2013 Fiscal Year Final Research Report
Innovation of the Asymmetric Reactions by Means of Chiral Bronsted Acid
| Project/Area Number |
23350046
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
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| Project Period (FY) |
2011-04-01 – 2014-03-31
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| Keywords | 有機分子触媒 / キラルブレンステッド酸 / 不斉合成 / 不斉還元 / 触媒 / リン酸 |
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| Research Abstract |
Development of an efficient method for the preparation of the desired compounds is an important task in the fields of chemistry because it will lead to the preservation of the environment of the earth and will avoid wasting natural resources. We already reported that chiral phosphoric acid derived from (R)-BINOL functioned as an efficient chiral Bronsted acid catalyst. In this study, we developed efficient method for the preparation of a number of synthetically important intermediates which will be employed for the synthesis of biologically important compounds such as agrochemicals and pharmaceuticals.
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