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2013 Fiscal Year Final Research Report

Mechanism of hetero nano-structure formation and electrical properties of relaxor ferroelectric thin films

Research Project

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Project/Area Number 23360283
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

KIGUCHI Takanori  東北大学, 金属材料研究所, 准教授 (70311660)

Co-Investigator(Kenkyū-buntansha) SATO Kazuhisa  東北大学, 金属材料研究所, 助教 (70314424)
Co-Investigator(Renkei-kenkyūsha) NISHIMATSU Tsuyoshi  東北大学, 金属材料研究所, 助教 (70323095)
YAMADA Tomoaki  名古屋大学, 工学研究科, 准教授 (80509349)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywordsリラクサー / 極性ナノ領域 / 化学的秩序構造 / ヘテロナノ組織 / 原子変位 / HAADF-STEM / TEM / 局所弾性場
Research Abstract

This study examined that the formation behavior of chemically ordered regions (CORs) in Pb(Mg1/3Nb2/3)O3 (PMN) thin film. CORs nucleated at the crystallization temperature of 650˚C, which was as half as the processing temperature for bulk PMN crystals. The formation of CORs was occurred mainly by nucleation under the post annealing treatments at 700˚C or 800˚C, and they grow by contacting each other. An atomic resolution compositional analysis was attempted to directly detect Mg/Nb atomic arrangements in the PMN lattice. These results show that the nano-structure design of PMN, inhibition of the growth of COR, would improve electrical properties of PMN.

  • Research Products

    (28 results)

All 2014 2013 2012 2011

All Journal Article (14 results) (of which Peer Reviewed: 12 results) Presentation (14 results)

  • [Journal Article] TEM analysis of the nanostructure of Pb(Mg_<1/3>Nb_<2/3>)O_3 thin films by MOD method2014

    • Author(s)
      Y. Misaka, T. Kiguchi, K. Sato, T. Nishimatsu, T. Yamada, N. Usami, and T.J. Konno
    • Journal Title

      Key Eng. Mater

      Volume: 582 Pages: 19-22

    • DOI

      10.4028/www.scientific.net/KEM.582.19

    • Peer Reviewed
  • [Journal Article] Aberration-corrected STEM analysis of ordered structure in Pb(Mg_<1/3>Nb_<2/3>)0_3 thin films2014

    • Author(s)
      C. Fan, T. Kiguchi, T. Yamada, and T.J. Konno
    • Journal Title

      AMTC Lett

      Volume: 4 Pages: 200-201

  • [Journal Article] Nanostructure around 90° Domain Wall and Elastic Interaction with Misfit Dislocation in PbTiO_3 Thin Film2013

    • Author(s)
      T. Kiguchi, K. Aoyagi, Y. Ehara, H. Funakubo, T. Yamada, N. Usami, T.J. Konno
    • Journal Title

      Key Eng. Mater

      Volume: 566 Pages: 167-170

    • DOI

      10.4028/www.scientific.net/KEM.566.167

    • Peer Reviewed
  • [Journal Article] Analysis of Lattice Defects in an Epitaxial PbTiO_3 Thick Film by Transmission Electron Microscopy2013

    • Author(s)
      K. Aoyagi, T. Kiguchi, Y. Ehara, H. Funakub, and T. J. Konno
    • Journal Title

      Key Eng. Mater

      Volume: 566 Pages: 171-174

    • DOI

      10.4028/www.scientific.net/KEM.566.171

    • Peer Reviewed
  • [Journal Article] Effect of Facing Annealing on Crystallization and Decomposition of Pb(Mg_<1/3>Nb_<2/3>)O_3 Thin Films Prepared by CSD Technique Using MOD Solution2013

    • Author(s)
      T. Kiguchi, Y. Misaka, M. Nishijima, N. Sakamoto, N. Wakiya, H. Suzuki, and T.J. Konno
    • Journal Title

      J. Ceram. Soc. Jpn

      Volume: 121 Pages: 236-241

    • DOI

      10.2109/jcersj2.121.236

    • Peer Reviewed
  • [Journal Article] Effect of Excess Pb on Epitaxial Growth of Pb(Mg_<1/3>Nb_<2/3>)O_3 Thin Films Prepared by Chemical Solution Deposition Process2013

    • Author(s)
      T. Kiguchi, T. Tsukamoto, C. Fan, M. Nishijima, and T.J. Konno
    • Journal Title

