• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2013 Fiscal Year Final Research Report

Science of soft materials with organic-inorganic network structure - structure control and creation of new functions -

Research Project

  • PDF
Project/Area Number 23350117
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research Institution一般財団法人川村理化学研究所

Principal Investigator

HARAGUCHI Kazutoshi  一般財団法人川村理化学研究所, 材料化学研究室, 室長 (10373391)

Co-Investigator(Kenkyū-buntansha) TAKADA Tetsuo  一般財団法人川村理化学研究所, 材料化学研究室, 主席研究員 (00425670)
KATO Shinji  一般財団法人川村理化学研究所, 高分子化学研究室, 室長 (10415458)
TAKEHISA Toru  一般財団法人川村理化学研究所, 材料化学研究室, 研究主任 (70425669)
Co-Investigator(Renkei-kenkyūsha) DHARMESH Varade  一般財団法人川村理化学研究所, 材料化学研究室, 客員研究員
OHBAYASHI Akira  一般財団法人川村理化学研究所, 材料化学研究室, 研究員
NOMURA Mitsuko  一般財団法人川村理化学研究所, 材料化学研究室, 派遣研究員
REN Huai-yin  一般財団法人川村理化学研究所, 材料化学研究室, 東華大学院博士学生
NING Jinyan  一般財団法人川村理化学研究所, 材料化学研究室, 東華大学院博士学生
LI Feng  一般財団法人川村理化学研究所, 材料化学研究室, 客員研究員
Project Period (FY) 2011-04-01 – 2014-03-31
Keywordsナノ材料 / 複合材料物性 / 表面・界面物性 / ヒドロゲル / 触媒
Research Abstract

We have studied on the precise controls of organic/inorganic network structure, morphology, stimuli-sensitivities, mechanical and catalytic properties, and phase transition in soft hybrid materials such as nanocomposite (NC) gels and N-NCs. We found many new functions such as self-healing, autonomous deswelling, cell cultivation and thermoresponsive detachment, etc. Further, we created novel soft NC and clay-mediated noble metal nanoparticles/clay hybrid materials, such as new stimuli-sensitive MD-NC gel, zwitterionic NC gel, aqueous dispersion of NC microspheres, MDM and (MD)4 block copolymers, Ag/clay hybrid, Pt/(f)clay hybrids, and core-shell nanostructured Pt-Pd/clay and Pt-Au/clay hybrids.

  • Research Products

    (40 results)

All 2014 2013 2012 2011

All Journal Article (32 results) (of which Peer Reviewed: 32 results) Presentation (4 results) Book (4 results)

  • [Journal Article] Platinum-Polymer-Clay Nanocomposite Hydrogels via Exfoliated Clay-Mediated In Situ Reduction2014

    • Author(s)
      Kazutoshi Haraguchi, Dharmesh Varade
    • Journal Title

      Polymer

      Volume: (in press)

    • DOI

      10.1016/j.polymer.2014.03.040

    • Peer Reviewed
  • [Journal Article] Polymer-Clay Nanocomposite Microspheres and their Thermosensitive Characteristics2014

    • Author(s)
      Kazutoshi Haraguchi, Tetsuo Takada
    • Journal Title

      Macromol. Chem. Phys

      Volume: Vol. 215 Pages: 295-305

    • DOI

      10.1002/macp.201300593

    • Peer Reviewed
  • [Journal Article] Effects of Polymer Concentration on Structure and Properties of Zwitterionic Nanocomposite Gels2014

    • Author(s)
      Jinyan Ning, Guang Li, Kazutoshi Haraguchi
    • Journal Title

      Macromol. Chem. Phys

      Volume: Vol. 215 Pages: 235-244

    • DOI

      10.1002/macp.201300637

    • Peer Reviewed
  • [Journal Article] Novel Bimetallic Core-Shell Nanocrystal/Clay Composites with Superior Catalytic Activities2014

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      Chem. Comm

      Volume: Vol. 50 Pages: 3014-3017

    • DOI

      10.1039/C3CC49110B

    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Highly Planar Flexible Silver Crystal Belts2014

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: Vol. 16 Pages: 880-884

    • DOI

      10.1039/C3CP54214A

    • Peer Reviewed
  • [Journal Article] ネットワーク再構築による高分子ゲルの自己修復2014

    • Author(s)
      原口和敏
    • Journal Title

      科学と工業

      Volume: Vol. 88 Pages: 57-64

    • Peer Reviewed
  • [Journal Article] Superior CO Catalytic Oxidation on Novel Pt/Clay Nanocomposites2013

    • Author(s)
      Dharmesh Varade, Hideki Abe, Yusuke Yamauchi, Kazutoshi Haraguchi
    • Journal Title

      ACS Appl. Mater. Inter.

      Volume: Vol. 5 Pages: 11613-11617

    • DOI

      10.1021/am402998q

    • Peer Reviewed
  • [Journal Article] Super-thermostable Platinum Nanoparticles on Fluorinated Clay2013

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: Vol. 15 Pages: 16477-16480

    • DOI

      10.1039/c3cp52938j

    • Peer Reviewed
  • [Journal Article] Stimuli-Responsive Properties of Nanocomposite Gels Comprising (2-methoxyethylacrylate-co-N, N-dime thylacrylamide) Copolymer-Clay Networks2013

    • Author(s)
      Kazutoshi Haraguchi, Kazutaka Murata, Toru Takehisa
    • Journal Title

      Macromol. Symposia

      Volume: Vol. 329 Pages: 150-161

    • DOI

      10.1002/masy.201300026

    • Peer Reviewed
  • [Journal Article] Synthesis of Highly Stretchable, Mechanically Tough, Zwitterionic Sulfobetaine Nanocomposite Gels with Controlled Thermosensitivities2013

    • Author(s)
      Jinyan Ning, Guang Li, Kazutoshi Haraguchi
    • Journal Title

      Macromolecules

      Volume: Vol. 46 Pages: 5317-5328

    • DOI

      10.1021/ma4009059

    • Peer Reviewed
  • [Journal Article] Characteristics of Zwitterionic Sulfobetaine Acrylamide Polymer and the Hydrogels Prepared by Free-radical Polymerization and Effects of Physical and Chemical Crosslinks on the UCST2013

    • Author(s)
      Jinyan Ning, Kazuomi Kubota, Guang Li, Kazutoshi Haraguchi
    • Journal Title

      React. Funct. Polym

      Volume: Vol. 73 Pages: 969-978

    • DOI

      10.1016/j.reactfunctpolym.2012.11.005

    • Peer Reviewed
  • [Journal Article] Synthesis of Highly Active and Thermally Stable Nanostructured Pt/Clay Materials by Clay Mediated in Situ Reduction2013

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      Langmuir

      Volume: Vol. 29 Pages: 1977-1984

    • DOI

      10.1021/la3044945

    • Peer Reviewed
  • [Journal Article] Proliferation and Harvest of Human Mesenchymal Stem Cells Using New Thermoresponsive Nanocomposite Gels2013

    • Author(s)
      Noriko Kotobuki, Kazutaka Murata, Kazutoshi Haraguchi
    • Journal Title

      J. Biomed. Mater. Res. A

      Volume: Vol. 101 Pages: 537-546

    • DOI

      10.1002/jbm.a.34355

    • Peer Reviewed
  • [Journal Article] Nanocomposite Gels Consisting of a Unique Polymer/Clay Network and Their Characteristics2013

    • Author(s)
      Kazutoshi Haraguchi
    • Journal Title

      CMC Workshop Lectures

      Volume: Vol. 18 Pages: 41-74

    • DOI

      10.1346CMS-WLS-18.3

    • Peer Reviewed
  • [Journal Article] 機能性ソフトナノコンポジット2013

    • Author(s)
      原口和敏
    • Journal Title

      成形加工

      Volume: Vol. 25 Pages: 125-130

    • Peer Reviewed
  • [Journal Article] 自己修復性高分子ヒドロゲル2013

    • Author(s)
      原口和敏
    • Journal Title

      高分子

      Volume: Vol. 62 Pages: 383-384

    • Peer Reviewed
  • [Journal Article] Stimuli-Responsive Nanocomposite Gels and Soft Nanocomposites Consisting of Inorganic Clays and Copolymers with Different Chemical Affinities2012

