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2013 Fiscal Year Final Research Report

Functional element doping effect to multifunctional oxides thin films and elucidation of relationships among ferroic properties

Research Project

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Project/Area Number 23360284
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionNagoya University

Principal Investigator

SAKAMOTO Wataru  名古屋大学, エコトピア科学研究所, 准教授 (50273264)

Co-Investigator(Renkei-kenkyūsha) YOGO Toshinobu  名古屋大学, エコトピア科学研究所, 教授 (00135310)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords誘電体物性 / 強誘電特性 / 磁気的特性 / 格子欠陥 / 薄膜作製 / 機能元素ドープ / リーク電流特性
Research Abstract

Fabrication of the functional fusion oxide thin films which had a number of ferroic properties was carried out by the chemical solution deposition process that composition control was facile, and optimization of the doping of the functional element (Mn) to obtain desired properties was successfully achieved. In addition, for the elucidation of the properties improvement mechanism by the doping of the functional element, the valence state of the doped element and relations based on the defect chemistry between electrical and magnetic properties were clarified. Furthermore, visualization of the interaction between ferroelectric and magnetic domains was achieved.

  • Research Products

    (20 results)

All 2013 2012 2011

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (13 results)

  • [Journal Article] Influence of Volatile Element Composition and Mn Doping on the Electrical Properties of Lead-Free Piezoelectric (Bi_<0.5>Na_<0.5>)TiO3 Thin Films2013

    • Author(s)
      W. Sakamoto, N. Makino, B.-Y. Lee, T. Iijima, M. Moriya and T. Yogo
    • Journal Title

      Sensors and Actuators A

      Volume: vol.200 Pages: 60-67

    • DOI

      10.1016/j.sna.2012.10.006

    • Peer Reviewed
  • [Journal Article] Ferroelectric Properties Improvement of Mn-Doped 0.7BiFeO_3-0.3BaTiO_3 Thin Films Fabricated by Chemical Solution Deposition2013

    • Author(s)
      Y. Ito, M. Moriya, W. Sakamoto and T. Yogo
    • Journal Title

      Key Engineering Materials

      Volume: vol.566 Pages: 159-162

    • DOI

      10.4028/www.scientific.net/KEM.566.159

    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Multiferroic 0.7BiFeO_3-0.3BaTiO_3 Thin Films by Mn Doping2013

    • Author(s)
      Y. Ito, W. Sakamoto, M. Moriya and T. Yogo
    • Journal Title

      Ceramics International

      Volume: vol.39 Pages: S451-S455

    • DOI

      10.1016/j.ceramint.2012.10.112

    • Peer Reviewed
  • [Journal Article] Electrical Properties of Lead-Free Ferroelectric Mn-Doped K_<0.5>Na_<0.5>NbO_3-CaZrO_3 Thin Films Prepared by Chemical Solution Deposition2012

    • Author(s)
      T. Matsuda, W. Sakamoto, B.-Y. Lee, T. Iijima, J. Kumagai, M. Moriya, T. Yogo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: vol.51 Pages: 09LA03-1-6

    • DOI

      10.1143/JJAP.51.09LA03

    • Peer Reviewed
  • [Journal Article] マルチフェロイック酸化物の作製と物性 - BiFeO_3 と積層構造 -2012

    • Author(s)
      坂本 渉, 浅野秀文
    • Journal Title

      まぐね/Magnetics Jpn

      Volume: vol.7, no.3 Pages: 114-122

    • URL

      http://www.magnetics.jp/journal/magne.html

    • Peer Reviewed
  • [Journal Article] Nanomagnetism in Nanocrystalline Multiferroic Bismuth Ferrite Lead Titanate Films2011

    • Author(s)
      V. Tuboltsev, A. Savin, W. Sakamoto, A. Hieno, T. Yogo, J. Räisänen
    • Journal Title

      Journal of Nanoparticle Research

      Volume: vol.13 Pages: 5603-5613

    • DOI

      10.1007/s11051-010-0134-9

    • Peer Reviewed
  • [Journal Article] Synthesis of BiFeO_3-Bi_<0.5>Na_<0.5>TiO_3 Thin Films by Chemical Solution Deposition and Their Properties2011

    • Author(s)
      A. Hieno, W. Sakamoto, M. Moriya, T. Yogo
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: vol.50 Pages: 09NB04-1-6

    • DOI

      10.1143/JJAP.50.09NB04

    • Peer Reviewed
  • [Presentation] 化学溶液法により調製したMn ドープBiFeO_3 薄膜の光電流特性2013

    • Author(s)
      吉田 健司, 守谷 誠, 坂本 渉, 余語 利信
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜情報文化センター(横浜市)
    • Year and Date
      2013-12-09
  • [Presentation] Synthesis and Photo-Induced Electrical Properties of Bismuth Ferrite-Based Thin Films2013

