2013 Fiscal Year Final Research Report
Synthesis and properties of novel phthalocyanine analogues
| Project/Area Number |
23550040
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
SHIMIZU Soji 東北大学, 理学(系)研究科(研究院), 講師 (70431492)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 構造有機化学 / 機能性分子 / 超分子化学 / π共役 / フタロシアニン / サブフタロシアニン |
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| Research Abstract |
Synthesis of novel phthalocyanine and subphthalocyanine analogues has been an indispensable research subject in the chemistry of phthalocyanines as it can directly lead to modification of their useful optical and electrochemical properties, but the investigation along this research direction has been very limited due to synthetic difficulty. In this research, a various novel phthalocyanines and subphthalocyanines were successfully synthesized using novel synthetic precursors, which have rarely been utilized in the syntheses of phthalocyanines and subphthalocyanines, and their novel properties, which were significantly perturbed by the molecular structures and introduced functional units, were investigated and fully demonstrated by spectroscopic analyses and theoretical calculations. Moreover, by using supramolecular interactions and metal-coordination, control of molecular alignment was also investigated.
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[Journal Article] Effects of Carbon-metal-carbon Linkage on the Optical, Photophysical, and Electrochemical Properties of Phosphametallacycle-linked Coplanar Porphyrin Dimers2012
Author(s)
Y. Matano, K. Matsumoto, H, Hayashi, Y. Nakao, T, Kumpulainen, V. Chukharev, N. V. Tkachenko, H. Lemmetyinen, S. Shimizu, N, Kobayashi, D. Sakamaki, A. Ito, K. Tanaka, H. Imahori
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Journal Title
J. Am. Chem. Soc
Volume: Vol. 134
Pages: 1825-1839
DOI
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