    • Author(s)
      Kazutoshi Haraguchi, Kazutaka Murata, Toru Takehisa
    • Journal Title

      Macromolecules

      Volume: Vol. 45 Pages: 385-391

    • DOI

      10.1021/ma202114z

    • Peer Reviewed
  • [Journal Article] One-Pot Synthesis of Noble Metal Nanoparticles and their Ordered Self-Assembly Nanostructures2012

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      Soft Matter

      Volume: Vol. 8 Pages: 3743-3746

    • DOI

      10.1039/c2sm07004a

    • Peer Reviewed
  • [Journal Article] Effects of Counter Ions of Clay Platelets on the Swelling Behavior of Nanocomposite Gels2012

    • Author(s)
      Huai-Yin Ren, Meifang Zhu, Kazutoshi Haraguchi
    • Journal Title

      J. Colloid Interface Sci.

      Volume: Vol. 375 Pages: 134-141

    • DOI

      10.1016/j.jcis.2012.02.032

    • Peer Reviewed
  • [Journal Article] Stress Relaxation and Hysteresis of Nanocomposite Gel Investigated by SAXS and SANS Measurement2012

    • Author(s)
      Toshihiko Nishida, Akira Ohbayashi, Kazutoshi Haraguchi, Mitsuhiro Shibayama
    • Journal Title

      Polymer (United Kingdom)

      Volume: Vol. 53 Pages: 4533-4538

    • DOI

      10.1016/j.polymer.2012.07.038

    • Peer Reviewed
  • [Journal Article] Efficient Approach for Preparing Gold Nanoparticles in Layered Double Hydroxide : Synthesis, Structure, and Properties2012

    • Author(s)
      Dharmesh Varade, Kazutoshi Haraguchi
    • Journal Title

      J. Mater. Chem

      Volume: Vol. 22 Pages: 17649-17655

    • DOI

      10.1016/j.polymer.2012.07.038

    • Peer Reviewed
  • [Journal Article] Thermal Analyses of Poly(N-isopropylacrylamide) in Aqueous Solutions and in Nanocomposite Gels2012

    • Author(s)
      Kazutoshi Haraguchi, Yingjia Xu
    • Journal Title

      Colloid Polym. Sci.

      Volume: Vol. 290 Pages: 1627-1636

    • DOI

      10.1007/s00396-012-2694-y

    • Peer Reviewed
  • [Journal Article] Development of Soft Nanocomposite Materials and Their Applications in Cell Culture and Tissue Engineering2012

    • Author(s)
      Kazutoshi Haraguchi
    • Journal Title

      J. Stem Cells Regenerative Medicine (JSRM)

      Volume: Vol. 8 Pages: 2-11

    • Peer Reviewed
  • [Journal Article] ナノコンポジットゲル材料2012

    • Author(s)
      原口和敏
    • Journal Title

      ファインケミカル9月号

      Volume: Vol. 41 Pages: 18-25

    • Peer Reviewed
  • [Journal Article] 有機-無機ネットワークの分子論考察その22012

    • Author(s)
      原口和敏
    • Journal Title

      ネットワークポリマー

      Volume: Vol. 33 Pages: 341-353

    • Peer Reviewed
  • [Journal Article] Stimuli-Responsive Nanocomposite Gels2011

    • Author(s)
      Kazutoshi Haraguchi
    • Journal Title

      Colloid Polym. Sci

      Volume: Vol. 289 Pages: 455-473

    • DOI

      10.1007/s00396-010-2373-9

    • Peer Reviewed
  • [Journal Article] Self-healing in Nanocomposite Hydrogels2011

    • Author(s)
      Kazutoshi Haraguchi, Kazuhisa Uyama Hisashi Tanimoto
    • Journal Title

      Macromol. Rapid Commun

      Volume: Vol. 32 Pages: 1253-1258

    • DOI

      10.1002/marc.201100248

    • Peer Reviewed
  • [Journal Article] Poly(N-isopropylacrylamide) Prepared by Free-Radical Polymerization in Aqueous Solutions and in Nanocomposite Hydrogels2011