    • Author(s)
      W. Sakamoto, N. Makino, K. Yoshida, M. Moriya and T. Yogo
    • Organizer
      The 10th Pacific Rim Conference on Ceramic and Glass Technology (PacRim10-2013)
    • Place of Presentation
      San Diego (U.S.A.)
    • Year and Date
      2013-06-04
  • [Presentation] Processing and Characterization of Multiferroic Composite Films Using Metal-Organic Precursor Solutions2013

    • Author(s)
      W. Sakamoto, Y. Kawabata, D. Maeda, M. Moriya, T. Yogo
    • Organizer
      37th International Conference and Exposition on Advanced Ceramics and Composites (ICACC'13)
    • Place of Presentation
      Daytona Beach (U.S.A.)
    • Year and Date
      2013-01-28
  • [Presentation] Bi_<0.5>Na_<0.5>TiO_3 系化合物薄膜へのMn ドープが特性に及ぼす効果2012

    • Author(s)
      牧野 成道, Bong-Yeon Lee, 守谷 誠, 坂本 渉, 飯島 高志, 余語 利信
    • Organizer
      第32回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2012-10-27
  • [Presentation] Chemically Synthesized Mn-Doped BiFeO_3-BaTiO_3 Thin Films and Their Properties2012

    • Author(s)
      W. Sakamoto, Y. Ito, M. Moriya, T. Yogo
    • Organizer
      Materials Science & Technology 2012
    • Place of Presentation
      Pittsburg (U.S.A.)
    • Year and Date
      2012-10-09
  • [Presentation] 化学溶液法によるBi(Fe,Mn)O_3 薄膜の作製と電気的・光学的特性2012

    • Author(s)
      吉田 健司, 守谷 誠, 坂本 渉, 余語 利信
    • Organizer
      日本セラミックス協会第25回秋季シンポジウム
    • Place of Presentation
      名古屋大学(名古屋市)
    • Year and Date
      2012-09-19
  • [Presentation] マルチフェロイック酸化物の材料設計と強磁性強誘電体薄膜作製へのアプローチ2012

    • Author(s)
      坂本 渉
    • Organizer
      日本セラミックス協会 東海支部 第44回東海若手セラミスト懇話会 2012年夏期セミナー
    • Place of Presentation
      ウェルシーズン浜名湖(浜松市)
    • Year and Date
      2012-06-28
  • [Presentation] 機能性酸化物材料のケミカルプロセスによる合成と特性評価 -強誘電体薄膜を中心に-2012

    • Author(s)
      坂本 渉
    • Organizer
      平成24年度応用物理学会北陸・信越支部講演会
    • Place of Presentation
      金沢大学(金沢市)
    • Year and Date
      2012-06-06
  • [Presentation] BiFeO_3 系化合物薄膜へのMnドープが特性に及ぼす効果2011

    • Author(s)
      坂本 渉, 伊藤 裕矢, 前田 大樹, 守谷 誠, 余語 利信
    • Organizer
      第31回エレクトロセラミックス研究討論会
    • Place of Presentation
      東京大学(東京都)
    • Year and Date
      2011-10-28
  • [Presentation] Mn Doping Effect on Electrical Properties of Lead-Free K_<0.5>Na_<0.5>NbO_3 Thin Films2011

    • Author(s)
      W. Sakamoto, T. Matsuda, Y. Nakashima, B.-Y. Lee, T. Iijima, M. Moriya, T. Yogo
    • Organizer
      Materials Science & Technology 2011
    • Place of Presentation
      Columbus (USA)
    • Year and Date
      2011-10-18
  • [Presentation] 化学溶液法により作製したBiFeO_3-(Bi_<0.5>Na_<0.5>)TiO_3 薄膜の電気的特性に対するMn ドープ効果2011

    • Author(s)
      坂本 渉, 日恵野 敦, 守谷 誠, 余語 利信
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形大学(山形市)
    • Year and Date
      2011-08-31
  • [Presentation] Mn Doping Effect on Electrical and Magnetic Properties of BiFeO_3-BaTiO_3 Thin Films Prepared by Chemical Solution Deposition2011

    • Author(s)
      W. Sakamoto, Y. Ito, M. Moriya, T. Yogo
    • Organizer
      International Symposium on Integrated Functionalities (ISIF) 2011
    • Place of Presentation
      Cambridge (England)
    • Year and Date
      2011-08-02
  • [Presentation] Synthesis and Properties of Multiferroic BiFeO_3-Based Thin Films by a Crystal Lattice Distortion Control2011

    • Author(s)
      W. Sakamoto, Y. Ito, A. Iwata, M. Moriya, T. Yogo
    • Organizer
      12th Conference of the European Ceramic Society (ECerS VII)
    • Place of Presentation
      Stockholm (Sweden)
    • Year and Date
      2011-06-22

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Published: 2015-06-25  

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