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2013 Fiscal Year Final Research Report

A study on phase change characteristics of Ge-Cu-Te alloy film for PCRAM

Research Project

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Project/Area Number 23360297
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

SUTOU Yuji  東北大学, 工学(系)研究科(研究院), 准教授 (80375196)

Co-Investigator(Renkei-kenkyūsha) KOIKE Junichi  東北大学, 未来科学技術共同研究センター, 教授 (10261588)
KOBAYASHI Keisuke  高知工科大学, 総合研究所, 客員教授 (50372149)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords相変化メモリ / 不揮発性メモリ / アモルファス / 結晶化
Research Abstract

Phase change random access memory (PCRAM) has attracted much attention as a new class of non-volatile memories because of its low production cost and high scalability. PCRAM is operated by way of Joule heating to induce phase transition between high resistance amorphous (reset state) and low resistance crystalline (set state) phases of a phase change material (PCM). In this study, we proposed a new PCM, Ge-Cu-Te compounds, with high crystallization temperature and low melting point, and investigated their phase change behaviors and memory characteristics.
We found that the GeCu2Te3 compound shows unique phase change characteristics, such as volume expansion by crystallization and reflectance increase by amorphization. Moreover, it was also found that the GeCu2Te3 compound shows a fast phase change speed. Therefore, the GCT film is strongly expected as a phase change material for PCRAM with low energy consumption, high data retention and fast writing speed.

  • Research Products

    (24 results)

All 2014 2013 2012 2011 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results) Presentation (10 results) (of which Invited: 7 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Multiple phase change structure for the scalable phase change random access memory array2014

    • Author(s)
      J.M. Lee, Y. Saito, Y. Sutou, J. Koike, J.W. Jung M. Sahashi, Y.H. Song
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 53 Pages: 041801-1-3

    • DOI

      10.7567/JJAP.53.041801

    • Peer Reviewed
  • [Journal Article] Origin of the unusual reflectance and density contrasts in the phase-change material Cu_2GeT_32013

    • Author(s)
      J.M. Skelton, K. Kobayashi, Y. Sutou, S.R. Elliott
    • Journal Title

      Appl. Phys. Lett

      Volume: 102 Pages: 224105-1-4

    • DOI

      10.1063/1.4809598

    • Peer Reviewed
  • [Journal Article] Investigation of a selective switching device using a phase-change material for a 3-dimensional PCRAM array2013

    • Author(s)
      JM. Lee, YH. Song, Y. Saito, Y. Sutou, J. Koike
    • Journal Title

      J. Kore. Phys. Soc

      Volume: 62 Pages: 1258-1263

    • DOI

      10.3938/jkps.62.1258

    • Peer Reviewed
  • [Journal Article] Fourfold coordicated Te atoms in amorhous GeCu_2Te_3 phase change material2013

    • Author(s)
      P. Jovari, Y. Sutou, I. Kaban, Y. Saito, J. Koike
    • Journal Title

      Scr. Mater

      Volume: 68 Pages: 122-125

    • Peer Reviewed
  • [Journal Article] Optical contrast and laser-induced phase transition in GeCu_2Te_3 thin film2013

    • Author(s)
      Y. Saito, Y. Sutou, J. Koike
    • Journal Title

      Appl. Phys. Lett

      Volume: 102 Pages: 051910-1-5

    • DOI

      10.1063/1.4791567

    • Peer Reviewed
  • [Journal Article] Fast crystal nucleation induced by surface oxidation in Si-doped GeTe amorphous thin film2012

    • Author(s)
      Y. Saito, Y. Sutou J. Koike
    • Journal Title

      Appl. Phys. Lett

      Volume: 100 Pages: 231606-1-4

    • DOI

      10.1063/1.4726107

    • Peer Reviewed
  • [Journal Article] Study of GeCu_2Te_3 by hard X-ray photoelectron spectroscopy2012

    • Author(s)
      K. Kobayashi, M. Kobata, Y. Saito, Y. Sutou, J. Koike
    • Journal Title

      Proceedings of PCOS2012

      Volume: 1 Pages: 76-84

  • [Journal Article] Multiresistance characteristics of PCRAM with GeCu_2Te_3 and Ge_2Sb_2Te_5 films2012

    • Author(s)
      Y. Saito, YH. Song, JM Lee, Y. Sutou, J. Koike
    • Journal Title

      IEEE Elec. Dev. Lett

      Volume: 33 Pages: 1399-1401

    • DOI

      10.1109/LED.2012.2210534

    • Peer Reviewed
  • [Journal Article] Effects of Si addition on the crystallization behavior of GeTe phase change materials2012

    • Author(s)
      Y. Saito, Y. Sutou J. Koike
    • Journal Title

      J. Phys. D Appl. Phys

      Volume: 45 Pages: 405302-1-7

    • DOI

      10.1088/0022-3727/45/40/405302

    • Peer Reviewed
  • [Journal Article] Crystallizaiton and electrical characteristics of Ge_1Cu_2Te_3 films for phase change random access memory2012

    • Author(s)
      T. Kamada, Y. Sutou, M. Sumiya, Y. Saito, J. Koike
    • Journal Title

      Thin Solid Films

      Volume: 520 Pages: 4389-4393

    • DOI

      10.1016/j.tsf.2012.02.025

    • Peer Reviewed
  • [Journal Article] Crystallization process and thermal stability of Ge_1Cu_2Te_3 amorphous thin films for use as phase change materials2012

    • Author(s)
      Y. Sutou, K. Kamada, T. Sumiya, Y. Saito, J. Koike
    • Journal Title

      Acta Mater

      Volume: 60 Pages: 872-880

    • DOI

      10.1016/j.actamat.2011.10.048

    • Peer Reviewed
  • [Journal Article] Crystallizaiton behavior and resistance change in eutectic Si_<15>Te_<85> amorphous films2012

    • Author(s)
      Y. Saito, Y. Sutou, J. Koike
    • Journal Title

      Thin Solid Films

      Volume: 520 Pages: 2128-2131

    • DOI

      10.1016/j.tsf.2011.09.012

    • Peer Reviewed
  • [Presentation] Phase transition characteristics of GeCu_2Te_3 film2013

    • Author(s)
      Y. Sutou
    • Organizer
      PCOS2013
    • Place of Presentation
      仙台
    • Year and Date
      2013-11-29
    • Invited
  • [Presentation] Phase transition characteristics of GeCu_2Te_3 for PCRAM2013

    • Author(s)
      Y, Sutou, Y. Saito, J. Koike
    • Organizer
      ADMETA2013
    • Place of Presentation
      東京
    • Year and Date
      2013-10-09
  • [Presentation] PCRAM 用Ge-Te 系薄膜の相変化挙動2013

    • Author(s)
      須藤祐司
    • Organizer
      第138回結晶工学分科会研究会
    • Place of Presentation
      東京
    • Year and Date
      2013-04-19
    • Invited
  • [Presentation] 不揮発性メモリ用相変化材料に関する研究2013

    • Author(s)
      須藤祐司
    • Organizer
      日本金属学会春季大会
    • Place of Presentation
      東京
    • Year and Date
      2013-03-29
    • Invited
  • [Presentation] A study on phase change characteristics of Ge-Cu-Te ternary alloy thin films2012

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike
    • Organizer
      PCOS2012
    • Place of Presentation
      静岡
    • Year and Date
      2012-11-30
  • [Presentation] Study of GeCu_2Te_3 by hard X-ray photoelectron spectroscopy2012

    • Author(s)
      K. Kobayashi, M. Kobata, Y. Saito, Y. Sutou, J. Koike
    • Organizer
      PCOS2012
    • Place of Presentation
      静岡
    • Year and Date
      2012-11-30
  • [Presentation] Crystallization behaviors and structural study of amorhous GeCu_2Te_32012

    • Author(s)
      Y. Sutou, Y. Saito, J. Koike, P. Jovari, I. Kaban
    • Organizer
      EPCOS2012
    • Place of Presentation
      フィンランド, タンペレ
    • Year and Date
      2012-07-09
    • Invited
  • [Presentation] PCRAM 用相変化材料の最近の研究開発2012

    • Author(s)
      須藤祐司
    • Organizer
      反応工学部会CVD 反応分科会主催14回シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2012-01-30
    • Invited
  • [Presentation] PCRAM 用相変化材料の研究開発動向2011

    • Author(s)
      須藤祐司
    • Organizer
      SEMI テクノロジーシンポジウム2011(セミコンジャパ2011)
    • Place of Presentation
      東京
    • Year and Date
      2011-12-08
    • Invited
  • [Presentation] Phase change characteristics of Ge_1Cu_2Te_3 films for use as phase change material2011

    • Author(s)
      Y. Sutou, Y. Saito, T. Kamada, M. Sumiya, J. Koike
    • Organizer
      EPCOS2011
    • Place of Presentation
      スイス, チューリッヒ
    • Year and Date
      2011-09-05
    • Invited
  • [Remarks]

    • URL

      http://www.koike-lab.jp/

  • [Patent(Industrial Property Rights)] Multi-level phase change memory device2012

    • Inventor(s)
      Y. Sutou,Y. Saito, J. Koike, YH. Song
    • Industrial Property Rights Holder
      東北大学, Hanyang 大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      10-2012-0039492
    • Filing Date
      2012-04-17
    • Overseas

URL: 

Published: 2015-06-25  

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