    • Author(s)
      Kazutoshi Haraguchi, Yingjia Xu, Guang Li
    • Journal Title

      Macromol. Symp

      Volume: Vol. 306-307 Pages: 33-48

    • DOI

      10.1002/masy.201000149

    • Peer Reviewed
  • [Journal Article] Characteristic Swelling-Deswelling of Polymer/Clay Nanocomposite Gels2011

    • Author(s)
      Huai-Yin Ren, Meifang Zhu, Kazutoshi Haraguchi
    • Journal Title

      Macromolecules

      Volume: Vol. 44 Pages: 8516-8526

    • DOI

      10.1021/ma201272j

    • Peer Reviewed
  • [Journal Article] Thermoresponsible Cell Adhesion / Detachment on Transparent Nanocomposite Films Consisting of Poly(2-methoxyethyl acrylate) and Clay2011

    • Author(s)
      Kazutoshi Haraguchi, Sakie Masatoshi, Noriko Kotobuki, Kazutaka Murata
    • Journal Title

      J. Biomater. Sci. Polym. Ed

      Volume: Vol. 22, 48 Pages: 2389-2406, 36-37

    • DOI

      10.1163/092050610X540459

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Soft Nanocomposite Materials with Novel Organic/Inorganic Network Structures2011

    • Author(s)
      Kazutoshi Haraguchi
    • Journal Title

      Polym. J

      Volume: Vol. 43 Pages: 223-241

    • DOI

      10.1038/pj.2010.141

    • Peer Reviewed
  • [Journal Article] 超分子の視点からみたナノコンポジットゲルの創成2011

    • Author(s)
      原口和敏
    • Journal Title

      化学工業12月号

      Volume: Vol. 62 Pages: 948-953

    • Peer Reviewed
  • [Presentation] New Stimuli-Responsive Nanocomposite Gels with LCST and UCST Type Phase Transitions.2014

    • Author(s)
      Kazutoshi Haraguchi
    • Organizer
      Asian Polymer Association (APA2014)
    • Place of Presentation
      India Habitat Centre, New Delhi, India
    • Year and Date
      2014-02-19
  • [Presentation] 有機/無機ハイブリッド材料の展開2012

    • Author(s)
      原口和敏
    • Organizer
      無機マテリアル学会第124回学術講演会
    • Place of Presentation
      船橋市民文化創造館, 船橋
    • Year and Date
      2012-06-07
  • [Presentation] 高分子ゲルの新展開2011

    • Author(s)
      原口和敏
    • Organizer
      Webinar講演会(高分子学会)
    • Place of Presentation
      高分子学会, web上での講演
    • Year and Date
      2011-08-23
  • [Presentation] Soft Nanocomposite Materials with Novel Organic/Inorganic Network Structures2011

    • Author(s)
      Kazutoshi Haraguchi
    • Organizer
      2011 International Conference on Advanced Fibers and Polymer Materials (ICAFPM)
    • Place of Presentation
      Donghua Univ/Shanghai
    • Year and Date
      2011-08-16
  • [Book] 高分子ナノテクノロジーハンドブック2014

    • Author(s)
      原口和敏
    • Total Pages
      1120
    • Publisher
      エヌ・ティー・エス出版
  • [Book] ゾル-ゲル法の最新応用と展望2014

    • Author(s)
      原口和敏
    • Total Pages
      320
    • Publisher
      シーエムシー出版
  • [Book] Encyclopedia of Biomedical Polymers and Polymeric Biomaterials (Ed. by Munmaya Mishra)2014

    • Author(s)
      Kazutoshi Haraguchi
    • Total Pages
      8000
    • Publisher
      Taylor & Francis Group
  • [Book] Advances in Polymer Nanocomposites (Ed. by Fengge Gao)2012

    • Author(s)
      Kazutoshi Haraguchi
    • Total Pages
      6800
    • Publisher
      Woodhead Publishing Ltd

URL: 

Published: 2015-06-25  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi