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2013 Fiscal Year Final Research Report

Standardization of leaching, immobilization, and adsorption experiments for excavated rock samples

Research Project

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Project/Area Number 23360202
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Geotechnical engineering
Research InstitutionHokkaido University

Principal Investigator

IGARASHI Toshifumi  北海道大学, 工学(系)研究科(研究院), 教授 (90301944)

Co-Investigator(Kenkyū-buntansha) YONEDA Tetsuro  北海道大学, 大学院・工学研究院, 客員教授 (00002056)
KAWASAKI Satoru  北海道大学, 大学院・工学研究院, 准教授 (00304022)
Co-Investigator(Renkei-kenkyūsha) TAMOTO Shuichi  独立行政法人土木研究所, 寒地土木研究所 (60414231)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords環境技術 / 地盤工学 / 土壌圏現象 / 地下水 / 固液相反応 / 溶出 / 不溶化 / 吸着
Research Abstract

Batch and column leaching experiments using mudstone samples were conducted to understand the leaching processes and mechanisms of arsenic, selenium, and boron. The results showed that two leaching mechanisms, consisting of a rapid leaching related to easily leachable fraction and a slower leaching related to pyrite oxidation, controlled the phenomena. The results of both batch and column leaching experiments can be explained by the two fractions.
Batch and column adsorption experiments for the leached arsenic, selenium, and boron were carried out to elucidate the adsorption processes. The results showed that the leached arsenic, selenium, and boron were adsorbed by not only artificial adsorbents but also natural adsorbents like volcanic ashes when the pH did not change dramatically.

  • Research Products

    (35 results)

All 2014 2013 2012 Other

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (20 results) (of which Invited: 1 results) Remarks (1 results)

  • [Journal Article] Leaching of boron, arsenic and selenium from sedimentary rocks : II. pH dependence, speciation and mechanisms of release2014

    • Author(s)
      C.B. Tabelin, A. Hashimoto, T. Igarashi, T. Yoneda
    • Journal Title

      Science of the Total Environment

      Volume: Vol.473-474 Pages: 244-253

    • DOI

      10.1016/j.scitotenv.2013.12.029

    • Peer Reviewed
  • [Journal Article] Leaching of boron, arsenic and selenium from sedimentary rocks : I. Effects of contact time, mixing speed and liquid-to-solid ratio2014

    • Author(s)
      C. B. Tabelin, A. Hashimoto, T. Igarashi, T. Yoneda
    • Journal Title

      Science of the Total Environment

      Volume: Vol.472 Pages: 620-629

    • DOI

      10.1016/j.scitotenv.2013.11.006

    • Peer Reviewed
  • [Journal Article] Characterization and evaluation of arsenic and boron adsorption onto natural geologic materials, and their application in the disposal of excavated altered rock2014

    • Author(s)
      C. B. Tabelin, T. Igarashi, T. Arima, D. Sato, T. Tatsuhara, S. Tamoto
    • Journal Title

      Geoderma

      Volume: Vol.213 Pages: 163-172

    • DOI

      10.1016/j.geoderma.2013.07.037

    • Peer Reviewed
  • [Journal Article] Porewater chemistry under different layer systems on a sloping surface at a closed mine site2013

    • Author(s)
      O. R. Salinas Villafane, T. Igarashi, M. Kurosawa, T. Takase
    • Journal Title

      Water, Air, & Soil Pollution

      Volume: Vol.224 Pages: 1480(1-12)

    • DOI

      10.1007/s11270-013-1480-x

    • Peer Reviewed
  • [Journal Article] Factors affecting the leaching of nitrogen species from diatomaceous mudstone2013

    • Author(s)
      T. Igarashi, T. Ueda, H. Hokora, M. Jo, H. Kudo
    • Journal Title

