Novel catalytic function of stable 0-valent active species generated from base metal supports

2013 Fiscal Year Final Research Report

• Project/Area Number: 23350044
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Kyushu University
• Principal Investigator: TOKUNAGA MAKOTO 九州大学, 理学(系)研究科(研究院), 教授 (40301767)
• Co-Investigator(Kenkyū-buntansha): ISHIDA Tamao 九州大学, 大学院・理学研究院, 准教授 (90444942) ; HAMASAKI Akiyuki 九州大学, 大学院・理学研究院, 助教 (00515174)
• Project Period (FY): 2011-04-01 – 2014-03-31
• Keywords: 固体触媒 / 金ナノ粒子 / 酸化物担体 / コバルト / ニッケル / パラジウム

Research Abstract

Promotion effect of reduction of base matals was obserbed by the hydrogen reduction in the presence of noble metals including gold and plladium, ehich were supported by deposition-precipitation or co-precipitation method. Hydroformylation, hydroaminomethylation, amidocarbonylation, FT reaction, etc. were able to carried out under milder conditions compared to usual catalysts. In addition, when nickel was used as support metal, Au-Ni alloys were formed and those have high activities for debenzylation.

Research Products

• [Journal Article] Cooperative Catalysis of Palladium Nanoparticles and Cobalt Oxide Support for Formylation of Aryl Iodides under Syngas Atmosphere (2014)
  • Author(s): Hamasaki, A.; Yasutake, Y.; Norio, T.; Ishida, T.; Akita, T.; Ohashi, H.; Yokoyama, T.; Honma, T.; Tokunaga, M
  • Journal Title: Appl. Catal. A Gen Volume: 469 Pages: 146-152
  • DOI: 10.1016/j.apcata.2013.09.043
  • Peer Reviewed
• [Journal Article] 金ナノ粒子による担体還元促進作用と新たな触媒機能 (2013)
  • Author(s): 石田玉青, 濱崎昭行, 徳永信
  • Journal Title: 触媒(特集「貴金属触媒の精密構造制御とその活用」) Volume: 55 Pages: 195-200
  • URL: http://ci.nii.ac.jp/naid/40019783916
  • Peer Reviewed
• [Journal Article] Promotional effect of Au on reduction of Ni(II) to form Au-Ni alloy catalysts for hydrogenolysis of benzylic alcohols (2013)
  • Author(s): Nishikawa, H.; Kawamoto, D.; Yamamoto, Y.; Ishida, T.; Ohashi, H.; Akita, T.; Honma, T.; Hamasaki, A.; Yokoyama, T.; Tokunaga, M
  • Journal Title: J. Catal Volume: 307 Pages: 254-264
  • DOI: 10.1016/j.jcat.2013.07.027
  • Peer Reviewed
• [Journal Article] Gold Nanoparticles Assisted Formation of Cobalt Species for Intermolecular Hydroaminomethylation and Intramolecular Cyclocarbonylation of Olefins (2013)
  • Author(s): Liu, X.; Hamasaki, A.; Yamane, Y.; Aikawa, S.; Ishida, T.; Haruta, M.; Tokunaga, M
  • Journal Title: Catal. Sci. Tech Volume: 3 Pages: 3000-3006
  • DOI: 10.1039/C3CY00336A
  • Peer Reviewed
• [Journal Article] Synthesis of higher alcohols by Fischer-Tropsch synthesis over alkali metal-modified cobalt catalysts (2013)
  • Author(s): Ishida, T.; Yanagihara, T.; Liu, X.; Ohashi, H.; Hamasaki, A.; Honma, T.; Oji, H.; Yokoyama, T.; Tokunaga, M
  • Journal Title: Appl. Catal. A Gen Volume: 458 Pages: 145 -154
  • DOI: 10.1016/j.apcata.2013.03.042
  • Peer Reviewed
• [Journal Article] 酸化物担持金ナノ粒子による新たな触媒機能 (2013)
  • Author(s): 濱崎昭行, 石田玉青, 徳永信
  • Journal Title: 有機合成化学協会誌 Volume: 71 Pages: 443-451
  • DOI: 10.5059/yukigoseikyokaishi.71.443
  • Peer Reviewed
• [Journal Article] X 線吸収分光法と197Au Mössbauer 分光法を組み合わせた金属酸化物担持金触媒のキャラクタリゼーション : 金合金生成の確認 (2012)
  • Author(s): 川本大祐, 西川裕昭, 大橋弘範,陰地宏, 本間徹生, 小林康浩, 濱崎昭行,石田玉青, 岡上吉広, 徳永信, 横山拓史
  • Journal Title: X 線分析の進歩 Volume: 43 Pages: 293-302
  • Peer Reviewed
• [Journal Article] 酸化ニッケル担持金触媒の状態分析 (2012)
