• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2013 Fiscal Year Final Research Report

Development of spin polarized metastable atom source and application of surface magnetic analysis

Research Project

  • PDF
Project/Area Number 23540387
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

AOKI Masaru  東京大学, 総合文化研究科, 助教 (50302823)

Co-Investigator(Renkei-kenkyūsha) MASUDA Shigeru  東京大学, 大学院・総合文化研究科, 教授 (50173745)
Project Period (FY) 2011 – 2013
Keywords準安定原子 / 電子分光 / 表面磁性
Research Abstract

Electronic properties of potassium-doped dibenzopentacene thin films were studied by electron spectroscopy method using herium metastable atom as a probe. The spectra for KxDBP (0 < x < 3.5) films show three types of gap state in the HOMO-LUMO gap of pristine DBP. The threshold of electron emission for K1DBP is located ~0.1 eV below the Fermi level with no metallic feature, suggesting that K1DBP is a Mott-Hubbard insulator. At the formation of K2DBP, the film has a wide-gap insulator. Upon further deposition of K, the new gap state appears near Fermi level and is attributed to partial electron filling in the LUMO+1~LUMO+3 states, however, the leading edge of the gap state is located ~0.1 eV below Fermi level without a metallic feature. Therefore, the heavily doped species transfers to a Mott-Hubbard insulator again. The gap state plays a key role in superconductivity of K3.5DBP at low temperature.

  • Research Products

    (11 results)

All 2014 2013 2012 2011 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (8 results) Remarks (1 results)

  • [Journal Article] Chemisorption-induced gap states at organic-metal interfaces : benzenethiol and benzeneselenol on metal surfaces2012

    • Author(s)
      M. Aoki, T. Kamada, K. Sasaki, S. Masuda, Y. Morikawa
    • Journal Title

      Phys.Chem.Chem.Phys

      Volume: 14 巻 Pages: 4101-4108

    • Peer Reviewed
  • [Journal Article] Loal eletroni properties at organi-metal interfaes : Thiophene deri:ati:es on Pt(111)2012

    • Author(s)
      H. Sato, S. Ushiyama, M. Sogo, M. Aoki, K. Shudo, T. Sugawara, S. Yanagisawa, Y. Morikawa, S. Masuda
    • Journal Title

      Phys.Chem.Chem.Phys

      Volume: 14 巻 Pages: 15229-15608

    • Peer Reviewed
  • [Presentation] ジベンゾペンタセン薄膜のカリウム添加による価電子構造変化2014

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      物理学会第69回年次大会
    • Place of Presentation
      東海大学(平塚)
    • Year and Date
      2014-03-27
  • [Presentation] カリウム添加ジベンゾペンタセンの価電子構造2013

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      第7回分子科学討論会
    • Year and Date
      2013-09-27
  • [Presentation] Gap states in Cs-doped organic films on Au substrate : A combined spectroscopic and theoretial study2012

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      14th Vibrations at Surface
    • Place of Presentation
      Nichii-Gakkan(Kobe)
    • Year and Date
      2012-09-25
  • [Presentation] セシウムドープされた有機薄膜におけるギャップ準位のキャラクタリゼーション2012

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学本郷キャンパス(東京)
    • Year and Date
      2012-09-21
  • [Presentation] Local electronic properties at organic-metal interface : Thiophene derivatives on Pt(111)2012

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      ICESS2012
    • Place of Presentation
      Palais des Congres(Saint-Malo)
    • Year and Date
      2012-09-18
  • [Presentation] チオフェン誘導体-Pt(111)接合系における化学吸着誘起準位2011

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター(札幌市)
    • Year and Date
      2011-09-21
  • [Presentation] Local Electronic States Induced at Thiolate-Metal Interfaces2011

    • Author(s)
      青木優, 増田茂, 他
    • Organizer
      8th International Symposium on Atomic Level Characterizations for New Materials and Devices '11
    • Place of Presentation
      Olympic Parktel(ソウル市)
    • Year and Date
      2011-05-23
  • [Presentation] カリウム添加ジベンゾペンタセン薄膜におけるギャップ電子準位の生成機構

    • Author(s)
      佐藤博史, 青木優, 増田茂, 他
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学東山キャンパス(名古屋)
  • [Remarks]

    • URL

      http://maildbs.c.u-tokyo.ac.jp/~masuda/index.html

URL: 

Published: 2015-07-16  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi