2013 Fiscal Year Final Research Report
Construction of Luminescent Chromic Metal Complexes with Dynamic Ordering
| Project/Area Number |
23350025
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
KATO Masako 北海道大学, 理学(系)研究科(研究院), 教授 (80214401)
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| Co-Investigator(Kenkyū-buntansha) |
KOBAYASHI Atsushi 北海道大学, 大学院・理学研究院, 講師 (50437753)
CHANG Ho-chol 北海道大学, 大学院・理学研究院, 准教授 (60335198)
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Keywords | 金属錯体 / 発光 / クロミズム / 動的秩序 / 環境応答 |
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| Research Abstract |
The purpose of this project is to construct novel assembled metal complex systems with dynamical ordering by using various intermolecular interactions such as metal-metal, pai-pai, hydrophobic, and hydrogen bonding interactions. In this concept, we have developed luminescent metal complexes which exhibit unique chromic behaviors in response to the various environmental stimuli such as vapor, light, and heat: 1) Vapochromic coordination polymers and suplamolecular restorable systems based on luminescent platinum(II) or ruthenium(II) complexes; 2) Luminescent dinuclear copper(I) complexes which exhibit luminescence changes induced by light and vapor; 3) Vapor and mechanically induced chromic behavior of platinum(II) complexes with a dimer-of-dimer motif and the effect of hetero metal ions.
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