  • Author(s): 西川裕昭, 川本大祐, 大橋弘範,陰地宏, 本間徹生, 小林康浩, 岡上吉広,濱崎昭行, 石田玉青, 横山拓史, 徳永信
  • Journal Title: X 線分析の進歩 Volume: 43 Pages: 285-292
  • Peer Reviewed
• [Journal Article] Cobalt oxide supported gold nanoparticles as a stable and readily-prepared precursor for the in situ generation of cobalt carbonyl like species (2011)
  • Author(s): Hamasaki, A.; Muto, A.; Haraguchi, S.; Liu, X.; Sakakibara, T.; Yokoyama, T.; Tokunaga, M
  • Journal Title: Tetrahedron Lett Volume: 52 Pages: 6869-6872
  • DOI: 10.1016/j.tetlet.2011.09.067
  • Peer Reviewed
• [Journal Article] Anti-ASF distribution in Fischer-Tropsch Synthesis over Unsupported Cobalt Catalysts in a Batch Slurry Phase Reactor (2011)
  • Author(s): Liu, X.; Hamasaki, A.; Honma, T.; Tokunaga, M
  • Journal Title: Catal. Today Volume: 175 Pages: 494-503
  • DOI: 10.1016/j.cattod.2011.03.030
  • Peer Reviewed
• [Presentation] 金を助触媒としたハイパフォーマンスな有機合成 (2013)
  • Author(s): 徳永信
  • Organizer: 第3回公開シンポジウム「ナノ界面が生み出す次世代機能」
  • Place of Presentation: 東京
  • Year and Date: 2013-12-16
• [Presentation] 金ナノ粒子による担体酸化物の還元促進効果を利用した触媒反応 (2012)
  • Author(s): 徳永信
  • Organizer: 第110回触媒討論会
  • Place of Presentation: 福岡
  • Year and Date: 2012-09-26
• [Presentation] Au/Co3O4 catalyzed hydroaminomethylation and related carbonylations (2012)
  • Author(s): A. Hamasaki, X. Liu, A. Muto, T. Ishida, T. Honma, H. Ohashi, T. Yokoyama, M. Tokunaga
  • Organizer: The 6th International Conference on Gold Science, Technology and its Applications (Gold2012)
  • Place of Presentation: Post Conference, Kyoto
  • Year and Date: 2012-09-10
• [Presentation] Organic Transformations by Metal Oxide Supported Heterogeneous Gold Catalysts (2012)
  • Author(s): Makoto Tokunaga
  • Organizer: The 6th International Conference on Gold Science, Technology and its Applications (Gold2012)
  • Place of Presentation: CREST Symposium, Tokyo
  • Year and Date: 2012-09-08
• [Presentation] Synergistic effect of gold nano-particle and oxide supports for catalytic reactions (2011)
  • Author(s): Makoto Tokunaga
  • Organizer: The 4 th Pusan National Univ. Global COE Kyushu Univ. Joint Symposium on Molecular Science and Technology
  • Place of Presentation: Busan,Korea
  • Year and Date: 2011-12-21
• [Presentation] 酸化物担持金ナノ粒子触媒による有機合成および炭素資源変換反応,新化学技術推進協会 (2011)
  • Author(s): 徳永信
  • Organizer: 先端化学・材料技術部会・高選択性反応分科会
  • Place of Presentation: 東京
  • Year and Date: 2011-12-01
• [Presentation] 酸化コバルト担持パラジウム触媒によるヨウ化アリールのホルミル化 (2011)
  • Author(s): 則尾貴史・安武祐太郎・濱崎昭行・石田玉青・大橋弘範・○徳永信
  • Organizer: 第108回触媒討論会
  • Place of Presentation: 北見
  • Year and Date: 2011-09-20
• [Presentation] Syngas Transformation By Cobalt Oxide Supported Gold Nanoparticle Catalysts (2011)
  • Author(s): Makoto Tokunaga
  • Organizer: 14th Asian Chemical Congress 2011, Contemporary Chemistry for Sustainability and Economic Suffucuency
  • Place of Presentation: Bangkok,Thailand
  • Year and Date: 2011-09-06
• [Presentation] 酸化物担持金属ナノ粒子の触媒機能を探る (2011)
  • Author(s): 徳永信
  • Organizer: 第23回若手研究者のためのセミナー
  • Place of Presentation: 有機合成化学協会九州山口支部,福岡
  • Year and Date: 2011-08-27
• [Patent(Industrial Property Rights)] N-アシルアミノ酸の製造方法 (2013)
  • Inventor(s): 徳永信, 石田玉青, 濱崎昭行, 柳原達也, 小林可奈
  • Industrial Property Rights Holder: 九州大学, 住友化学
  • Industrial Property Rights Type: 特許出願
  • Industrial Property Number: 2013-72524
  • Filing Date: 2013-03-29