2013 Fiscal Year Final Research Report
Development for X-ray crystal structure analysis of a surface-shallow layer and epitaxial growth of single-crystal thin film
| Project/Area Number |
23350012
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | University of Hyogo |
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Principal Investigator |
TORIUMI Koshiro 兵庫県立大学, 物質理学研究科, 教授 (90124221)
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| Co-Investigator(Kenkyū-buntansha) |
OZAWA Yoshiki 兵庫県立大学, 大学院・物質理学研究科, 准教授 (40204200)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Keywords | 結晶構造解析 / 薄膜結晶 / 表面界面 / 金属錯体化学 / 放射光 / エピタキシャル結晶 |
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| Research Abstract |
The surface film crystals of the chloro-bridged one-dimensional platinum(II,IV) complex have been prepared by epitaxial growth from the aqueous solution on substrate crystals of the bromo-bridged complex. The grazing incidence X-ray diffraction experiments were made using 8 keV micro-focus X-ray beam. X-ray intensities have been measured for both the epitaxial crystal and the substrate crystal having wide and flat surface with unevenness less than 0.15 micron, and corrected for Lp and absorption effects to give the observed intensities. Conventional R indexes calculated for the observed and calculated intensities are 0.04~0.10 for the flat substrate crystal. Although, for the surface film of epitaxial crystal, R indexes are greater than 0.50 for all the observed data, R reduce to 0.03~0.10 for the data appropriately observed. This suggests that X-ray crystal structure analysis of a surface-shallow layer should be a powerful tool to determine three-dimensional surface structure.
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[Presentation] 表面薄膜単結晶のX線構造解析とハロゲン架橋一次元白金(II,IV)錯体のエピタキシャル薄膜結晶作製2013
Author(s)
鳥海幸四郎, 堀本泰洋, 山崎隆博, 井上敬章, 高崎亜希, 山下大輔, 山中宏晃, 満身稔, 小澤芳樹, 宋哲昊, 坂田修身
Organizer
錯体化学会第63回討論会
Place of Presentation
琉球大学千原キャンパス(沖縄県中頭郡)
Year and Date
2013-11-02
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[Presentation] 表面薄膜単結晶のX線構造解析と一次元白金混合原子価錯体のエピタキシャル薄膜結晶作製2013
Author(s)
鳥海幸四郎, 堀本泰洋, 山崎隆博, 井上敬章, 高崎亜希, 山下大輔, 山中宏晃, 満身稔, 小澤芳樹, 宋哲昊, 坂田修身
Organizer
日本結晶学会平成25年度年会
Place of Presentation
熊本大学黒髪南キャンパス(熊本市中央区)
Year and Date
2013-10-13
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