      J. Ceram. Soc. Jpn

      Volume: 121 Pages: 638-643

    • DOI

      10.2109/jcersj2.121.638

    • Peer Reviewed
  • [Journal Article] Direct Observation of Atomic Arrangement around 90° Domain Wall in Lead Titanate Thin Film2013

    • Author(s)
      T. Kiguchi, T.J. Konno, Y. Ehara, T. Yamada, and H. Funakubo
    • Journal Title

      Mater. Res. Soc. Symp. Proc

      Volume: 1515 Pages: mrsf12-1515-II05-02-01(6)

    • DOI

      10.1557/opl.2013.1094

    • Peer Reviewed
  • [Journal Article] Fabrication and Evaluation of One-axis Oriented Lead Zirconate Titanate Films using Metal-oxide Nanosheet Interface Layer2013

    • Author(s)
      Y. Minemura, K. Nagasaka, T. Kiguchi, T.J. Konno, H. Funakubo, and H. Uchida
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 52 Pages: 09KA04(7)

    • DOI

      10.7567/JJAP.52.09KA04

    • Peer Reviewed
  • [Journal Article] Stacking Faults in an Epitaxially Grown PbTiO_3 Thick Film and Their Size Distribution2012

    • Author(s)
      K. Aoyagi, Y. Kodama, T. Kiguchi, Y. Ehara, H. Funakubo, and T.J. Konno
    • Journal Title

      Mater. Sci. Eng. B

      Volume: 177 Pages: 528-531

    • DOI

      10.1016/j.mseb.2012.01.013

    • Peer Reviewed
  • [Journal Article] Molecular Dynamics Simulation of 90˚ Ferroelectric Domains in PbTiO_32012

    • Author(s)
      T. Nishimatsu, K. Aoyagi, T. Kiguchi, T.J. Konno, Y. Kawazoe, H. Funakubo, A. Kumar, and U.V. Waghmare
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Pages: 124702(5)

    • DOI

      10.1143/JPSJ.81.124702

    • Peer Reviewed
  • [Journal Article] Configuration and Local Elastic Interaction of Ferroelectric Domains and Misfit Dislocation in PbTiO_3/SrTiO_3 Epitaxial Thin Films2011

    • Author(s)
      T. Kiguchi, K. Aoyagi, Y. Ehara, H. Funakubo, T. Yamada, N. Usami, and T.J. Konno
    • Journal Title

      Sci. Technol. Adv. Mater

      Volume: 12 Pages: 034413(9)

    • DOI

      10.1088/1468-6996/12/3/034413

    • Peer Reviewed
  • [Journal Article] Diffraction Contrast Analysis of 90º and 180º Ferroelectric Domain Structures of PbTiO_3 Thin Films2011

    • Author(s)
      K. Aoyagi, T. Kiguchi, Y. Ehara, T. Yamada, H. Funakubo, and T.J. Konno
    • Journal Title

      Sci. Technol. Adv. Mater

      Volume: 12 Pages: 034403(6)

    • DOI

      10.1088/1468-6996/12/3/034403

    • Peer Reviewed
  • [Journal Article] TEM Observation on Ferroelectric Domain Structures of PbTiO_3 Epitaxial Films2011

    • Author(s)
      K. Aoyagi, T. Kiguchi, Y. Ehara, H. Funakubo, and T.J. Konno
    • Journal Title

      Key Eng. Mater

      Volume: 485 Pages: 179-182

    • DOI

      10.4028/www.scientific.net/KEM.485.179

    • Peer Reviewed
  • [Journal Article] Direct Evidence of Elastic Interaction between Ferroelectric Domain and Misfit Dislocation2011

    • Author(s)
      T. Kiguchi
    • Journal Title

      KINKEN Research Highlights 2011

      Pages: 59-60

  • [Presentation] PMN-PT 薄膜における規則構造の原子分解能観察2014

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 山田智明
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      横浜
    • Year and Date
      2014-03-18
  • [Presentation] Pb(Mg_<1/3>Nb_<2/3>)O_3 薄膜の原子分解能走査型電子顕微鏡観察2014

