2013 Fiscal Year Final Research Report
Development of novel sulfuration reagents acting as a sulfur-atom donor
| Project/Area Number |
23550045
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Saitama University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | 硫化 / 一原子硫黄導入 / チイラン / ワンポット合成 / 固相チイラン化 / 水素結合 |
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| Research Abstract |
Synthesis of sulfuration reagents acting as a sulfur-atom donor and their sulfuration ability were studied. As a result, we reveald that methoxycarbonylsulfenyl chloride is a suitable sulfur-atom donor for one-pot synthesis of thiiranes from alkenes, and hydrogen bonding of hydroxy groups in isolated silanols to reactants participates in solid-state thiiranation of alkenes with 3H-1,2-benzodithiole-3-one 1,1-dioxide and silica gel.
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