2014 Fiscal Year Final Research Report
Development of new synthetic methodologies based on photochemical carbene formation reaction
| Project/Area Number |
23350016
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
|
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| Research Institution | Gakushuin University (2013)
Tokyo Institute of Technology (2011-2012) |
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Principal Investigator |
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| Project Period (FY) |
2011-04-01 – 2015-03-31
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| Keywords | カルベン / 光反応 / 炭素骨格形成反応 |
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| Outline of Final Research Achievements |
We have investigated the development of new and clean synthetic methodologies by using photochemical processes without aid of metal catalysts.
Photochemical generation of carbenes, highly reactive intermediates, from acylsilanes has scarcely been employed for organic synthesis, so far. In this project, we examined application of this photochemical process to organic reactions with appropriate design of reaction systems and succeeded in developing several useful and original synthetic reactions.
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| Free Research Field |
有機合成化学
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