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 安本洵, 山田智明, 長崎正雅
    • Organizer
      日本顕微鏡学会 第38回関東支部講演会
    • Place of Presentation
      東京
    • Year and Date
      2014-03-08
  • [Presentation] Pb(Mg_<1/3>Nb_<2/3>)O_3薄膜における化学的秩序構造2014

    • Author(s)
      木口賢紀, 範滄宇, 今野豊彦, 安本洵, 長崎正雅, 山田智明
    • Organizer
      日本セラミックス協会第52回セラミックス基礎科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-01-09
  • [Presentation] Atomic resolution imaging for Pb-based ferroelectric thin film s using aberration-corrected electron mic roscopy2014

    • Author(s)
      T. Kiguchi
    • Organizer
      CMSI/CMRI Workshop for Ferro electrics and Related Materials
    • Place of Presentation
      仙台
    • Year and Date
      2014-01-06
  • [Presentation] 収差補正電子顕微鏡によるPb(Mg_<1/3>Nb_<2/3>)O_3 薄膜における化学的秩序構造の原子分解能観察2013

    • Author(s)
      範滄宇, 木口賢紀, 今野豊彦, 安本洵, 山田智明, 長崎正雅
    • Organizer
      第33回エレクトロセラミックス研究討論会
    • Year and Date
      2013-10-25
  • [Presentation] 鉛系リラクサー薄膜における化学的秩序構造の原子分解能観察2013

    • Author(s)
      木口賢紀, 範滄宇, 塚本倫一人, 今野豊彦, 安本洵, 長崎正雅, 山田智明
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      長野
    • Year and Date
      2013-09-04
  • [Presentation] Atomic-Resolution STEM Analysis of Hetero-Nanostructure in Relaxor Thin Films2013

    • Author(s)
      T. Kiguchi, C. Fan, T. Tsukamoto, J. Yasumoto, T. Yamada, T. Nagasaki, and T.J. Konno
    • Organizer
      STAC-7
    • Place of Presentation
      横浜
    • Year and Date
      2013-06-22
  • [Presentation] 高分解能電子顕微鏡の結像原理と強誘電体薄膜への応用2012

    • Author(s)
      木口賢紀
    • Organizer
      第237回東京工業大学応用セラミックス研究所講演会
    • Place of Presentation
      横浜
    • Year and Date
      2012-12-21
  • [Presentation] PbTiO_3 エピタキシャル薄膜における90°ドメインの核生成・成長メカニズム2012

    • Author(s)
      木口賢紀, 三坂好央, 佐藤和久, 西松毅, 今野豊彦, 山田智明, 舟窪浩
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-21
  • [Presentation] PbTiO_3 エピタキシャル薄膜におけるドメイン境界構造のHRTEM 観察2012

    • Author(s)
      木口賢紀, 今野豊彦, 青柳健大, 山田智明, 舟窪浩
    • Organizer
      日本金属学会2012年春期大会
    • Place of Presentation
      名古屋
    • Year and Date
      2012-09-21
  • [Presentation] Effects of the processing condition of PMN thin films on crystallinity and chemical ordering2012

    • Author(s)
      Y. Misaka,T. Kiguchi, K. Aoyagi, N. Usami, T.J. Konno
    • Organizer
      STAC-6
    • Place of Presentation
      横浜
    • Year and Date
      2012-06-27
  • [Presentation] PbTiO_3 の昇温/降温分子動力学シミュレーション2012

    • Author(s)
      西松毅, 青柳健大, 木口賢紀, 今野豊彦, 川添良幸, Anil Kumar, Umesh V. Waghmare
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      西宮
    • Year and Date
      2012-03-21
  • [Presentation] Heating-up and cooling-down moleculardynamics simulations of 90-degree domain structures in PbTiO_32012

    • Author(s)
      T. Nishimatsu, K. Aoyagi, T. Kiguchi, T.J. Konno, Y. Kawazoe, A. Kumar, U.V. Waghmare
    • Organizer
      Fundamental Physics of Ferroelectrics and Related Materials 2012
    • Place of Presentation
      アメリカ, アルゴンヌ
    • Year and Date
      2012-01-31
  • [Presentation] CSD 法によるPMN 薄膜の作製と不均一ナノ組織の解明2011

    • Author(s)
      木口賢紀, 中村崇昭, 宇佐美徳隆, 内田寛, 坂元尚紀, 脇谷尚樹, 鈴木久男, 今野豊彦
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-09

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Published: 2015-06-25  

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