

      Solid State Commun.

      Volume: 152巻 Pages: 975-978

    • DOI

      10.1016/j.ssc.2012.04.005

    • Peer Reviewed
  • [Journal Article] Large Variations of the Raman Signal in the Spectra of Twisted Bilayer Graphene on a Bn Substrate2012

    • Author(s)
      M. Kalbac, K. Watanabe, T. Taniguchi 他5名
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 3巻 Pages: 796-799

    • DOI

      10.1021/jz300176a

    • Peer Reviewed
  • [Journal Article] Mechanical Cleaning of Graphene2012

    • Author(s)
      S. A. M. Goossens, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 100巻 Pages: 073110

    • DOI

      10.1063/1.3685504

    • Peer Reviewed
  • [Journal Article] Tunneling Spectroscopy of Graphene-Boron-nitride Heterostructures2012

    • Author(s)
      F. Amet, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Phys. Rev. B

      Volume: 85巻 Pages: 073405

    • DOI

      10.1103/PhysRevB.85.073405

    • Peer Reviewed
  • [Journal Article] Quantum Hall Effect, Screening, and LayerPolarized Insulating States in Twisted Bilayer Graphene2012

    • Author(s)
      J. D. Sanchez-Yamagishi, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 108巻 Pages: 076601

    • DOI

      10.1103/PhysRevLett.108.076601

    • Peer Reviewed
  • [Journal Article] Long-Wavelength Local Density of States Oscillations Near Graphene Step Edges2012

    • Author(s)
      J. Xue, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Phys. Rev. Lett.

      Volume: 108巻 Pages: 016801

    • DOI

      10.1103/PhysRevLett.108.016801

    • Peer Reviewed
  • [Journal Article] BN/graphene/BN Transistors for Rf Applications2011

    • Author(s)
      H. Wang, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      IEEE Electron Device Lett.

      Volume: 32巻 Pages: 1209-1211

    • DOI

      10.1109/LED.2011.2160611

    • Peer Reviewed
  • [Journal Article] Boron Nitride Substrates for High Mobility Chemical Vapor Deposited Graphene2011

    • Author(s)
      W. Gannett, K. Watanabe, T. Taniguchi 他3名
    • Journal Title

      Appl. Phys. Lett.

      Volume: 98巻 Pages: 242105

    • DOI

      10.1063/1.3599708

    • Peer Reviewed
  • [Journal Article] Micrometer -Scale Ballistic Transport in Encapsulated Graphene At Room Temperature2011

    • Author(s)
      A. S. Mayorov, K. Watanabe, T. Taniguchi 他9名
    • Journal Title

      Nano Letters

      Volume: 11巻 Pages: 2396-2399

    • DOI

      10.1021/nl200758b

    • Peer Reviewed
  • [Journal Article] Exciton Optical Transitions in a Hexagonal Boron Nitride Single Crystal2011

    • Author(s)
      L. Museur, K. Watanabe, T. Taniguchi 他8名
    • Journal Title

      physica status solidi (RRL) . Rapid Research Letters

      Volume: 5巻 Pages: 214-216

    • DOI

      10.1002/pssr.201105190

    • Peer Reviewed
  • [Journal Article] Luminescence Characteristics and Annealing Effect of Tb-Doped AlBO Films for Inorganic Electroluminescence Devices2011

    • Author(s)
      K. Masumoto, K. Watanabe, T. Taniguchi 他4名
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 50巻 Pages: 04DH01

    • DOI

      10.1143/JJAP.50.04DH01

    • Peer Reviewed
  • [Presentation] 高圧合成法による高純度窒化ホウ素単結晶研究の現状と新しい応用展開2013

    • Author(s)
      渡邊賢司
    • Organizer
      第15回応用物理学会プラズマエレクトロニクス分科会新領域研究会
    • Place of Presentation
      名古屋市、愛知県
    • Year and Date
      2013-11-22
    • Invited
  • [Presentation] 高温高圧法により育成した六方晶窒化ホウ素単結晶劈開面のカソードルミネッセンス像観察2013

    • Author(s)
      渡邊賢司
    • Organizer
      第27回ダイヤモンドシンポジウム
    • Place of Presentation
      南埼玉郡、埼玉県
    • Year and Date
      2013-11-21
  • [Presentation] Synthesis of high purity hBN single crystals by using solvent growth p rocess2013

    • Author(s)
      谷口尚
    • Organizer
      5th International Conf on Recent Progress in Graphene Research
    • Place of Presentation
      東京都
    • Year and Date
      2013-09-11
    • Invited
  • [Presentation] Luminescence image of cleaved crystal in hexagonal boron nitride grown by temperature gradient method2013

    • Author(s)
      渡邊賢司
    • Organizer
      第32回電子材料シンポジウム
    • Place of Presentation
      守山市,滋賀県
    • Year and Date
      2013-07-11
  • [Presentation] Optical Properties of Boron Nitride Single Crystals2013

    • Author(s)
      Kenji Watanabe
    • Organizer
      CLEO-PR 2013
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2013-07-01
    • Invited
  • [Presentation] Near-band edge optical properties of hexagonal boron nitride2012

    • Author(s)
      A.Pierret
    • Organizer
      International Workshop on Nitride Semiconductors 2012
    • Place of Presentation
      Sapporo、Japan
    • Year and Date
      2012-10-17
  • [Presentation] Fluorescence properties of hexagonal boron nitride singlecrystal powder2011

    • Author(s)
      渡邊賢司
    • Organizer
      第30回電子材料シンポジウム
    • Place of Presentation
      守山市、滋賀県
    • Year and Date
      2011-07-01
  • [Presentation] Excitonic fluorescence for hBN single-crystal powder2011

    • Author(s)
      Kenji Watanabe
    • Organizer
      NDNC2011
    • Place of Presentation
      Matsue、Japan
    • Year and Date
      2011-05-19
  • [Presentation] 六方晶窒化ホウ素単結晶の光学特性とその応用2011

    • Author(s)
      渡邊賢司
    • Organizer
      日本学術振興会ワイドギャップ半導体光・電子デバイス第162委員会
    • Place of Presentation
      東京都
    • Year and Date
      2011-04-22
    • Invited
  • [Book] サイエンス誌に載った日本人研究者2013、"2次元的物質との1次元的電気接触"2014

    • Author(s)
      渡邊賢司、谷口尚
    • Total Pages
      69
    • Publisher
      AAAS
  • [Book] 脚光を浴びる高純度hBN"、82巻12号2013

    • Author(s)
      谷口尚、渡邊賢司
    • Total Pages
      1060-1061
    • Publisher
      OYO BUTURI
  • [Book] サイエンス誌に載った日本人研究者2011、"六方晶窒化ホウ素基板により新しいグラフェンの特性を発見"2012

    • Author(s)
      渡邊賢司、谷口尚
    • Total Pages
      26
    • Publisher
      AAAS
  • [Book] "グラフェンの特性を活かす六方晶窒化ホウ素基板~六方晶窒化ホウ素応用の進展開~", Vol.104,No.12012

    • Author(s)
      渡邊賢司、谷口尚
    • Total Pages
      37-39
    • Publisher
      (株)オーム社、 NEW DIAMOND
  • [Remarks]

    • URL

      http://www.nims.go.jp/personal/BN_research/index-j_BNR.html

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Published: 2015-06-25  

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