      ASEAN Engineering Journal

      Volume: Part C, Vol.2, No.1 Pages: 133-139

    • URL

      http://www.seed-net.org/download/C2_1_paper9.pdf

    • Peer Reviewed
  • [Journal Article] カラム溶出試験による珪藻質泥岩掘削土(ズリ)由来の硝化生成物の溶出に関する影響因子の考察2013

    • Author(s)
      五十嵐敏文・上田貴宏・洞秀幸・城まゆみ・加藤欣也・三代雅崇・工藤元
    • Journal Title

      Journal of MMIJ

      Volume: Vol.130 Pages: 60-64

    • Peer Reviewed
  • [Journal Article] Utilization of natural and artificial adsorbents in the mitigation of arsenic leached from hydrothermally altered rock2013

    • Author(s)
      C. B. Tabelin, T. Igarashi, T. Yoneda, S. Tamamura
    • Journal Title

      Engineering Geology

      Volume: Vol.156 Pages: 58-67

    • DOI

      10.1016/j.enggeo.2013.02.001

    • Peer Reviewed
  • [Journal Article] Mobilization and speciation of arsenic from hydrothermally altered rock containing calcite and pyrite under anoxic conditions2012

    • Author(s)
      C. B. Tabelin, T. Igarashi, T. Yoneda
    • Journal Title

      Applied Geochemistry

      Volume: Vol.27 Pages: 2300-2314

    • DOI

      10.1016/j.apgeochem.2012.04.020

    • Peer Reviewed
  • [Journal Article] The roles of pyrite and calcite in the mobilization of arsenic and lead from hydrothermally altered rocks excavated in Hokkaido, Japan2012

    • Author(s)
      C. B. Tabelin, T. Igarashi, R. Takahashi
    • Journal Title

      Journal of Geochemical Exploration

      Volume: Vol.119 Pages: 17-31

    • DOI

      10.1016/j.gexplo.2012.06.003

    • Peer Reviewed
  • [Journal Article] Removal of arsenic, boron and selenium from excavated rocks by consecutive washing2012

    • Author(s)
      C. B. Tabelin, A. H. M. Basri, T. Igarashi, T. Yoneda
    • Journal Title

      Water, Air, & Soil Pollution

      Volume: Vol.223, No.7 Pages: 4153-4167

    • DOI

      10.1007/s11270-012-1181-x

    • Peer Reviewed
  • [Journal Article] Combined neutralization -adsorption system for the disposal of hydrothermally altered excavated rock producing acidic leachate with hazardous elements2012

    • Author(s)
      T. Tatsuhara, T. Arima, T. Igarashi, C. B. Tabelin
    • Journal Title

      Engineering Geology

      Volume: Vol.139/140 Pages: 76-84

    • Peer Reviewed
  • [Journal Article] Comparison of potentially toxic metals leaching from weathered rocks at a closed mine site between laboratory columns and field observation2012

    • Author(s)
      O. R. Salinas Villafane, T. Igarashi, M. Kurosawa, T. Takase
    • Journal Title

      Applied Geochemistry

      Volume: Vol.27 Pages: 2271-2279

    • DOI

      10.1016/j.apgeochem.2012.08.013

    • Peer Reviewed
  • [Journal Article] Effect of different soil layers on porewater to remediate acidic surface environment at a closed mine site2012

    • Author(s)
      O. R. Salinas Villafane, T. Igarashi, S. Harada, M. Kurosawa, T. Takase
    • Journal Title

      Environment Monitoring and Assessment

      Volume: Vol.184 Pages: 7665-7675

    • DOI

      10.1007/s10661-012-2526-z

    • Peer Reviewed
  • [Journal Article] Mobilization and speciation of arsenic from hydrothermally altered rock in laboratory column experiments under ambient conditions2012

    • Author(s)
      C.B. Tabelin, T. Igarashi, R. Takahashi
    • Journal Title

      Applied Geochemistry

      Volume: Vol.27 Pages: 326-342

    • DOI

      10.1016/j.apgeochem.2011.10.007

    • Peer Reviewed
  • [Presentation] Mineralogy and leaching behavior of mineralized rocks excavated near tunnel construction sites2013

