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2013 Fiscal Year Final Research Report

New functionality of organic-inorganic hybrids with chemically modified nanoparticles and development of innovative devices based on the hybrids

Research Project

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Project/Area Number 23360140
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionOsaka Prefecture University

Principal Investigator

NAITO Hiroyoshi  大阪府立大学, 工学(系)研究科(研究院), 教授 (90172254)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Takashi  大阪府立大学, 大学院・工学研究科, 准教授 (10342784)
NAGASE Takashi  大阪府立大学, 大学院・工学研究科, 助教 (00399536)
MATSUKAWA Kiminori  大阪市立工業研究所, 電子材料研究部, 部長 (90416321)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords電子・電気材料 / 電子デバイス・機器 / 半導体物性 / 光物性 / 太陽電池
Research Abstract

Thin film transistors have been fabricated using a mixture of organic semiconductors silica nanoparticles whose surfaces are chemically modified. The thin film transistors exhibit excellent electrical characteristics because of improved coatability on hydrophobic surfaces and improved crystallinity of organic semiconductors. New thin film transistor production processes have been established from the findings. Organic-inorganic hybrid bulk heterojunction solar cells have also been fabricated, and the device lifetime of the hybrid solar cells is found to be much improved in comparison with conventional organic solar cells. The interface density of states of the thin film transistor has been determined with impedance spectroscopy, and it is demonstrated that the density of states at the organic-inorganic hybrid gate insulator/organic semiconductor interface is extremely low, indicating that the hybrid materials are suitable to a gate insulator for thin film transistors as well.

  • Research Products

    (7 results)

All 2014 2013 2012 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (2 results) Remarks (1 results)

  • [Journal Article] High performance top-gate field-effect transistors based on poly(3-hexylthiophene) with different alkyl chain lengths2014

    • Author(s)
      K. Takagi, T. Nagase, T. Kobayashi, H. Naito
    • Journal Title

      Org. Electron

      Volume: 15 Pages: 372-377

    • Peer Reviewed
  • [Journal Article] Angular distribution of field-effect mobility in oriented poly[5, 50-bis(3-dodecyl-2-thienyl)-2 , 20-bithiophene] fabricated by roll-transfer printing2014

    • Author(s)
      T. Kushida, T. Nagase, H. Naito
    • Journal Title

      Appl. Phys. Lett

      Volume: 104 Pages: 93304

    • Peer Reviewed
  • [Journal Article] Structure of electron collection electrode in dye-sensitized nanocrystalline TiO22013

    • Author(s)
      M. Yanagida, Y. Numata, K. Yoshimatsu, M. Ochiai, H. Naito and L. Han
    • Journal Title

      Electrochemica Acta

      Volume: 87巻 Pages: 309-316

    • Peer Reviewed
  • [Journal Article] Polysilsesquioxanes for gate insulating materials of organic thin-film transistors2012

    • Author(s)
      K. Matsukawa, M. Watanabe, T. Hamada, T. Nagase and H. Naito
    • Journal Title

      International Journal of Polymer Science

      Volume: 2012巻 Pages: 852063

    • Peer Reviewed
  • [Presentation] Device performance of top-gate organic transistors with embedded electrodes : Effects of thin and planar C8-BTBT layer on FET characteristics2013

    • Author(s)
      Y. Kimura, T. Nagase, T. Kobayashi, K. Takimiya, M. Ikeda, H. Naito
    • Organizer
      International Conference on Solid State Devices and Materials 2013
    • Place of Presentation
      Fukuoka
    • Year and Date
      20130925-27
  • [Presentation] Impedance Spectroscopy for Characterization of Organic Light-emitting Diodes and Organic Solar Cells(Plenary Talk)2013

    • Author(s)
      H. Naito
    • Organizer
      9th International Symposium on Electrochemical Impedance Spectroscopy
    • Place of Presentation
      Okinawa
    • Year and Date
      20130617-21
  • [Remarks]

    • URL

      http://pe3.pe.osakafu-u.ac.jp/

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Published: 2015-06-25  

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