2013 Fiscal Year Final Research Report
Specific free energy picture and solvation structure formed in ionic liquids
| Project/Area Number |
23350033
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Niigata University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
KAMEDA Yasuo 山形大学, 理学部, 教授 (60202024)
KANAKUBO Mitsuhiro 独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 主任研究員 (70286764)
KANZAKI Ryo 鹿児島大学, 理工学研究科, 准教授 (50363320)
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| Project Period (FY) |
2011-11-18 – 2014-03-31
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| Keywords | イオン液体 / CO2 / 溶媒和構造 / 溶媒和自由エネルギー |
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| Research Abstract |
Ionic liqudis show specific liquid and/or solvation structure, which have never been found in ordinary solvents. In this subject, to elucidate specific solvation in ionic liquids at a molecular and/or atomistic level, we foucused on the CO2 solvation in ionic liquids and studied (1) CO2 solvation in ionic liquids in terms of solvation structure and energy by means of molecular simulation asisted liquid structure anakyses and free energy calculations, (2) structure and thermidynamics of CO2 protonatin in ionic liquids, and (3) CO2 electrochemical reduction in ionic liquids.
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