    • Author(s)
      M. Hirota, N. Yokobori, T. Igarashi, T. Yoneda
    • Organizer
      ASEAN++2013
    • Place of Presentation
      Centara Duangtawan Hotel, チェンマイ(タイ)
    • Year and Date
      20131112-13
  • [Presentation] Chemical forms of arsenic and selenium leached from excavated mudstones2013

    • Author(s)
      R. Sasaki, T. Igarashi
    • Organizer
      ASEAN++2013
    • Place of Presentation
      Centara Duangtawan Hotel, チェンマイ(タイ)
    • Year and Date
      20131111-13
  • [Presentation] Arsenic adsorption onto lignite under saturated flow conditions : Experiment and reactive transport modeling2013

    • Author(s)
      C. B. Tabelin, B. Ty, K.K. Mar, D.P.E. Putra, T. Igarashi, T. Yoneda
    • Organizer
      ASEAN++2013
    • Place of Presentation
      Centara Duangtawan Hotel, チェンマイ(タイ)
    • Year and Date
      20131111-13
  • [Presentation] Effectiveness of adsorption layer using natural volcanic ash in reducing arsenic leached from mudstone2013

    • Author(s)
      S. Tamoto, Y. Ito, T. Igarashi
    • Organizer
      ASEAN++2013
    • Place of Presentation
      Centara Duangtawan Hotel, チェンマイ(タイ)
    • Year and Date
      20131111-13
  • [Presentation] 火山灰を利用した掘削ずりからの自然由来ヒ素などの溶出抑制対策に関する考察2013

    • Author(s)
      田本修一・伊東佳彦・五十嵐敏文・龍原毅・有馬孝彦
    • Organizer
      日本応用地質学会平成25年度研究発表会
    • Place of Presentation
      名大
    • Year and Date
      20131024-25
  • [Presentation] トンネル掘削ずりからのヒ素の溶出とその対策2013

    • Author(s)
      五十嵐敏文
    • Organizer
      資源・素材2013
    • Place of Presentation
      札幌, 北大
    • Year and Date
      20130903-05
  • [Presentation]2013

    • Author(s)
      田本修一・岡崎健治・伊東佳彦・五十嵐敏文
    • Organizer
      資源・素材2013
    • Place of Presentation
      札幌, 北大
    • Year and Date
      20130903-05
  • [Presentation] 道央の鉱化変質岩からの重金属類溶出特性2013

    • Author(s)
      横堀野原・五十嵐敏文・米田哲朗
    • Organizer
      資源・素材2013
    • Place of Presentation
      札幌, 北大
    • Year and Date
      20130903-05
  • [Presentation] Application of natural geological materials as adsorbents of arsenic and boron leached from hydrothermally altered rocks2013

    • Author(s)
      T. Igarashi, C.B. Tabelin, T. Arima, D. Sato
    • Organizer
      RCM5&RCNRM5
    • Place of Presentation
      Park Royal Hotel, ペナン(マレーシア)
    • Year and Date
      20130122-23
    • Invited
  • [Presentation] Arsenic adsorption performance of lignite in saturated column experiments2013

    • Author(s)
      K.K. Mar, D. Karnawati, Sarto, D.P.E. Putra, T. Igarashi, C.B. Tabelin
    • Organizer
      The 5th AUN/SEED-Net Regional Conference on Geological Engineering
    • Place of Presentation
      クアラルンプール(マレーシア)
    • Year and Date
      20130115-16
  • [Presentation] 鉱化変質岩からの重金属類溶出特性2013

    • Author(s)
      横堀野原・五十嵐敏文・米田哲朗
    • Organizer
      資源・素材学会北海道支部平成25年度春季講演会
    • Place of Presentation
      北見工大
    • Year and Date
      2013-06-15
  • [Presentation] The importance of pH in the leaching of boron, arsenic and selenium in sedimentary rocks2013

    • Author(s)
      C.B. Tabelin, A. Hashimoto, T. Igarashi, T. Yoneda
    • Organizer
      12th Geo-Environmental Engineering (GEE2013)
    • Place of Presentation
      ソウル大学(韓国)
    • Year and Date
      2013-05-31
  • [Presentation] Leaching of arsenic from hydrothermally altered rock in laboratory saturated-column experiments2012

    • Author(s)
      C.B. Tabelin, T. Igarashi, T. Yoneda
    • Organizer
      The 3rd Arsenic Symposium in Miyazaki
    • Place of Presentation
      宮日会館, 宮崎
    • Year and Date
      20121123-25
  • [Presentation] Chemical forms of arsenic and selenium leached from mudstones2012

    • Author(s)
      T. Igarashi, R. Sasaki, C.B. Tabelin
    • Organizer
      International Symposium on Earth Science and Technology, CINEST 2012
    • Place of Presentation
      バンドン工科大学(インドネシア)
    • Year and Date
      20120918-20
  • [Presentation] Comparison of arsenic adsorption on lignite, bentonite, shale, and iron sand from Indonesia2012

    • Author(s)
      K.K. Mar, D. Karnawati, Sarto, D.P.E. Putra, T. Igarashi, C.B. Tabelin
    • Organizer
      International Symposium on Earth Science and Technology, CINEST 2012
    • Place of Presentation
      バンドン工科大学(インドネシア)
    • Year and Date
      20120918-20
  • [Presentation] 連続溶出試験に基づく泥岩からのヒ素およびセレンの溶出挙動とその化学形態2012

    • Author(s)
      佐々木亮介・五十嵐敏文
    • Organizer
      資源・素材2012
    • Place of Presentation
      秋田, 秋田大
    • Year and Date
      20120911-13
  • [Presentation] Mineralogy and leaching behavior of hydrothermally altered rocks near two closed sulfur mines2012

    • Author(s)
      M. Hirota, T. Igarashi, T. Yoneda
    • Organizer
      The 5th AUN/SEED-Net Regional Conference on Geo-Disaster Mitigation in ASEAN
    • Place of Presentation
      Manila Marriott Hotel, マニラ(フィリピン)
    • Year and Date
      20120906-07
  • [Presentation] Adsorption of arsenic onto lignite, bentonite, shale and iron sand : Effects of pH, particle size and sulfate concentration2012

    • Author(s)
      K.K. Mar, D. Karnawati, Sarto, D.P.E. Putra, T. Igarashi, C.B. Tabelin
    • Organizer
      The 5th AUN/SEED-Net Regional Conference on Geo-Disaster Mitigation in ASEAN
    • Place of Presentation
      Manila Marriott Hotel, マニラ(フィリピン)
    • Year and Date
      20120906-07
  • [Presentation] Leaching of arsenic, boron, selenium and heavy metals from tunnel excavated rocks and their mitigation2012

    • Author(s)
      C.B. Tabelin, T. Arima, T. Igarashi, T. Yoneda
    • Organizer
      Proceedings of the 2nd International Conference on Advances in Mining and Tunneling
    • Place of Presentation
      ハノイ鉱山大学(ベトナム)
    • Year and Date
      20120823-25
  • [Presentation] 泥岩から溶出する重金属類に対する各種吸着材の有効性2012

    • Author(s)
      橋本綾佳・五十嵐敏文
    • Organizer
      日本応用地質学会北海道支部平成24年度研究発表会
    • Place of Presentation
      寒地土木研究所, 札幌
    • Year and Date
      2012-06-22
  • [Remarks]

    • URL

      http://trans-er.eng.hokudai.ac.jp.

URL: 

Published: 2015-06-25  

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